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천연 및 합성 제올라이트의 Triadimefon 흡ㆍ탈착 특성
Adsorption and Desorption of Triadimefon by Natural and Synthetic Zeolites
제주대학교 환경공학과, 제주 690-756 1제주도 보건환경연구원, 제주 690-170 2전북대학교 화학교육과, 전주 561-756 3부경대학교 화학공학부, 부산 608-739
Department of Environmental Engineering, Cheju National University, Jeju 690-756, Korea 1Jeju Provincial Institute of Public Health and Environmental Research, Jeju 690-170, Korea 2Department of Chemistry Education, Chonbuk National University, Chonju 561-756, Korea 3Division of Chemical Engineering, Pukyong National University, Pusan 608-739, Korea
HWAHAK KONGHAK, April 2002, 40(2), 265-273(9), NONE
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Abstract
제올라이트의 농약 흡ㆍ탈착 특성을 살펴보기 위해 천연제올라이트(CLIN), 석탄재로부터 합성된 Faujasite 제올라이트(FAUF), 스코리아와 석탄재를 6:4의 비율로 하여 합성한 FAU와 Na-P1이 혼합된 제올라이트[(FAU+Na-P1)SF], 폐 유동층 촉매 분해반응촉매(FCCW) 등을 이용하여 골프장에 살포되고 있는 triazole류 살균제인 tridaimefon에 대해 각 제올라이트와 triadimefon 상호간의 흡ㆍ탈착, triadimefon 흡착에 미치는 용액의 pH, 온도 영향 등에 대하여 검토하였다. 제올라이트 종류에 따른 triadimefon의 분배계수 KD 및 Freundlich 흡착상수인 KF는 FCCW>FAUF>(FAU+Na-P1)SF>CLIN의 순으로 감소하였다. 천연 제올라이트인 CLIN에 흡착된 triadimefon은 4회 연속적인 탈착실험 동안 쉽게 탈착이 일어나 탈착등온선이 흡착등온선에 접근하였으나, 합성 제올라이트의 경우 탈착되는 triadimefon의 양이 매우 적어 흡착등온선과 크게 벗어나는 이력현상을 보였다. 또한 이력현상은 농약의 농도가 감소할수록, 그리고 triadimefon에 대한 흡착능이 큰 제올라이트일수록 증가하였다.
Adsorption-desorption characteristics of triadimefon(pesticide) by natural zeolite(CLIN) and several synthetic zeolites was investigated. The synthetic zeolites used in this study were as follows : Faujasite(FAUS) synthesized from coal fly ash; the mixture of FAU and Na-P1 synthesized from the ratio of Jeju scoria 6 to coal fly ash 4 by weight (FAU+Na-P1)SF;_x000D_
waste fluid catalytic cracking catalyst(FCCW). The distribution coefficient, KD and Freundlich constant, KF decreased in the following sequences: FCCW>FAUF>(FAU+Na-P1)SF>CLIN among the zeolites. The desorption characteristics of triadimefon adsorbed on zeolites was greatly different among natural and synthetic zeolites, i.e., the desorption of triadimefon occurred easily_x000D_
during four successive desorption cycles for natural zeolite CLIN, however, for synthetic zeolites, it leaded to poorly defined desorption isotherms with very small triadimefon concentrations desorbed, greatly deviated from the adsorption isotherms, indicating the severe hysterisis. The hysterisis was more evident in more adsorptive zeolites and at lower triadimefon concentrations.
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Leppert D, Min. Eng., 42, 604 (1990)
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Aiello R, Colella C, Di Lorenzo A, Inquinamento, 22(5), 41 (1980)
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Henmi T, Clay Sci., 6, 277 (1987)
Lee MG, Yi G, Ahn BJ, Roddick F, Korean J. Chem. Eng., 17(3), 325 (2000)
Hyunn SS, "Studies on the Removal of Heavy Metal Ions in Wastewater using the Zeolites Synthesized from Cheju Scoria," MS thesis, Cheju National Univ. (1999)
Celis R, Koskinen WC, J. Agric. Food Chem., 47, 776 (1999)
Grover G, Weed Sci., 25, 159 (1977)
Wahid PA, Sethunathan N, J. Agric. Food Chem., 26, 101 (1978)
Singh N, Wahid PA, Murthy MVR, Sethunathan N, J. Environ. Sci. Health., B25(6), 713 (1990)
Locke MA, J. Environ. Qual., 21, 558 (1992)
Davis JW, Environ. Toxicol. Chem., 12, 27 (1993)
Sundaram KMS, Sloane L, Nott R, J. Environ. Sci. Health., B32(1), 1 (1997)
Clay SA, Koskinen WC, Weed Sci., 38, 74 (1990)
Lim SG, Bong WA, J. Korean Soc. Environ. Agric., 11, 101 (1992)
Deli J, Warren GF, Weed Sci., 19, 67 (1971)
Bansal OP, Soil Sci. Soc. Am. J., 47, 877 (1983)
Kozak J, Toth SJ, Weed Sci., 31, 368 (1983)
Sabljik A, J. Agric. Food. Chem., 32, 243 (1984)
Woodburn KB, Delfino JJ, Rao PSC, Chemopere, 24, 1037 (1992)
Oh SS, "Adsorption Characteristics and Potential Leachability of Selected Pesticides in Cheju Citrus Orchards," Ph. D. Thesis, Cheju National Univ. (1999)
Harris CI, Kaufman DD, Sheets TJ, Nash RG, Kearney PC, Adv. Pest Control Res., 8, 1 (1968)
Farmer WJ, Aochi Y, Soil Sci. Soc. Am. Proc., 38, 418 (1974)
Garcia-Miragaya J, Page AL, Soil Sci. Soc. Am. J., 40, 658 (1976)
Singhal JP, Khan SU, Bansal OP, Aust. J. Chem., 31, 2151 (1978)
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Matsumoto Y, Totsuka Y, Tsukamoto Y, Shizuoka-ken Shizuoka Kogyo Gijutsu Senta Kenkyu Hokoku, 39, 71 (1994)
Umetami T, Moriguchi Y, Yasuo H, Hayashi H, Osaka-shi Suidokyoky Suishitsu Shikensho Chosa Kenkyu Narabashi Shiken Seiseki, 45, 32 (1994)
Gregg SJ, Sing KSW, "Adsorption, Surface Area and Porosity," 2nd ed., Academic Press, London (1982)
Page AL, "Methods of Soil Analysis(2nd ed.), part 2, chemical and Microbiological Properties," Am. Soc. Agron. Inc., Soil Soc. Am. Inc., Madison, Wisconsin, USA (1985)
Tomlin C, "The Pesticide Manual(10th ed.)," Crop Protection Publications, 1000 (1994)
Jeon BE, "Synthesis of Zeolites from Cheju Scoria," MS Thesis, Chonbuk National Univ. (1994)
Kim CH, Ahn BJ, Lee M, Kam S, Appl. Chem., 4(1), 320 (2000)
Bowman BT, Sans WW, Soil Sci. Soc. Am. J., 41, 514 (1997)
Cancela GE, Taboada EP, Sanchex-Rasero F, Soil Sci., 150(6), 836 (1990)
Sanchez-Martin MJ, Sanchez-Camazano M, Soil Sci., 152(4), 283 (1991)
Hu JY, Aizawa T, Ookubo Y, Morita T, Magara Y, Water Res., 32(9), 2593 (1998)
Bosetto M, Arfaioli, Fusi P, Soil Sci., 155(2), 105 (1993)
Cheah UB, Kirkwood RC, Lum KY, Pesticide Sci., 50, 53 (1997)
Niwas R, Gupta U, Khan AA, Varshney KG, Colloids Surf. A: Physicochem. Eng. Asp., 164, 115 (2000)
Grover J, Smith AE, Can. J. Soil Sci., 54, 179 (1974)
Muray MR, Hall JK, J. Environ. Qual., 18, 51 (1989)
Hyun HN, Oh SS, Rhu SH, J. Korean Soc. Pesticide Sci., 14, 135 (1995)
Kim JH, Kam SK, Korean. J. Pesticide Sci., 4(1), 19 (2000)
Cleveland CB, Weed Technol., 10, 157 (1996)
Leenheer JA, Ahlrichs JL, Soil Sci. Soc. Amer. Proc., 35, 700 (1971)
Aly MI, Bakry N, Kishk F, El-Sebae AH, Soil Sci. Soc. Am. J., 44, 1213 (1980)
Sanchez-Martin MJ, Sandchez-Camazano M, J. Agric. Food Chem., 32, 720 (1984)
Altzman S, Kiliger L, Yaron B, J. Agric. Food Chem., 20, 1224 (1972)
Pusino A, Liu W, Petretto S, Gessa C, Can. J. Soil Sci., 73, 325 (1994)
O'Connor GA, Wierenga HH, Cheng HH, Doxtader KG, Soil Sci., 130, 157 (1980)
Barriuso E, Laird DA, Koskinen WC, Dowdy RH, Soil Sci. Am. J., 58, 1632 (1994)
Celis R, Koskinen WC, J. Agri Food Chem., 47, 782 (1999)
Cox L, koskinen WC, Yen RY, J. Agric. Food Chem., 45, 1468 (1997)
Di Toro DM, Horzempa LM, Environ. Sci. Technol., 16, 594 (1982)
