Articles & Issues
- Language
- korean
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
옥타데실아민과 폴리스티렌을 이용한 탄소나노튜브의 화학적 개질
Chemical Modification of Singlewall Carbon Nanotubes with Octadecylamine and Amino-terminated Polystyrene
한국과학기술원 생명화학공학과, 대전 305-701
Department of Chemical and Biomolecular Engineering, KAIST, Daejeon 305-701, Korea
chung@cais.kaist.ac.kr
HWAHAK KONGHAK, October 2002, 40(5), 618-623(6), NONE
Download PDF
Abstract
탄소나노튜브의 말단에 화학적 작용기를 붙여서 탄소나노튜브의 유기용매에 대한 용해도에 대해 살펴보았다. 탄소나노튜브를 정제 및 절단하여 열린 말단에 카르복실산기를 생성하고, 아미드 작용기 생성 반응을 통하여 각각 octadecylamine과 amino-terminated polystyrene을 탄소나노튜브에 붙였다. 말단에 카르복실산기가 형성된 탄소나노튜브의 경우는 유기용매에 분산이 잘 되지 않았지만, 폴리스티렌과 옥타데실아민이 붙여진 탄소나노튜브는 유기용매에 잘 분산되었다.
The solubility enhancements of singlewall carbon nanotubes(SWNTs) in various organic solvents were investigated by chemical modification of SWNTs. Carboxylic acids were attached to the open ends of SWNTs during purification and cutting. Octadecylamine and amino-terminated polystyrene were grafted to cut SWNTs via the formation of amide functionality. SWNTs with carboxylic acid bond were not dispersed well in organic solvents. But, polystyrene-grafted SWNTs and octadecylamine-grafted SWNTs were dispersed well in some organic solvents.
References
Iijima S, Nature, 354, 56 (1991)
Whitney TM, Jiang JS, Searson PC, Chien CL, Science, 261, 1316 (1993)
Dresselhaus MS, Dresselhaus G, Eklund PC, Academic Press Inc., Chap. 19 (1996)
Treacy MM, Ebbesen TW, Gibson JM, Nature, 381(6584), 678 (1996)
Delaney P, Choi HJ, Ihm J, Louie SG, Cohen ML, Nature, 391(6666), 466 (1998)
Jhi SH, Ihm J, Louie SG, Cohen ML, Nature, 399(6732), 132 (1999)
Riggs JE, Walker DB, Carroll DL, Sun YP, J. Phys. Chem. B, 104(30), 7071 (2000)
Shi Z, Lian Y, Zhou X, Gu Z, Zhang Y, Iijima S, Gong Q, Li H, Zhang SL, Chem. Commun., 6, 461 (2000)
Chen J, Hamon M, Hu H, Chen Y, Rao AM, Eklund PC, Haddon RC, Science, 282, 95 (1998)
Hamon M, Chen J, Hu H, Chen Y, Itkis M, Rao AM, Eklund PC, Haddon RC, Adv. Mater., 11, 834 (1999)
Mickelson ET, Chiang IW, Zimmerman JL, Boul PJ, Lozano J, Liu J, Smalley RE, Hauge RH, Margrave JL, J. Phys. Chem. B, 103(21), 4318 (1999)
Mickelson ET, Huffman CB, Rinzler AG, Smalley RE, Hauge RH, Margrave JL, Chem. Phys. Lett., 296, 188 (1998)
Liu J, Rinzler AG, Dai HJ, Hafner JH, Bradley RK, Boul PJ, Lu A, Iverson T, Shelimov K, Huffman CB, Rodriguez-Macias F, Shon YS, Lee TR, Colbert DT, Smalley RE, Science, 280(5367), 1253 (1998)
Rinzler A, Liu J, Dai H, Nikolaev P, Huffman C, Rodriguez-Macias F, Boul P, Lu A, Heymann D, Col-bert DT, Lee RS, Fischer F, Rao A, Eklund PC, Smalley RE, Appl. Phys. A-Mater. Sci. Process., 67, 29 (1998)
Gelinas S, Finch JA, Vreugdenhil AJ, Colloids Surf. A: Physicochem. Eng. Asp., 164, 257 (2000)
Hiura H, Ebbesen TW, Tanigaki K, Adv. Mater., 7, 275 (1995)
Chen J, Rao AM, Lyuksyutov S, Itkis ME, Hamon MA, Hu H, Cohn RW, Eklund PC, Colbert DT, Smalley RE, Haddon RC, J. Phys. Chem. B, 105(13), 2525 (2001)
Rao AM, Richter E, Bandow S, Chase B, Eklund PC, Williams KA, Fang S, Subbaswamy KR, Menon M, Thess A, Smalley RE, Dresselhaus G, Dresselhaus MS, Science, 275(5297), 187 (1997)
Chiang IW, Brinson BE, Smalley RE, Margrave JL, Hauge RH, J. Phys. Chem. B, 105(6), 1157 (2001)
Whitney TM, Jiang JS, Searson PC, Chien CL, Science, 261, 1316 (1993)
Dresselhaus MS, Dresselhaus G, Eklund PC, Academic Press Inc., Chap. 19 (1996)
Treacy MM, Ebbesen TW, Gibson JM, Nature, 381(6584), 678 (1996)
Delaney P, Choi HJ, Ihm J, Louie SG, Cohen ML, Nature, 391(6666), 466 (1998)
Jhi SH, Ihm J, Louie SG, Cohen ML, Nature, 399(6732), 132 (1999)
Riggs JE, Walker DB, Carroll DL, Sun YP, J. Phys. Chem. B, 104(30), 7071 (2000)
Shi Z, Lian Y, Zhou X, Gu Z, Zhang Y, Iijima S, Gong Q, Li H, Zhang SL, Chem. Commun., 6, 461 (2000)
Chen J, Hamon M, Hu H, Chen Y, Rao AM, Eklund PC, Haddon RC, Science, 282, 95 (1998)
Hamon M, Chen J, Hu H, Chen Y, Itkis M, Rao AM, Eklund PC, Haddon RC, Adv. Mater., 11, 834 (1999)
Mickelson ET, Chiang IW, Zimmerman JL, Boul PJ, Lozano J, Liu J, Smalley RE, Hauge RH, Margrave JL, J. Phys. Chem. B, 103(21), 4318 (1999)
Mickelson ET, Huffman CB, Rinzler AG, Smalley RE, Hauge RH, Margrave JL, Chem. Phys. Lett., 296, 188 (1998)
Liu J, Rinzler AG, Dai HJ, Hafner JH, Bradley RK, Boul PJ, Lu A, Iverson T, Shelimov K, Huffman CB, Rodriguez-Macias F, Shon YS, Lee TR, Colbert DT, Smalley RE, Science, 280(5367), 1253 (1998)
Rinzler A, Liu J, Dai H, Nikolaev P, Huffman C, Rodriguez-Macias F, Boul P, Lu A, Heymann D, Col-bert DT, Lee RS, Fischer F, Rao A, Eklund PC, Smalley RE, Appl. Phys. A-Mater. Sci. Process., 67, 29 (1998)
Gelinas S, Finch JA, Vreugdenhil AJ, Colloids Surf. A: Physicochem. Eng. Asp., 164, 257 (2000)
Hiura H, Ebbesen TW, Tanigaki K, Adv. Mater., 7, 275 (1995)
Chen J, Rao AM, Lyuksyutov S, Itkis ME, Hamon MA, Hu H, Cohn RW, Eklund PC, Colbert DT, Smalley RE, Haddon RC, J. Phys. Chem. B, 105(13), 2525 (2001)
Rao AM, Richter E, Bandow S, Chase B, Eklund PC, Williams KA, Fang S, Subbaswamy KR, Menon M, Thess A, Smalley RE, Dresselhaus G, Dresselhaus MS, Science, 275(5297), 187 (1997)
Chiang IW, Brinson BE, Smalley RE, Margrave JL, Hauge RH, J. Phys. Chem. B, 105(6), 1157 (2001)
