Articles & Issues
- Language
- korean
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
가스 하이드레이트를 이용한 이산화탄소의 심해저장
Carbon Dioxide Ocean Sequestration Using Gas Hydrate
한국과학기술원 생명화학공학과, 305-701 대전시 유성구 구성동 373-1 1고려대학교 화공생명공학과, 136-701 서울시 성북구 안암동 5가 1 2서울대학교 지구환경시스템공학과, 151-742 서울시 관악구 신림9동 산 56-1
Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology, 373-1, Guseong-dong, Yuseong-gu, Daejeon 305-701, Korea 1Department of Chemical and Biological Engineering, Korea University, 1, Anam-dong 5(o)-ga, Seongbuk-gu, Seoul 136-701, Korea 2School of Civil, Urban and Geo-System Engineering, Seoul National University, San 56-1, Sillim 9(gu)-dong, Gwanak-gu, Seoul 151-742, Korea
hlee@mail.kaist.ac.kr
HWAHAK KONGHAK, April 2003, 41(2), 135-146(12), NONE
Download PDF
Abstract
가스 하이드레이트란 고압 저온의 형성 조건에서 저분자량의 가스가 물분자들에 의해 만들어지는 격자 속으로 포집되면서 형성되는 특별한 결정 상태의 화합물을 일컫는 말이다. 가스 하이드레이트에 대한 존재가 알려진 것은 비교적 오래 되었으나, 물과 가스에 의해 형성되어 진다는 점에서 최근 관심이 증가되고 있다. 포집되는 가스의 종류에 따라 다양한 구조의 결정을 형성하는 하이드레이트는 최근 천연가스의 사용과 지구 온난화 가스에 대한 관심이 증가하면서 이들에 대한 활용을 모색하고자 연구가 진행되고 있는 상황이다. 따라서 본고에서는 가스 하이드레이트 활용 분야 중에서 최근 가장 주목받고 있는 분야, 즉 대표적 지구 온난화 가스인 이산화탄소의 심해저장과 관련하여 이산화탄소 하이드레이트에 관한 전반적인 연구 동향을 소개하도록 한다.
Gas hydrate is a special kind of inclusion compound that can be formed by capturing gas molecules to water lattice in high pressure and low temperature conditions. The hydrate crystal structures were different depending on a kind of guest molecules. Recently, gas hydrates have attracted the attention of many investigators from all areas of natural gas production and environmental science from a fact that this compound could be formed from only host water and guest gas molecules. The most attrative application of hydrates is to dispose of carbon dioxide in the form of solid hydrates in the ocean to reduce atmospheric carbon dioxide concentration and mitigate global warming. Therefore, this paper summarized present research works concerning the carbon dioxide hydrate and suggested the connection between these results and the strategies for carbon dioxide sequestration. In addition, general topics and research trends related to carbon dioxide hydrate are presented with focusing on carbon dioxide ocean sequestration to resolve the global warming problems.
References
Houghton JT, MeiraFildo LG, Collander BA, Harris N, Kattenberg A, Maskell K, Climate Change 1995: The Science of Climate Change, Cambridge University Press, Cambridge, UK (1996)
Kane RL, Klein DE, Chem. Eng. Prog., 97(6), 44 (2001)
U.S. Department of Energy, Office of Science, Office of Fossil Energy, Carbon Sequestration: State of the Science, A Working Paper for Roadmapping Future Carbon Sequestration R&D (1999)
IEA GHG, Ocean Storage of CO2, IEA Greenhouse Gas R&D Programme (1999)
Herzog H, "Ocean Sequestration of CO2: An Overview," 4th International Conference on Greenhouse Gas Control Technologies, August 30-September 2, Interlaken, Switzerland (1998)
Sloan ED, Clathrate Hydrate of Natural Gases, 2nd ed., Marcel Dekker, New York (1998)
Jeffrey GA, McMullan RK, Prog. Inorg. Chem., 8, 43 (1967)
McMullan RK, Jeffery GA, J. Chem. Phys., 42(8), 2725 (1965)
Mak TCW, McMullan RK, J. Chem. Phys., 42(8), 2732 (1965)
Davison DW, El-Defrawy MK, Fuglem MO, Judge AS, Proceedings of 3rd International Conference on Permafrost 1, 938-943 (1983)
Ripmeester JA, Tse JS, Ratcliffe CI, Powell BM, Nature, 325, 135 (1987)
Udachin KA, Lipkowski J, "New Structures of Calthrates Hydrates," Proceedings of 2nd International Conference on Natural Gas Hydrates, 25-32 (1996)
Mehta AP, Sloan DE, "Structure H Hydrates: the State-of-the-art," Proceedings of 2nd International Conference on Natural Gas Hydrates, 1-8 (1996)
Holder GD, Zetts SP, Pradham N, Rev. Chem. Eng., 5, 1 (1988)
vander Waals JH, Platteeuw JC, Adv. Chem. Phys., 2, 1 (1959)
McKoy V, Sinanoglu O, J. Chem. Phys., 38, 2946 (1963)
Parrish WR, Prausnitz JM, Ind. Eng. Chem. Process Des. Dev., 11, 26 (1972)
Holder GD, Corbin G, Papadopoulos KD, Ind. Eng. Chem. Fundam., 19, 282 (1980)
Soave G, Chem. Eng. Sci., 27, 1197 (1972)
Huron MJ, Vidal J, Fluid Phase Equilib., 3, 255 (1979)
Dahl S, Michelsen ML, AIChE J., 36, 1829 (1990)
Yoon JH, Chun MK, Lee H, AIChE J., 48(6), 1317 (2002)
Yang SO, Yang IM, Kim YS, Lee CS, Fluid Phase Equilib., 175(1-2), 75 (2000)
Englezos P, Ind. Eng. Chem. Res., 32(7), 1251 (1993)
Englezos P, Hall S, Can. J. Chem. Eng., 72(5), 887 (1994)
Dholabhai PD, Kalogerakis N, Bishnoi PR, J. Chem. Eng. Data, 38(4), 650 (1993)
Dholabhai PD, Parent JS, Bishnoi PR, Ind. Eng. Chem. Res., 35(3), 819 (1996)
Kang SP, Chun MK, Lee H, Fluid Phase Equilib., 147(1-2), 229 (1998)
Larson SD, Ph.D. Dissertation, Univ. of Michigan (1955)
Uchida T, Ebinuma T, Takeya S, Nagao J, Narita H, J. Phys. Chem. B, 106(4), 820 (2002)
Seo Y, Lee H, Uchida T, Langmuir, 18(24), 9164 (2002)
Vysniauskas A, Bishinoi PR, Chem. Eng. Sci., 38, 1061 (1983)
Glew DN, Hagget ML, Can. J. Chem., 46, 3857 (1968)
Scanlon WJ, Fennema O, Cryobiology, 8, 249 (1972)
Englezos P, Kalogerakis NE, Dholabhai PD, Bishnoi PR, Chem. Eng. Sci., 42, 2659 (1987)
Skovborg P, Rasmussen P, Chem. Eng. Sci., 49(8), 1131 (1994)
Shindo Y, Lund PC, Fujioka Y, Komiyama H, Energy Conv. Manag., 34, 1073 (1993)
Teng H, Kinoshita CM, Masutani SM, Chem. Eng. Sci., 50(4), 559 (1995)
Chun MK, Lee H, Korean J. Chem. Eng., 13(6), 620 (1996)
Udachin KA, Ratcliffe CI, Ripmeester JA, J. Phys. Chem. B, 105(19), 4200 (2001)
Takeya S, Hondoh T, Uchida T, Annals of the New York Academy of Sciences, 912, 973 (2000)
Davidson DW, Ripmeester JA, In Inclusion Compounds, Atwood, J.L., Davies, J.E.D. and MacNichol, D.D., Eds., Academic Press, New York, vol. 3 (1983)
Ripmeester JA, Ratcliffe CI, Solid State NMR Studies of Inclusion Compounds, Report C1181-895, National Research Council of Canada (1989)
Ripmeester JA, Ratcliffe CI, J. Phys. Chem., 94, 8773 (1990)
Ripmeester JA, Ratcliffe CI, J. Phys. Chem., 92, 337 (1988)
Dharmawardhana PB, Parrish WR, Sloan ED, Ind. Eng. Chem. Fundam., 19, 410 (1980)
Davidson DW, Handa YP, Ripmeester JA, J. Phys. Chem., 90, 6549 (1986)
Ripmeester JA, Ratcliffe CI, Energy Fuels, 12(2), 197 (1998)
Sum AK, Burruss RC, Sloan ED, J. Phys. Chem. B, 101(38), 7371 (1997)
Seo Y, Lee H, J. Phys. Chem. B, 106(37), 9668 (2002)
Uchida T, Takagi A, Kawabata J, Mae S, Hondoh T, Energy Conv. Manag., 36, 547 (1995)
Kawamura T, Komai T, Yamamoto Y, Nagashima K, Ohga K, Higuchi K, J. Cryst. Growth, 234, 220 (2002)
Parrish WR, Prausnitz JM, Ind. Eng. Chem. Process Des. Dev., 11, 26 (1972)
Aya I, Yamane K, Nariai H, Energy Int. J., 22, 263 (1997)
Yoon JH, Lee H, AIChE J., 43(7), 1884 (1997)
Seo Y, Lee H, Environ. Sci. Technol., 35, 3386 (2001)
Kang SP, Lee H, Environ. Sci. Technol., 34, 4397 (2000)
Yamasaki A, Teng H, Wakatsuki M, Yanagisawa Y, Yamada K, Ann. NY Acad. Sci., 912, 235 (2000)
Teng H, Yamasaki A, Shindo Y, Int. J. Energy Res., 23(4), 295 (1999)
Koide H, Takahashi M, Tsukamoto H, Energy Conv. Manag., 36, 505 (1995)
Koide H, Takahashi M, Shindo Y, Tazaki Y, Iijima M, Ito K, Kimura N, Omata K, Energy, 22(2-3), 279 (1997)
Ohgaki K, Nakano S, Matsubara T, Yamanaka S, J. Chem. Eng. Jpn., 30(2), 310 (1997)
Komai T, Yamamoto Y, Ohga K, Ann. NY Acad. Sci., 912, 272 (2000)
Lee H, Kang JM, "Development of the Fundamental Key Technologies for Large Scale Ocean Sequestration of Carbon Dioxide," the Greenhouse Gas Research Center, Korea (2002)
Kane RL, Klein DE, Chem. Eng. Prog., 97(6), 44 (2001)
U.S. Department of Energy, Office of Science, Office of Fossil Energy, Carbon Sequestration: State of the Science, A Working Paper for Roadmapping Future Carbon Sequestration R&D (1999)
IEA GHG, Ocean Storage of CO2, IEA Greenhouse Gas R&D Programme (1999)
Herzog H, "Ocean Sequestration of CO2: An Overview," 4th International Conference on Greenhouse Gas Control Technologies, August 30-September 2, Interlaken, Switzerland (1998)
Sloan ED, Clathrate Hydrate of Natural Gases, 2nd ed., Marcel Dekker, New York (1998)
Jeffrey GA, McMullan RK, Prog. Inorg. Chem., 8, 43 (1967)
McMullan RK, Jeffery GA, J. Chem. Phys., 42(8), 2725 (1965)
Mak TCW, McMullan RK, J. Chem. Phys., 42(8), 2732 (1965)
Davison DW, El-Defrawy MK, Fuglem MO, Judge AS, Proceedings of 3rd International Conference on Permafrost 1, 938-943 (1983)
Ripmeester JA, Tse JS, Ratcliffe CI, Powell BM, Nature, 325, 135 (1987)
Udachin KA, Lipkowski J, "New Structures of Calthrates Hydrates," Proceedings of 2nd International Conference on Natural Gas Hydrates, 25-32 (1996)
Mehta AP, Sloan DE, "Structure H Hydrates: the State-of-the-art," Proceedings of 2nd International Conference on Natural Gas Hydrates, 1-8 (1996)
Holder GD, Zetts SP, Pradham N, Rev. Chem. Eng., 5, 1 (1988)
vander Waals JH, Platteeuw JC, Adv. Chem. Phys., 2, 1 (1959)
McKoy V, Sinanoglu O, J. Chem. Phys., 38, 2946 (1963)
Parrish WR, Prausnitz JM, Ind. Eng. Chem. Process Des. Dev., 11, 26 (1972)
Holder GD, Corbin G, Papadopoulos KD, Ind. Eng. Chem. Fundam., 19, 282 (1980)
Soave G, Chem. Eng. Sci., 27, 1197 (1972)
Huron MJ, Vidal J, Fluid Phase Equilib., 3, 255 (1979)
Dahl S, Michelsen ML, AIChE J., 36, 1829 (1990)
Yoon JH, Chun MK, Lee H, AIChE J., 48(6), 1317 (2002)
Yang SO, Yang IM, Kim YS, Lee CS, Fluid Phase Equilib., 175(1-2), 75 (2000)
Englezos P, Ind. Eng. Chem. Res., 32(7), 1251 (1993)
Englezos P, Hall S, Can. J. Chem. Eng., 72(5), 887 (1994)
Dholabhai PD, Kalogerakis N, Bishnoi PR, J. Chem. Eng. Data, 38(4), 650 (1993)
Dholabhai PD, Parent JS, Bishnoi PR, Ind. Eng. Chem. Res., 35(3), 819 (1996)
Kang SP, Chun MK, Lee H, Fluid Phase Equilib., 147(1-2), 229 (1998)
Larson SD, Ph.D. Dissertation, Univ. of Michigan (1955)
Uchida T, Ebinuma T, Takeya S, Nagao J, Narita H, J. Phys. Chem. B, 106(4), 820 (2002)
Seo Y, Lee H, Uchida T, Langmuir, 18(24), 9164 (2002)
Vysniauskas A, Bishinoi PR, Chem. Eng. Sci., 38, 1061 (1983)
Glew DN, Hagget ML, Can. J. Chem., 46, 3857 (1968)
Scanlon WJ, Fennema O, Cryobiology, 8, 249 (1972)
Englezos P, Kalogerakis NE, Dholabhai PD, Bishnoi PR, Chem. Eng. Sci., 42, 2659 (1987)
Skovborg P, Rasmussen P, Chem. Eng. Sci., 49(8), 1131 (1994)
Shindo Y, Lund PC, Fujioka Y, Komiyama H, Energy Conv. Manag., 34, 1073 (1993)
Teng H, Kinoshita CM, Masutani SM, Chem. Eng. Sci., 50(4), 559 (1995)
Chun MK, Lee H, Korean J. Chem. Eng., 13(6), 620 (1996)
Udachin KA, Ratcliffe CI, Ripmeester JA, J. Phys. Chem. B, 105(19), 4200 (2001)
Takeya S, Hondoh T, Uchida T, Annals of the New York Academy of Sciences, 912, 973 (2000)
Davidson DW, Ripmeester JA, In Inclusion Compounds, Atwood, J.L., Davies, J.E.D. and MacNichol, D.D., Eds., Academic Press, New York, vol. 3 (1983)
Ripmeester JA, Ratcliffe CI, Solid State NMR Studies of Inclusion Compounds, Report C1181-895, National Research Council of Canada (1989)
Ripmeester JA, Ratcliffe CI, J. Phys. Chem., 94, 8773 (1990)
Ripmeester JA, Ratcliffe CI, J. Phys. Chem., 92, 337 (1988)
Dharmawardhana PB, Parrish WR, Sloan ED, Ind. Eng. Chem. Fundam., 19, 410 (1980)
Davidson DW, Handa YP, Ripmeester JA, J. Phys. Chem., 90, 6549 (1986)
Ripmeester JA, Ratcliffe CI, Energy Fuels, 12(2), 197 (1998)
Sum AK, Burruss RC, Sloan ED, J. Phys. Chem. B, 101(38), 7371 (1997)
Seo Y, Lee H, J. Phys. Chem. B, 106(37), 9668 (2002)
Uchida T, Takagi A, Kawabata J, Mae S, Hondoh T, Energy Conv. Manag., 36, 547 (1995)
Kawamura T, Komai T, Yamamoto Y, Nagashima K, Ohga K, Higuchi K, J. Cryst. Growth, 234, 220 (2002)
Parrish WR, Prausnitz JM, Ind. Eng. Chem. Process Des. Dev., 11, 26 (1972)
Aya I, Yamane K, Nariai H, Energy Int. J., 22, 263 (1997)
Yoon JH, Lee H, AIChE J., 43(7), 1884 (1997)
Seo Y, Lee H, Environ. Sci. Technol., 35, 3386 (2001)
Kang SP, Lee H, Environ. Sci. Technol., 34, 4397 (2000)
Yamasaki A, Teng H, Wakatsuki M, Yanagisawa Y, Yamada K, Ann. NY Acad. Sci., 912, 235 (2000)
Teng H, Yamasaki A, Shindo Y, Int. J. Energy Res., 23(4), 295 (1999)
Koide H, Takahashi M, Tsukamoto H, Energy Conv. Manag., 36, 505 (1995)
Koide H, Takahashi M, Shindo Y, Tazaki Y, Iijima M, Ito K, Kimura N, Omata K, Energy, 22(2-3), 279 (1997)
Ohgaki K, Nakano S, Matsubara T, Yamanaka S, J. Chem. Eng. Jpn., 30(2), 310 (1997)
Komai T, Yamamoto Y, Ohga K, Ann. NY Acad. Sci., 912, 272 (2000)
Lee H, Kang JM, "Development of the Fundamental Key Technologies for Large Scale Ocean Sequestration of Carbon Dioxide," the Greenhouse Gas Research Center, Korea (2002)
