Articles & Issues
- Language
- korean
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received October 22, 2003
Accepted January 5, 2004
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
C1-HVOCs 제거를 위한 Ru-Sn/γ-Al2O3 촉매 제조 및 반응성 평가
Preparation of Ru-Sn/γ-Al2O3 Catalyst and Evaluation of its Reactivity for the Removal of C1-HVOCs
서강대학교 화공생명공학과, 121-742 서울시 마포구 신수동 1 1대진대학교 화학공학과, 487-711 경기도 포천군 포천읍 선단리 11-1 2한국에너지기술연구원, 305-343 대전시 유성구 장동 71-2
Department of Chemical and Biomolecular Engineering, Sogang University, 1, Sinsu-dong, Mapo-gu, Seoul 121-742, Korea 1Department of Chemical Engineering, DaeJin University, 11-1, Sondan-ri, Pochun-up, Pochun-gun, Kyonggi 487-711, Korea 2Korea Institute of Energy Research, 71-2, Jang-dong, Yuseong-gu, Daejeon 305-343, Korea
koo@sogang.ac.kr
Korean Chemical Engineering Research, February 2004, 42(1), 38-43(6), NONE Epub 21 April 2004
Abstract
HVOCs 제거에 사용되는 백금-팔라듐계보다 저렴한 촉매 개발을 목적으로 다양한 루테늄계 촉매를 제조하여 C1-HVOCs분해 특성 평가 실험을 수행하였다. 그 결과 Ru[2]-Sn[2]/γ-Al2O3 촉매가 가장 우수한 성능을 보였다. 구조 증진제인 주석은 흡착 산소의 양을 증가시키고, 다양한 산소 이온 종의 생성에 기여함을 알 수 있었다. HVOCs분해 반응에 첨가되는 산소 원자는 주로 루테늄과 주석에 흡착되며, CH3Cl등 HVOCs는 지지체인 γ-Al2O3의 브뢴스테드 및 루이스 산점에 흡착됨을 알 수 있었다. 흡착된 HVOCs의 염소와 브뢴스테드 산점의 수소의 화학 결합에 의한 HCl의 생성 반응이 HVOCs 분해의 주 반응 기구임을 알 수 있었다.
Various ruthenium(Ru) based catalysts, which were less expensive than Pt-Pd based catalysts, were prepared and their activity with C1-HVOCs (Halogenated Volatile Organic Compounds) was evaluated. Ru[2]-Sn[2]/γ-Al2O3 was found to have the most desirable effect on the destruction of HVOCs. Tin taken as a structural promoter was found to increase the amount of oxygen adsorption and to generate various oxygen ions. Oxygen atoms were found to be mainly adsorbed on the surface of ruthenium and tin and HVOCs such as CH3Cl to be adsorbed on Bronsted and Lewis acid sites of γ-Al2O3 supports. It was found that the formation of HCl by the reaction of chlorine in HVOCs with hydrogen atom on Bronsted acid site was the main reaction mechanism in the destruction of HVOCs.
Keywords
References
Spivey JJ, Ind. Eng. Chem. Res., 26, 2165 (1987)
Sinquin G, Petit C, Libs S, Hindermann JP, Kiennemann A, Appl. Catal. B: Environ., 27(2), 105 (2000)
Report of Korea Institute of Energy Research "Efficient Exclusion Technology of Halogenation Volatility Organic Compound by Catalytic Oxidation," (1998)
Yang K, Reedy JD, Scamehorn JF, "Decomposition of Halogenated Organic Compounds," U.S. Patent, No. 4,059,675 (1977)
Hu SC, Chen YW, Ind. Eng. Chem. Res., 40(26), 6099 (2001)
Kawanami Y, Sonoda Y, Mori T, Yamamoto K, "Ruthenium Catlayzed Hydroxilylation of 1-Alkynes with Novel Regioselectivity," Organic Letters, 4, 2825-2827 (2002)
Windawi H, Zhang ZC, Catal. Today, 30(1-3), 99 (1996)
Lester GR, Catal. Today, 53(3), 407 (1999)
Chon HZ, Catalysis an Introduction, 3rd ed., Hanlimwon, Seoul (1995)
Kim HG, "Surface Characterization of γ-Al2O3 Prepared by Sol-Gel Process," M.S. Dissertation, Sogang Univ. (1998)
Spivy JJ, Butt JB, Catal. Today, 11, 465 (1992)
Stampfl C, Scheffler M, Surf. Sci., 433-435, 119 (1999)
Gonzalez-Velasco JR, Aranzabal A, Lopez-Fonseca R, Ferret R, Gonzalez-Marcos JA, Appl. Catal. B: Environ., 24(1), 33 (2000)
Ramachandran B, Greene HL, Chatterjee S, Appl. Catal. B: Environ., 8(2), 157 (1996)
Sinquin G, Petit C, Libs S, Hindermann JP, Kiennemann A, Appl. Catal. B: Environ., 27(2), 105 (2000)
Report of Korea Institute of Energy Research "Efficient Exclusion Technology of Halogenation Volatility Organic Compound by Catalytic Oxidation," (1998)
Yang K, Reedy JD, Scamehorn JF, "Decomposition of Halogenated Organic Compounds," U.S. Patent, No. 4,059,675 (1977)
Hu SC, Chen YW, Ind. Eng. Chem. Res., 40(26), 6099 (2001)
Kawanami Y, Sonoda Y, Mori T, Yamamoto K, "Ruthenium Catlayzed Hydroxilylation of 1-Alkynes with Novel Regioselectivity," Organic Letters, 4, 2825-2827 (2002)
Windawi H, Zhang ZC, Catal. Today, 30(1-3), 99 (1996)
Lester GR, Catal. Today, 53(3), 407 (1999)
Chon HZ, Catalysis an Introduction, 3rd ed., Hanlimwon, Seoul (1995)
Kim HG, "Surface Characterization of γ-Al2O3 Prepared by Sol-Gel Process," M.S. Dissertation, Sogang Univ. (1998)
Spivy JJ, Butt JB, Catal. Today, 11, 465 (1992)
Stampfl C, Scheffler M, Surf. Sci., 433-435, 119 (1999)
Gonzalez-Velasco JR, Aranzabal A, Lopez-Fonseca R, Ferret R, Gonzalez-Marcos JA, Appl. Catal. B: Environ., 24(1), 33 (2000)
Ramachandran B, Greene HL, Chatterjee S, Appl. Catal. B: Environ., 8(2), 157 (1996)
