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Received August 7, 2003
Accepted June 21, 2004
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퇴비를 이용한 플라스틱의 호기성 생분해도 측정
Determination of Aerobic Biodegradability of Plastic Materials using Compost
상명대학교 자연과학부, 110-743 서울시 종로구 홍지동 7 1한국기술표준원 생활복지표준과, 427-716 과천시 중앙동 2
Division of Natural Sciences, Sangmyung University, 7, Hongji-dong, Jongro-gu, Seoul 110-743, Korea 1Divisoin of Living & Welfare Standards Agency for Technology and Standards, 2, Jungang-dong, Gwacheon 427-716, Korea
mnkim@smu.ac.kr
Korean Chemical Engineering Research, August 2004, 42(4), 471-476(6), NONE Epub 15 September 2004
Abstract
동물 사료를 퇴비화한 퇴비를 이용하여 플라스틱의 생분해도를 KS M 3100-1(2002)의 규격에 의거하여 측정하였을 때 평가 결과의 재현성을 반복 실험을 통하여 조사하였다. 퇴비로부터의 이산화탄소 발생은 실험을 3회 반복하더라도 상호 유사한 거동을 나타내었다. Polycaprolactone(PCL)과 poly(butylene succinate-co-butylene adipate)(PBSA)에 대한 생분해도 측정을 동물 사료 퇴비를 이용하여 행한 결과 제조 날짜가 다른 퇴비를 사용하였을 때 생분해 10-35일 사이에는 생분해도가 약간 다르게 나타났으나 최종 생분해도는 상효 유사하여 퇴비를 이용한 플라스틱의 생분해도는 훌륭한 재현성을 보였다.
Biodegradability of plastics was evaluated according to KS M3100-1(2002) and reproducibility of the evaluation results was examined using a compost made from an animal fodder composting. Amount of CO2 produced from the compost exhibited almost the same trend in the three times of the repeated experiments. Biodegradability of polycaprolactone(PCL) and poly(butylene succinate-co-butylene adipate)(PBSA) was carried out by using the compost and it appeared slightly different during 10-35 days after the onset of the biodegradation test depending on the compost production date. However the final biodegradability was almost identical in the repeated experiments indicating that the biodegradation test can be realized in the compost with an excellent reproducibility.
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ASTM D5247-92, "Standard Test Method for Determining the Aerobic Biodegradability of Degradable Plastic by Spedific Microorganisms," Annual Book of ASTM Standards, Vol. 08-03, American Society for Testing and Materials, Philadelphia, U.S.A, 08-03 (1992)
Fields RD, Rodirguez P, Finn RK, J. Appl. Polym. Sci., 18(12), 3571 (1974)
ASTM D5338-92, "Standard Test Method for Determining the Aerobic Biodegradation of Plastics Materials Under Controlled Composting Condition," Annual Book of ASTM Standards, Vol. 08-03, American Society for Testing and Materials, Philadelphia, U.S.A, 08-03 (1992)
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Bernal MP, Sanchez-Monedero MA, Paredes C, Roig A, Agric. Ecosyst. Environ., 69(3), 175 (1998)
Fang M, Wong JWC, Ma KK, Wong MH, Bioresour. Technol., 67(1), 19 (1999)
Park JB, Kim YS, Choi SS, Hur HW, Han SH, J. Kor. Solid Wastes Engineering Society., 18, 559 (2001)
Ratto JA, Stenhouse PJ, Auerbach M, Mitchell J, Farrell R, Polymer, 40(24), 6777 (1999)
Ohtaki A, Akakura N, Nakasaki K, Polym. Degrad. Stabil., 62(2), 279 (1998)