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- In relation to this article, we declare that there is no conflict of interest.
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Received September 2, 2004
Accepted September 15, 2004
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화학공학에 마이크로파 에너지의 응용
Application of Microwave Energy in Chemical Engineering
부경대학교 응용화학공학부, 608-739 부산시 남구 용당동 산 100
Division of Applied Chemical Engineering, Pukyong National University, San 100, Yongdang-dong, Nam-gu, Busan 608-739, Korea
sspark@pknu.ac.kr
Korean Chemical Engineering Research, October 2004, 42(5), 485-493(9), NONE Epub 18 November 2004
Abstract
일상생활에서 음식물을 빠르고 편리하게 가열시키기 위하여 전자레인지를 반복적으로 사용한다. 최근 많은 과학자들은 이 가열방법의 잠재적인 응용 가능성을 인식하여 급속 및 선택적 가열 특성을 가진 마이크로파 기술을 다른 유용한 공정에 응용하고 있는 추세이다. 따라서 본 총설에서는 마이크로파 기술을 많은 공정에 응용하기 위하여 요구되는 기초 지식으로서 마이크로파 가열의 원리 및 특성, 마이크로파 장치의 설계, 마이크로파 물질간의 상호작용, 향후 마이크로파 응용 가능성 등에 관하여 간단히 소개하였다. 특히, 매개체 및 반응기구를 중심으로 화학반응에서의 마이크로파의 열적 및 비열적 효과를 집중적으로 설명하였다.
The fast and convenient heating of foodstuffs in microwave ovens is routinely used in the common life. Recently, many researchers have recognized other potential applications for this method of heating, then have applied the rapid and selective heating associated with microwave technology to a number of useful processes. With the tool of the basic information required to apply the microwave technology to many processes, this paper reviewed briefly the principle and characteristic of microwave heating, the design of microwave unit, the interaction of microwave-matter, and the outlook of future microwave technology. Especially, it is focussed to explain the microwave thermal and nonthermal effects in organic synthesis based on medium effects and mechanistic considerations.
References
Laverghetta TS, Practical Microwaves, Prentice-Hall, New Jersey (1996)
Collin RE, Foundations for Microwave Engineering. McGrawHill, New York (1985)
Loupy A, Microwaves in Organic Synthesis, Wiley-VCH, Weinheim (2002)
Sutton WH, Am. Ceram. Soc. Bull., 68, 376 (1989)
Chabinsky IJ, MRS Symp. Proc, 124, 17 (1988)
Oda SJ, MRS Symp. Proc, 347, 371 (1994)
Bolomey JC, Metail JP, MRS Symp. Proc., 189, 15 (1991)
Kingston HM, Jassie LB, Anal. Chem., 58, 2534 (1986)
Park SS, Meek TT, J. Mater. Sci., 26, 6309 (1991)
Fathi Z, Folz DC, Clark DE, Hutcheon R, Ceram. Trans, 36, 333 (1993)
Liao LQ, Liu LJ, Zhang C, He F, Zhuo RX, Wan K, J. Polym. Sci. A: Polym. Chem., 40(11), 1749 (2002)
Newalker BL, Olanrewaju J, Komarneni S, Chem. Mater., 13, 552 (2001)
Ding Y, Masuda N, Miura Y, J. Non-Cryst. Solids, 203, 88 (1996)
Komarneni S, Li DS, Newalkar B, Katsuki H, Bhalla AS, Langmuir, 18(15), 5959 (2002)
Jacob J, Chia LH, Boey FY, J. Mater. Sci., 30(21), 5321 (1995)
Karz JD, Blake RD, Ceram. Trans., 21, 95 (1991)
Raner KD, Strauss CR, Trainor RW, J. Org. Chem., 60, 2456 (1995)
Strauss CR, Trainor RW, Aust. J. Chem., 48, 1665 (1995)
Caddick S, Tetrahedron, 51, 10403 (1995)
Kingston HM, Haswell SJ, Microwave Enhanced Chemistry, Amer. Chem. Soc., Washington DC (1997)
Berteaud AJ, Badot JC, J. Microwave Power, 11, 315 (1976)
Tinga WR, MRS Symp. Proc, 124, 33 (1994)
Ford JD, Pei DCT, J. Microwave Power, 2, 61 (1967)
Hippel AV, Dielectric Materials and Applications, Artech House, London (1995)
Perreux L, Loupy A, Tetrahedron, 57, 9199 (2001)
Okress EC, Microwave Power Engineering, Academic Press, New York (1968)
Metaxas AC, Meredith RJ, Industrial Microwave Heating, Peter Peregrinus Lts., London (1993)
Jung KS, Ro JY, Lee JY, Park SS, J. Mater. Sci. Lett., 20, 2203 (2001)
Laverghetta TS, Microwave Materials and Fabrication Techniques, Artech House, London (2000)
Copson DA, Microwave Heating, AVI Publishing Co., Connecticut (1975)
Kashyap SC, Wyslouzil A, J. Microwave Power, 12, 223 (1977)
Chan CT, Reader HC, Understanding Microwave Heating Cavities, Artech House, London (2000)
Luxtron Corporation, 2775 Northwestern Parkway, Santa Clara, CA 95051-0941, USA(www.luxtron.com)
Land Infrared, 10 Friends Lane, Newtown, PA 18940-1814, USA(www.landinst.com)
Raytek Corporation, 1201 Shaffer Road, PO Box 1820, Santa Cruz, CA 95061-1820, USA(www.ravtek.com)
Olmstead WE, Brodwin ME, Int. J. Heat Mass Transf., 40(7), 1559 (1997)
Pert EP, Carmel Y, Birnboim A, Olorunyolemi T, Gershon D, Calame J, Lloyd IK, Wilson OC, J. Am. Ceram. Soc., 84, 1981 (2001)
Binner JGP, Fernie JA, Whitaker PA, Cross TE, J. Mater. Sci., 33(12), 3017 (1998)
Lewis DA, Summers JD, Ward TC, McGrath JE, J. Polym. Sci. A: Polym. Chem., 30, 1647 (1992)
Shibata C, Kashima T, Ohuchi K, Jpn. J. Appl. Phys., 35, 316 (1996)
Kabza KG, Chapados BR, Gestwicki JE, McGrath JL, J. Org. Chem., 65, 1210 (2000)
Langa F, Cruz P, Hoz A, Espildora E, Cossio FP, Lecea B, J. Org. Chem., 65, 2499 (2000)
Raner KD, Strauss CR, J. Org. Chem., 57, 6231 (1992)
Chandra Sheker Reddy A, Shanthan Rao P, Venkataratnam RV, Tetrahedron Lett., 37, 2845 (1996)
Laurent R, Laporterie A, Dubac J, Lefeuvre S, Audhuy M, J. Org. Chem., 57, 7099 (1992)
Tanaka K, Toda F, Chem. Rev., 100(3), 1025 (2000)
Carrillo JR, Diaz-Ortiz A, Cossio FP, Gomez-Escalonilla MJ, Hoz A, Moreno A, Prieto P, Tetrahedron, 50, 1569 (2000)
Hammond GS, J. Am. Chem. Soc., 77, 334 (1955)
Carrillo-Munoz JR, Bouvet D, Guibe-Jampel E, Loupy A, Petit A, J. Org. Chem., 61, 7746 (1996)
Hoz A, Diaz-Ortiz A, Moreno A, Langa F, Eur. J. Org. Chem., 65, 3659 (2000)
Varma RS, Dahiya R, Kumar S, Tetrahedron Lett., 38, 2039 (1997)
Park SS, Hwang EH, Kim BC, Park HC, J. Am. Ceram. Soc., 83, 1341 (2000)
Park SS, Jung KS, Kim BC, Lee SE, Park HC, Glass Technol., 43, 70 (2002)
Park HC, Kim SW, Lee SG, Kim JK, Hong SS, Lee GD, Park SS, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 363, 330 (2003)
Kim SW, Lee SG, Kim JK, Kwon JY, Park HC, Park SS, J. Mater. Sci., 39(4), 1445 (2004)
Jung KS, Kwon JH, Shon SM, Ko JP, Shin JS, Park SS, J. Mater. Sci., 39(2), 723 (2004)
Jung KS, Kwon JH, Son SM, Shin JS, Lee GD, Park SS, Synth. Met., 141, 259 (2004)
Collin RE, Foundations for Microwave Engineering. McGrawHill, New York (1985)
Loupy A, Microwaves in Organic Synthesis, Wiley-VCH, Weinheim (2002)
Sutton WH, Am. Ceram. Soc. Bull., 68, 376 (1989)
Chabinsky IJ, MRS Symp. Proc, 124, 17 (1988)
Oda SJ, MRS Symp. Proc, 347, 371 (1994)
Bolomey JC, Metail JP, MRS Symp. Proc., 189, 15 (1991)
Kingston HM, Jassie LB, Anal. Chem., 58, 2534 (1986)
Park SS, Meek TT, J. Mater. Sci., 26, 6309 (1991)
Fathi Z, Folz DC, Clark DE, Hutcheon R, Ceram. Trans, 36, 333 (1993)
Liao LQ, Liu LJ, Zhang C, He F, Zhuo RX, Wan K, J. Polym. Sci. A: Polym. Chem., 40(11), 1749 (2002)
Newalker BL, Olanrewaju J, Komarneni S, Chem. Mater., 13, 552 (2001)
Ding Y, Masuda N, Miura Y, J. Non-Cryst. Solids, 203, 88 (1996)
Komarneni S, Li DS, Newalkar B, Katsuki H, Bhalla AS, Langmuir, 18(15), 5959 (2002)
Jacob J, Chia LH, Boey FY, J. Mater. Sci., 30(21), 5321 (1995)
Karz JD, Blake RD, Ceram. Trans., 21, 95 (1991)
Raner KD, Strauss CR, Trainor RW, J. Org. Chem., 60, 2456 (1995)
Strauss CR, Trainor RW, Aust. J. Chem., 48, 1665 (1995)
Caddick S, Tetrahedron, 51, 10403 (1995)
Kingston HM, Haswell SJ, Microwave Enhanced Chemistry, Amer. Chem. Soc., Washington DC (1997)
Berteaud AJ, Badot JC, J. Microwave Power, 11, 315 (1976)
Tinga WR, MRS Symp. Proc, 124, 33 (1994)
Ford JD, Pei DCT, J. Microwave Power, 2, 61 (1967)
Hippel AV, Dielectric Materials and Applications, Artech House, London (1995)
Perreux L, Loupy A, Tetrahedron, 57, 9199 (2001)
Okress EC, Microwave Power Engineering, Academic Press, New York (1968)
Metaxas AC, Meredith RJ, Industrial Microwave Heating, Peter Peregrinus Lts., London (1993)
Jung KS, Ro JY, Lee JY, Park SS, J. Mater. Sci. Lett., 20, 2203 (2001)
Laverghetta TS, Microwave Materials and Fabrication Techniques, Artech House, London (2000)
Copson DA, Microwave Heating, AVI Publishing Co., Connecticut (1975)
Kashyap SC, Wyslouzil A, J. Microwave Power, 12, 223 (1977)
Chan CT, Reader HC, Understanding Microwave Heating Cavities, Artech House, London (2000)
Luxtron Corporation, 2775 Northwestern Parkway, Santa Clara, CA 95051-0941, USA(www.luxtron.com)
Land Infrared, 10 Friends Lane, Newtown, PA 18940-1814, USA(www.landinst.com)
Raytek Corporation, 1201 Shaffer Road, PO Box 1820, Santa Cruz, CA 95061-1820, USA(www.ravtek.com)
Olmstead WE, Brodwin ME, Int. J. Heat Mass Transf., 40(7), 1559 (1997)
Pert EP, Carmel Y, Birnboim A, Olorunyolemi T, Gershon D, Calame J, Lloyd IK, Wilson OC, J. Am. Ceram. Soc., 84, 1981 (2001)
Binner JGP, Fernie JA, Whitaker PA, Cross TE, J. Mater. Sci., 33(12), 3017 (1998)
Lewis DA, Summers JD, Ward TC, McGrath JE, J. Polym. Sci. A: Polym. Chem., 30, 1647 (1992)
Shibata C, Kashima T, Ohuchi K, Jpn. J. Appl. Phys., 35, 316 (1996)
Kabza KG, Chapados BR, Gestwicki JE, McGrath JL, J. Org. Chem., 65, 1210 (2000)
Langa F, Cruz P, Hoz A, Espildora E, Cossio FP, Lecea B, J. Org. Chem., 65, 2499 (2000)
Raner KD, Strauss CR, J. Org. Chem., 57, 6231 (1992)
Chandra Sheker Reddy A, Shanthan Rao P, Venkataratnam RV, Tetrahedron Lett., 37, 2845 (1996)
Laurent R, Laporterie A, Dubac J, Lefeuvre S, Audhuy M, J. Org. Chem., 57, 7099 (1992)
Tanaka K, Toda F, Chem. Rev., 100(3), 1025 (2000)
Carrillo JR, Diaz-Ortiz A, Cossio FP, Gomez-Escalonilla MJ, Hoz A, Moreno A, Prieto P, Tetrahedron, 50, 1569 (2000)
Hammond GS, J. Am. Chem. Soc., 77, 334 (1955)
Carrillo-Munoz JR, Bouvet D, Guibe-Jampel E, Loupy A, Petit A, J. Org. Chem., 61, 7746 (1996)
Hoz A, Diaz-Ortiz A, Moreno A, Langa F, Eur. J. Org. Chem., 65, 3659 (2000)
Varma RS, Dahiya R, Kumar S, Tetrahedron Lett., 38, 2039 (1997)
Park SS, Hwang EH, Kim BC, Park HC, J. Am. Ceram. Soc., 83, 1341 (2000)
Park SS, Jung KS, Kim BC, Lee SE, Park HC, Glass Technol., 43, 70 (2002)
Park HC, Kim SW, Lee SG, Kim JK, Hong SS, Lee GD, Park SS, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 363, 330 (2003)
Kim SW, Lee SG, Kim JK, Kwon JY, Park HC, Park SS, J. Mater. Sci., 39(4), 1445 (2004)
Jung KS, Kwon JH, Shon SM, Ko JP, Shin JS, Park SS, J. Mater. Sci., 39(2), 723 (2004)
Jung KS, Kwon JH, Son SM, Shin JS, Lee GD, Park SS, Synth. Met., 141, 259 (2004)
