Articles & Issues
- Language
- korean
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received September 22, 2004
Accepted December 10, 2004
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Fe-MCM-41의 제조, 물성조사 및 촉매적 응용 연구
Synthesis, Characterization, and Catalytic Applications of Fe-MCM-41
인하대학교 공과대학 화학공학과, 402-701 인천시 남구 용현동 253 1인하대학교 고분자공학과, 402-701 인천시 남구 용현동 253
School of Chemical Engineering, Inha University, 253, Yonghyun-dong, Nam-gu, Incheon 402-751, Korea 1School of Polymer Engineering, Inha University, 253, Yonghyun-dong, Nam-gu, Incheon 402-751, Korea
whasahn@inha.ac.kr
Korean Chemical Engineering Research, April 2005, 43(2), 215-221(7), NONE Epub 9 May 2005
Download PDF
Abstract
실리카계 메조 물질인 MCM-41의 합성시 Fe3+ 염을 합성 기질에 직접 도입하여 구조 내의 Si를 Fe로 일부 치환시킨 Fe-MCM-41(4 mol% Fe)을 합성하였다. XRD, N2 흡착법, TEM 등으로 합성한 메조 세공 물질의 구조적 특성을 조사하였으며, UV-Vis 및 FT-IR 등의 분광분석을 통하여 철의 상태를 확인하였다. 촉매적 활성 연구를 위하여 과산화수소를 산화제로 이용한 phenol hydroxylation을 수행하였으며, 물을 용매로 반응 온도 50 ℃, phenol:H2O2=1:1 조건에서 ca. 60% 의 전화율을 얻었다. 또한, 구조 중 Fe 활성점을 이용한 탄소 나노 튜브의 성장 가능성을 확인하기 위하여, 아세틸렌가스를 탄소원으로 사용한 thermal-CVD 반응기를 이용하였으며, 다중벽 탄소 나노 튜브를 제조할 수 있었다.
A Fe-containing mesoporous silica (Fe-MCM-41) in which part of Si in the framework was replaced by Fe(Si-O-Fe) has been successfully prepared using Fe3+ salt by a direct synthesis route. Physical properties of the material were characterized by XRD, N2 adsorption, SEM/TEM, UV-vis and FT-IR spectroscopies. Fe-MCM-41 exhibited high catalytic activity in phenol hydroxylation using H2O2 as oxidant, giving phenol conversion of ca. 60% at 50 ℃ [phenol : H2O2 = 1:1, water solvent]. Fe-MCM-41 was also applied to the growth of CNTs, utilizing a thermal-CVD reactor using acetylene gas, which demonstrated that multi-wall CNTs could be prepared efficiently using the Fe-MCM-41 catalyst.
References
Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JC, Nature, 359, 710 (1992)
Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am. Chem. Soc., 114(27), 10834 (1992)
Kang TG, Kim JH, Seo G, Park HC, HWAHAK KONGHAK, 36(3), 364 (1998)
Dai PS, Catal. Today, 26(1), 3 (1995)
Corma A, Martinez A, Martinezsoria V, Monton JB, J. Catal., 153(1), 25 (1995)
Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(23), 548 (1998)
Bagshaw SA, Prouzet E, Pinnavaia TJ, Science, 269(5228), 1242 (1995)
Lee JW, Yoon SH, Hyeon TH, Oh SM, Kim KB, Chem. Commun., 21, 2177 (1999)
Ryoo R, Joo SH, Jun SA, J. Phys. Chem. B, 103(27), 7743 (1999)
Han Y, Xiao FS, Wu S, Sun YY, Meng XJ, Li DS, Lin S, Deng F, Ai XJ, J. Phys. Chem. B, 105(33), 7963 (2001)
Bharat LN, Johnson O, Sridhar K, Chem. Mater., 13(2), 552 (2001)
Suvanto S, Hukkamaki J, Pakkanen TT, Pakkanen TA, Langmuir, 16(9), 4109 (2000)
Samanta S, Giri S, Sastry PU, Mal NK, Manna A, Bhaumik A, Ind. Eng. Chem. Res., 42(3), 3012 (2003)
Kim SW, Son SU, Lee SS, Hyeon TW, Chung YK, Chem. Commun., 21, 2212 (2001)
Xiao FS, Sun JM, Meng XJ, Yu RB, Yuan HM, Jiang DZ, Qiu SL, Xu RR, Appl. Catal. A: Gen., 207(1-2), 267 (2001)
Sun JM, Meng XJ, Shi YH, Wang RW, Feng SH, Jiang DH, Xu RR, Xiao FS, J. Catal., 193(2), 199 (2000)
Ribera A, Arends IWCE, de Vries S, Perez-Ramirez J, Sheldon RA, J. Catal., 195(2), 287 (2000)
Han Y, Meng X, Guan H, Yu Y, Zhao L, Xu X, Yang X, Wu S, Li N, Xiao FS, Microporous Mesoporous Mater., 57(2), 191 (2003)
Wang DA, Liu ZQ, Liu FQ, Ai X, Zhang XT, Cao Y, Yu JF, Wu TH, Bai YB, Li TJ, Tang XY, Appl. Catal. A: Gen., 174(1-2), 25 (1998)
Liu CB, Shan YJ, Yang XG, Ye XK, Wu Y, J. Catal., 168(1), 35 (1997)
Kim WJ, Ahn WS, Catal. Lett., 94(3-4), 187 (2004)
Zhang RY, Amlani I, Baker J, Tresek J, Tsui RK, Fejes P, Nano Lett., 3(6), 731 (2003)
Lim S, Ciuparu D, Pak C, Dobek F, Chen Y, Harding D, Pfefferle L, Haller G, J. Phys. Chem. B, 107(40), 11048 (2003)
Duxiao J, Nongyue H, Yuanying Z, Chunxiang X, Chunwei Y, Zuhong L, Mater. Chem. Phys., 69(1-3), 246 (2001)
Iijima S, Nature, 354, 56 (1991)
Soh HT, Quate CF, Morpurgo AF, Marcus CM, Kong J, Dai H, Appl. Phys. Lett., 75(5), 627 (1999)
Mo YH, Park KS, Park SH, Nahm KS, HWAHAK KONGHAK, 38(5), 683 (2000)
Li WZ, Xie SS, Qian LX, Chang BH, Zou BS, Zhou WY, Zhao RA, Wang G, Science, 274(5293), 1701 (1996)
Yuan ZY, Liu SQ, Chen TH, Wang JZ, Li HX, J. Chem. Soc. Chem. Commun.(9), 973 (1995)
Laurent C, Flahaut E, Peigney A, Rousset A, New J. Chem., 22(11), 1229 (1998)
Terrones M, Hsu WK, Kroto HW, Walton DRM, Topics in Current Chemistry, 199, 189 (1999)
Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am. Chem. Soc., 114(27), 10834 (1992)
Kang TG, Kim JH, Seo G, Park HC, HWAHAK KONGHAK, 36(3), 364 (1998)
Dai PS, Catal. Today, 26(1), 3 (1995)
Corma A, Martinez A, Martinezsoria V, Monton JB, J. Catal., 153(1), 25 (1995)
Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(23), 548 (1998)
Bagshaw SA, Prouzet E, Pinnavaia TJ, Science, 269(5228), 1242 (1995)
Lee JW, Yoon SH, Hyeon TH, Oh SM, Kim KB, Chem. Commun., 21, 2177 (1999)
Ryoo R, Joo SH, Jun SA, J. Phys. Chem. B, 103(27), 7743 (1999)
Han Y, Xiao FS, Wu S, Sun YY, Meng XJ, Li DS, Lin S, Deng F, Ai XJ, J. Phys. Chem. B, 105(33), 7963 (2001)
Bharat LN, Johnson O, Sridhar K, Chem. Mater., 13(2), 552 (2001)
Suvanto S, Hukkamaki J, Pakkanen TT, Pakkanen TA, Langmuir, 16(9), 4109 (2000)
Samanta S, Giri S, Sastry PU, Mal NK, Manna A, Bhaumik A, Ind. Eng. Chem. Res., 42(3), 3012 (2003)
Kim SW, Son SU, Lee SS, Hyeon TW, Chung YK, Chem. Commun., 21, 2212 (2001)
Xiao FS, Sun JM, Meng XJ, Yu RB, Yuan HM, Jiang DZ, Qiu SL, Xu RR, Appl. Catal. A: Gen., 207(1-2), 267 (2001)
Sun JM, Meng XJ, Shi YH, Wang RW, Feng SH, Jiang DH, Xu RR, Xiao FS, J. Catal., 193(2), 199 (2000)
Ribera A, Arends IWCE, de Vries S, Perez-Ramirez J, Sheldon RA, J. Catal., 195(2), 287 (2000)
Han Y, Meng X, Guan H, Yu Y, Zhao L, Xu X, Yang X, Wu S, Li N, Xiao FS, Microporous Mesoporous Mater., 57(2), 191 (2003)
Wang DA, Liu ZQ, Liu FQ, Ai X, Zhang XT, Cao Y, Yu JF, Wu TH, Bai YB, Li TJ, Tang XY, Appl. Catal. A: Gen., 174(1-2), 25 (1998)
Liu CB, Shan YJ, Yang XG, Ye XK, Wu Y, J. Catal., 168(1), 35 (1997)
Kim WJ, Ahn WS, Catal. Lett., 94(3-4), 187 (2004)
Zhang RY, Amlani I, Baker J, Tresek J, Tsui RK, Fejes P, Nano Lett., 3(6), 731 (2003)
Lim S, Ciuparu D, Pak C, Dobek F, Chen Y, Harding D, Pfefferle L, Haller G, J. Phys. Chem. B, 107(40), 11048 (2003)
Duxiao J, Nongyue H, Yuanying Z, Chunxiang X, Chunwei Y, Zuhong L, Mater. Chem. Phys., 69(1-3), 246 (2001)
Iijima S, Nature, 354, 56 (1991)
Soh HT, Quate CF, Morpurgo AF, Marcus CM, Kong J, Dai H, Appl. Phys. Lett., 75(5), 627 (1999)
Mo YH, Park KS, Park SH, Nahm KS, HWAHAK KONGHAK, 38(5), 683 (2000)
Li WZ, Xie SS, Qian LX, Chang BH, Zou BS, Zhou WY, Zhao RA, Wang G, Science, 274(5293), 1701 (1996)
Yuan ZY, Liu SQ, Chen TH, Wang JZ, Li HX, J. Chem. Soc. Chem. Commun.(9), 973 (1995)
Laurent C, Flahaut E, Peigney A, Rousset A, New J. Chem., 22(11), 1229 (1998)
Terrones M, Hsu WK, Kroto HW, Walton DRM, Topics in Current Chemistry, 199, 189 (1999)
