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Received January 18, 2005
Accepted April 1, 2005
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천연가스를 이용한 수소 제조 기술 현황
Status for the Technology of Hydrogen Production from Natural Gas
경상대학교 화학공학과, 공학연구원, 660-701 경남 진주시 가좌동 900
Department of Chemical Engineering, Engineering Research Institute, Gyeongsang National University, 900, Gajwa-dong, Jinju 660-701, Korea
Korean Chemical Engineering Research, June 2005, 43(3), 344-351(8), NONE Epub 7 July 2005
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Abstract
수소에너지는 기존의 석유화학공업의 원료로서 뿐만 아니라 연료전지와 연계하여 소요량이 급속히 증가할 것으로 예측된다. 장기적으로는 재생에너지를 사용한 물 전기분해, 원자력을 이용한 수소 제조가 주목받고 있지만, 안정된 기술이 확보되기까지는 화석연료를 사용한 수소 제조법이 대용량 수소 제조법 중 가장 경제적인 것으로 분석되고 있다. 현재 화석 연료 중 천연가스를 이용한 수증기 개질 수소 제조법이 상업적인 공정으로 채택되고 있으나 CO2 분리 처리 비용이 경제성 평가에 중요한 항목으로 부각되고 있다. 따라서 천연가스를 이용한 수소 제조에도 다양한 공정이 제안되고 있으므로 천연가스를 원료로 한 수소 제조 기술의 개발 현황을 살펴보았다.
Hydrogen energy will be considered one of the most important energy carries for the future not only as raw material of petroleum chemical industry but also as the fuel of the fuel cell. The hydrogen production based upon the water electrolysis system combined renewable energy or atomic power energy is being watched as long-term hydrogen sources. Hydrogen from fossil fuel, especially natural gas steam reforming, is the economical mass production method at this time. But the cost of CO2 reduction is added in the economic analysis of hydrogen production processes. Therefore many different results are suggested from these analyses about old processes, and modified schemes are studying for the efficient development. In this review, status for the technology of hydrogen production from natural gas are summarized.
Keywords
References
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Pena MA, Gomez JP, Fierro JL, Appl. Catal. A: Gen., 144(1-2), 7 (1996)
Steinberg M, Int. J. Hydrog. Energy, 24, 771 (1999)
Scholz WH, Gas Sep. Purif., 7(3), 131 (1993)
Heinzel A, Vogel B, Hubner P, J. Power Sources, 105(2), 202 (2002)
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Hufton JR, Mayorga S, Sircar S, AIChE J., 45(2), 248 (1999)
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Bak IH, Choi WK, Nam SC, Jon SK, Park JH, Lee KH, Rhee WH, Joo TS, Lee TS, Cha WS, Lee DK, Development of CO2 Capture Process with Chemical Dry Sorbent for Pre-combustion Decarbonization. MOST Report MI-0028-00-0005-01A27-00-014-00, KIER-A26611, 96-230 (2003)
Bak YC, Cho KJ, Kim SB, J. of KSEE, 25(5), 595 (2003)
Trimm DL, Catal. Today, 49(1-3), 3 (1999)
Lee JK, Park D, Korean J. Chem. Eng., 15(6), 658 (1998)
Moon KI, Kim CH, Choi JS, Lee SH, Kim YG, Lee JS, HWAHAK KONGHAK, 35(6), 890 (1997)
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Chang JS, Park SE, Roh HS, Park YK, Bull. Korean Chem. Soc., 19(8), 809 (1998)
Osaki T, Masuda H, Mori T, Catal. Lett., 29(1-2), 33 (1994)
Parmon VN, Catal. Today, 35(1-2), 153 (1997)
Wang HY, Ruckenstein E, J. Catal., 199(2), 309 (2001)
Hofstad KH, Hoebink JHBJ, Holmen A, Marin GB, Catal. Today, 40(2-3), 157 (1998)
Matsui N, Nakagawa K, Ikenaga N, Suzuki T, J. Catal., 194(1), 115 (2000)
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Liu ZW, Jun KW, Roh HS, Park SE, Oh YS, Korean J. Chem. Eng., 19(5), 735 (2002)
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Ji YY, Li WZ, Xu HY, Chen YX, Appl. Catal. A: Gen., 213(1), 25 (2001)
Mo L, Zheng X, Chen Y, Fei J, React. Kinet. Catal. Lett., 78(2), 233 (2003)
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Audus H, Kaarstad O, Kowal M, Proceeding of 11th World Hydrogen Energy Conference, Stuttgart, 525-534 (1996)
Donnet JB, Carbon Black, Marcel Dekker, New York, 16 (1976)
Popov RG, Shprilrain EE, Zaytchenko VM, Int. J. Hydrog. Energy, 24(4), 327 (1999)
Park JK, Lee YW, Lee BG, Lim JS, Choi DK, Kim DC, Theor. Appl. Chem. Eng., 8(1), 1509 (2002)
Pohleny JB, Scott NH, "Method of Hydrogen Production by Catalytic Decomposition of a Gaseous Hydrogen Stream", U. S. Patent 3,284,161 (1996)
Pourier MG, Sapundzhiev C, Int. J. Hydrog. Energy, 22(4), 429 (1997)
Muradov N, Int. J. Hydrog. Energy, 18(3), 211 (1993)
Muradov NZ, Energy Fuels, 12(1), 41 (1998)
Kim MH, Lee EK, Jun JH, Han GY, Kong SJ, Lee BK, Lee TJ, Yoon KJ, Korean J. Chem. Eng., 20(5), 835 (2003)
Lynum S, "CO2-free Hydrogen from Hydrocarbons. The Kverner CB&H Process", 5th Annual US Hydrogen Meeting, National Hydrogen Association (1994)
Gaudermack B, Lynum S, Int. J. Hydrog. Energy, 23(12), 1087 (1988)
Steomberg M, "The Carnol Process for CO2 Mitigation from Power Plants and the Transportation Sector", BNL 62835, Brookhaven National Laboratory, Upton, NY, December (1995)
