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- In relation to this article, we declare that there is no conflict of interest.
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Received July 12, 2005
Accepted August 10, 2005
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나노구조물질을 이용한 고체수소저장 기술 동향
Advances in the Technology of Solid State Hydrogen Storage Methods Using Novel Nanostructured Materials
전북대학교 화학공학과, 561-756 전북 전주시 덕진구 덕진동 1가 664-14
National Nanotechnology Integration Center and School of Chemical Engineering and Technology, Chonbuk National University, 664-14 1 Ga, Duckjin-dong, Duckjin-gu, Jeonju, Jeonbuk 561-756, Korea
nahmks@chonbuk.ac.kr
Korean Chemical Engineering Research, August 2005, 43(4), 439-451(13), NONE Epub 26 September 2005
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Abstract
수소저장기술은 수소경제를 달성하기 위해 개발해야할 핵심요소기술이다. 이 논문에서는 고체수소저장기술의 최신 개발 동향을 고찰하였다. 나노구조 탄소계 물질(nanostructured carbon materials), 유기금속구조물(metal organic framework, MOFs), 금속수소화물(metal hydrides), 클래스레이트수화물(clathrate hydrates), 금속착수소화물(complex chemical hydrides)과 같은 고체수소저장매체를 중점적으로 고찰하였다. 그 결과 지금까지 개발된 고체수소저장재료의 수소저장용량은 고체의 표면적에 비례하여 증가함을 알 수 있었다. 또한 수송용 탑재형 수소저장 응용을 목적으로 안전하면서도 가역적 고밀도 수소저장이 가능한 기능성 신 나노재료의 개발 방향을 제시하였다.
This article provides a panoramic overview of the state-of-the-art technologies in the field of solid-state hydrogen storage method. The emerging solid-state hydrogen storage techniques, such as nanostructured carbon materials, metal organic framework (MOFs), metal and inter-metal hydrides, clathrate hydrates, complex chemical hydride are discussed. The hydrogen storage capacity of the solid-sate hydrogen storage materials increases in proportion ot the surface area of the solid materials. Also, it is believed that new functional nanostructured materials will offer far-reaching solutions to the development of on-board hydrogen storage system for the application of the transportation vehicles.
Keywords
References
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Bogdanovic B, Schwickardi M, J. Alloy. Compd., 253, 1 (1997)
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ArroyoydeDompablo ME, Ceder G, J. Alloy. Compd., 364, 6 (2004)
Majer G, Stanik E, Valiente Banuet LE, Grinberg F, Kircher O, Fichtner M, J. Alloy. Compd. (2005)
Zuttel A, "Overview and State of the Art", IPHE International Hydrogen Storage Technology Conference, 19-22 June 2005, Lucca, Italy.
Pederson MR, Broughton JQ, Phys. Rev. Lett., 69, 2689 (1992)
Dillon AC, Jones KM, Bekkedahl TA, Kiang CH, Bethune DS, Heben MJ, Nature, 386(6623), 377 (1997)
Hafner JH, Bronikowski MJ, Azamian BR, Nikolaev P, Rinzler AG, Colbert DG, Smith KA, Smalley RE, Chem. Phys. Lett., 296, 195 (1998)
Ding RG, Finnerty JJ, Zhu ZH, Yan ZF, Lu GQ, "Hydrogen Storage by Carbon Nanotubes", in Encyclopedia of Nanoscience and Nanotechnology (Ed. Nalwa H. S.) American Scientific Publishers (2004)
Williams KA, Eklund PC, Chem. Phys. Lett., 320, 352 (2000)
Hirscher M, Becher M, J. Nanosci. Nanotechnol., 3, 3 (2003)
Badzian A, Badzian T, Breval E, Piotrowski A, Thin Solid Films, 398, 170 (2001)
Rajalakshmi N, Dhathathreyan KS, Govindaraj A, Satishkumar BC, Electrochim. Acta, 45(27), 4511 (2000)
Kibria AKMF, Mo YH, Park KS, Nahm KS, Yun MH, Int. J. Hydrog. Energy, 26, 823 (2001)
Nutzenadel C, Zuttel A, Chartouni D, Schlapbach L, Electrochem. Solid State Lett., 2, 30 (1999)
Ahn CC, Ye Y, Ratnakumar BV, Witham C, Bowman CC, Fultz B, Appl. Phys. Lett., 73, 3378 (1998)
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Ye Y, Ahn CC, Witham C, Fultz B, Liu J, Rinzler AG, Colbert D, Smith KA, Smalley RE, Appl. Phys. Lett., 74, 2307 (1999)
Zhang C, Lu X, Gu A, Int. J. Hydrog. Energy, 29, 1271 (2004)
Panella B, Hirscher M, Roth S, Carbon, 43, 2209 (2005)
Lueking A, Yang RT, J. Catal., 206(1), 165 (2002)
Lueking A, Yang RT, AIChE J., 49, 1556 (2004)
Huang WZ, Zhang XB, Tu JP, Kong FZ, Ma JX, Liu F, Lu HM, Chen CP, Mater. Chem. Phys., 78, 144 (2002)
Zacharia R, Kim KY, Kibria AKMF, Nahm KS, Chem. Phys. Lett., 412, 369 (2005)
Yilidirm T, Ciraci S, Phys. Rev. Lett., 94, 175501 (2005)
Xia Y, Zhu JZ, Zhao M, Li F, Huang B, Ji Y, Liu X, Tan Z, Song C, Yin Y, Phys. Rev. B, 71, 075412 (2005)
Liu F, Zhang X, Cheng J, Tu J, Kong F, Huang W, Chen C, Carbon, 41, 2527 (2003)
Orimo S, Matsushima T, Fujii H, Fukunaga T, Majer G, J. Appl. Phys., 90, 1545 (2001)
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Huang L, Wang H, Chen J, Wang Z, Sun J, Zhao D, Yan Y, Microporous Mesoporous Mater., 58, 105 (2003)
Panella B, Hirscher M, Adv. Mater., 17, 538 (2005)
Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, OKeeffe M, Yaghi OM, Science, 300, 1127 (2003)
Yildrim T, Hartman MR, "Direct Observation of Hydrogen Adsorption Sites and Nano-Cage Formation in Metal-Organic Frameworks (MOFs)", Available at http://www.arxive.org
Inerbaev TM, Belosludov VR, Belosludov RV, Sluiter M, Kawazoe Y, Comput. Mater. Sci. (2005)
Schuth F, Nature, 434, 712 (2005)
Nijkamp MG, Raaymakers JEMJ, vanDillen AJ, deJong KP, Appl. Phys. A-Mater. Sci. Process., 72, 619 (2001)
Hirscher M, "Physisorption of Hydrogen in Microporous Materials", IPHE International Hydrogen Storage Technology Conference, 19-22 June 2005, Lucca, Italy.
