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Received December 30, 2004
Accepted May 27, 2005
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반응성 염료 제거를 위한 재생 가능한 흡착제로서 Corynebacterium glutamicum 바이오매스의 이용
Utilization of Corynebacterium glutamicum Biomass as a Regenerable Biosorbent for Removal of Reactive Dyes from Aqueous Solution
전북대학교 환경화학공학부 및 공업기술연구센타, 561-756 전북 전주시 덕진구 덕진동 1가 664-14
Division of Environmental and Chemical Engineering, Chonbuk National University, 664-14 1Ga, Duckjin-dong, Duckjin-gu, Jeonbuk 561-756, Korea
Korean Chemical Engineering Research, August 2005, 43(4), 542-547(6), NONE Epub 27 September 2005
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Abstract
생체흡착은 염색폐수로부터 염료 제거를 위한 현재의 처리방법을 교체 또는 보충할 수 있는 유력한 대안이 되고 있다. 본 연구에서는 수용액으로부터 반응성 염료(Reactive Red 4, Reactive Blue 4)를 제거할 수 있는 생체흡착제로서 아미노산 발효공정에서 발생되고 있는 폐기물인 Corynebacterium glutamicum 바이오매스의 활용 가능성에 대해 평가 하였다. 염료들의 흡착량은 용액 pH가 감소함에 따라 증가하였는데 이는 산성 pH에서 바이오매스의
Biosorption is considered to be a promising alternative to replace or supplement the present methods for the treatment of dye-containing wastewater. In this study, the protonated biomass of Corynebacterium glutamicum was evaluated for its potential to remove two types of reactive dyes (Reactive Red 4, Reactive Blue 4) from aqueous solution. The uptakes of dyes were enhanced with decrease in the solution pH, which was likely because the biomass functional groups increased at acidic pH and the positively charged sites could bind the negatively charged sulfonate group (dye-SO3) of dye molecules. An equilibrium state was practically achieved in 10 hr. The Langmuir sorption model was used for the mathematical description of the sorption equilibrium. The maximum sorption capacities of C. glutamicum biomass for Reactive Red 4 and Reactive Blue 4 were estimated to 112.36 mg/g and 263.16 mg/g at pH 1, and 71.94 mg/g and 155.88 mg/g at pH 3.
References
McMullan G, Meehan C, Conneely A, Kirby N, Robinson T, Nigam P, Banat IM, Marchant R, Smyth WF, Appl. Microbiol. Biotechnol., 56(1-3), 81 (2001)
Mittal AK, Gupta SK, Water Sci. Technol., 34(10), 81 (1996)
Han MH, Kim BS, Ban MH, J. Korean Soc. Wat. Wastewat., 17(1), 145 (2003)
Netpradit S, Thiravetyan P, Towprayoon S, Water Res., 38(1), 71 (2004)
Robinson T, McMullan G, Marchant R, Nigam P, Bioresour. Technol., 77(3), 247 (2001)
Carliell CM, Barclay SJ, Buckley CA, Wat. SA, 22(3), 225 (1996)
Zumriye A, Process Biochem., 40(3-4), 997 (2005)
Slokar YM, MajcenLeMarechal A, Dyes Pigment., 37(4), 355 (1999)
Choy KKH, McKay G, Porter JF, Resour. Conserv. Recycl., 27(1-2), 57 (1999)
Fu YZ, Viraraghavan T, Bioresour. Technol., 79(3), 251 (2001)
Won SW, Choi SB, Chung BW, Park D, Park JM, Yun YS, Ind. Eng. Chem. Res., 43(24), 7865 (2004)
Yun YS, J. Microbiol. Biotechnol., 14(1), 29 (2004)
Yun YS, Volesky B, Environ. Sci. Technol., 37(16), 3601 (2003)
Yun YS, Park D, Park JM, Volesky B, Environ. Sci. Technol., 35(21), 4353 (2001)
Park D, Yun YS, Park JM, Environ. Sci. Technol., 38(18), 4860 (2004)
Park D, Yun YS, Cho HY, Park JM, Ind. Eng. Chem. Res., 43(26), 8226 (2004)
Waranusantigul P, Pokethitiyook P, Kruatrachue M, Upatham ES, Environ. Pollut., 125(3), 385 (2003)
Ozacar M, AyhanSengil I, Process Biochem., 40(2), 565 (2005)
Ho YS Chiang TH, Hsueh YM, Process Biochem., 40(1), 119 (2005)
Silke K, Anja K, Martin J, Water Res., 36(19), 4717 (2002)
Choi SB, Yun YS, Biotechnol. Lett., 26(4), 331 (2004)
Fu YZ, Viraraghavan T, Bioresour. Technol., 82(2), 139 (2002)
Gulnaz O, Kaya A, Matyar F, Arikan B, J. Hazard. Mater., 108(3), 183 (2004)
Netpradit S, Thiravetyan P, Towprayoon S, Water Res., 37(4), 763 (2003)
Morais LC, Freitas OM, Goncalves EP, Vasconcelos LT, Gonzalez CG, Water Res., 33(4), 979 (1999)
Gong R, Ding Y, Li M, Yang C, Liu H, Sun Y, Dyes Pigment., 64(3), 187 (2005)
McKay G, ElGeundi M, Nassar MM, Water Res., 21(12), 1513 (1987)
Nassar MM, Hamoda MF, Radwan GH, Water Sci. Technol., 32(11), 27 (1995)
Nassar MM, Water Sci. Technol., 40(7), 133 (1999)
LOW KS, LEE CK, TAN KK, Bioresour. Technol., 52(1), 79 (1995)
Mittal AK, Gupta SK, Water Sci. Technol., 34(10), 81 (1996)
Han MH, Kim BS, Ban MH, J. Korean Soc. Wat. Wastewat., 17(1), 145 (2003)
Netpradit S, Thiravetyan P, Towprayoon S, Water Res., 38(1), 71 (2004)
Robinson T, McMullan G, Marchant R, Nigam P, Bioresour. Technol., 77(3), 247 (2001)
Carliell CM, Barclay SJ, Buckley CA, Wat. SA, 22(3), 225 (1996)
Zumriye A, Process Biochem., 40(3-4), 997 (2005)
Slokar YM, MajcenLeMarechal A, Dyes Pigment., 37(4), 355 (1999)
Choy KKH, McKay G, Porter JF, Resour. Conserv. Recycl., 27(1-2), 57 (1999)
Fu YZ, Viraraghavan T, Bioresour. Technol., 79(3), 251 (2001)
Won SW, Choi SB, Chung BW, Park D, Park JM, Yun YS, Ind. Eng. Chem. Res., 43(24), 7865 (2004)
Yun YS, J. Microbiol. Biotechnol., 14(1), 29 (2004)
Yun YS, Volesky B, Environ. Sci. Technol., 37(16), 3601 (2003)
Yun YS, Park D, Park JM, Volesky B, Environ. Sci. Technol., 35(21), 4353 (2001)
Park D, Yun YS, Park JM, Environ. Sci. Technol., 38(18), 4860 (2004)
Park D, Yun YS, Cho HY, Park JM, Ind. Eng. Chem. Res., 43(26), 8226 (2004)
Waranusantigul P, Pokethitiyook P, Kruatrachue M, Upatham ES, Environ. Pollut., 125(3), 385 (2003)
Ozacar M, AyhanSengil I, Process Biochem., 40(2), 565 (2005)
Ho YS Chiang TH, Hsueh YM, Process Biochem., 40(1), 119 (2005)
Silke K, Anja K, Martin J, Water Res., 36(19), 4717 (2002)
Choi SB, Yun YS, Biotechnol. Lett., 26(4), 331 (2004)
Fu YZ, Viraraghavan T, Bioresour. Technol., 82(2), 139 (2002)
Gulnaz O, Kaya A, Matyar F, Arikan B, J. Hazard. Mater., 108(3), 183 (2004)
Netpradit S, Thiravetyan P, Towprayoon S, Water Res., 37(4), 763 (2003)
Morais LC, Freitas OM, Goncalves EP, Vasconcelos LT, Gonzalez CG, Water Res., 33(4), 979 (1999)
Gong R, Ding Y, Li M, Yang C, Liu H, Sun Y, Dyes Pigment., 64(3), 187 (2005)
McKay G, ElGeundi M, Nassar MM, Water Res., 21(12), 1513 (1987)
Nassar MM, Hamoda MF, Radwan GH, Water Sci. Technol., 32(11), 27 (1995)
Nassar MM, Water Sci. Technol., 40(7), 133 (1999)
LOW KS, LEE CK, TAN KK, Bioresour. Technol., 52(1), 79 (1995)
