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- In relation to this article, we declare that there is no conflict of interest.
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Received March 20, 2006
Accepted April 14, 2006
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바이오매스를 이용한 6가 크롬의 제거
Removal of Hexavalent Chromium by using Biomass
포항공과대학교 환경공학부/화학공학과, 차세대바이오환경기술연구센터, 790-784 포항시 남구 효자동 산31
Advanced Environmental Biotechnology Research Center, Department of Chemical Engineering/School of EnvironmentalScience and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Nam-gu, Pohang 790-784, Korea
jmpark@postech.ac.kr
Korean Chemical Engineering Research, April 2006, 44(2), 107-113(7), NONE Epub 10 May 2006
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Abstract
6가 크롬은 매우 유독한 중금속이면서도 토양 및 지하수의 주요 오염물질 중 하나이다. 따라서 6가 크롬을 함유한폐수는 자연계에 방류되기 전에 반드시 처리되어야 한다. 이를 위한 한 가지 방법으로 자연계에 풍부하게 존재하는 바이오매스를 이용해 6가 크롬을 제거하는 기술이 최근에 주목을 받고 있다. 즉, 이번 총론에서는 바이오매스에 의한6가 크롬의 제거에 대한 현재까지의 연구 상황 및 향후의 연구 방향에 대해 살펴 보았다. 특히, 이 분야에서 종종 실수하고 있는 부분에 대해 상세히 다룸으로써 관련 연구자들에게 도움을 주고자 하였다.
Not only Cr(VI) is very toxic, but also it is a major pollutant in soil and groundwater. Thus Cr(VI)-con-taining wastewater must be treated before being discharged into the environments. Recently, biosorption technologyusing abundant biomass has been considered as an innovative one for removing Cr(VI) from aqueous solution. In thisreview article, current research and future works on Cr(VI) biosorption were widely described. Particularly, the removalmechanism of Cr(VI) by biomass was described in detail, which has been misunderstood by many researchers until now.
Keywords
References
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Park D, Yun YS, Lee DS, Lim SR, Park JM, J. Hazard. Mater., in press
Park D, Yun YS, Jo JH, Park JM, Water Res., 39(4), 533 (2005)
Park D, Yun YS, Park JM, Process Biochem., 40(7), 2559 (2005)
Park D, Yun YS, Park JM, Ind. Eng. Chem. Res., 45(7), 2405 (2006)
Park D, Yun YS, Park JM, Chemosphere, 63(6), 1060 (2006)
Park D, Yun YS, Park JM, Water Res., in press
Park D, Yun YS, Park JM, J. Hazard. Mater., in press
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Yun YS, Park D, Park JM, Volesky B, Environ. Sci. Technol., 35(21), 4353 (2001)
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Davis TA, Volesky B, Mucci A, Water Res., 37(18), 4311 (2003)
Aksu Z, Process Biochem., 40(3-4), 997 (2005)
Marques MJ, Salvador A, Morales-Rubio A, de la Guardia M, Fresenius J. Anal. Chem., 367(7), 601 (2000)
Seigneur C, Constantinou E, Environ. Sci. Technol., 29(1), 222 (1995)
Barnhart J, Regul. Toxicol. Pharmacol., 26(11), S3 (1997)
Anderson RA, Regul. Toxicol. Pharmacol., 26(11), S35 (1997)
Rudolf E, Cervinka M, ATLA-Altern. Lab. Anim., 33(3), 249 (2005)
Costa M, Toxicol. Appl. Pharmacol., 188(1), 1 (2003)
Bartlett L, Vesilind PA, Environ. Eng. Pol., 1(1), 81 (1998)
Baral A, Engelken RD, Environ. Sci. Pol., 5(2), 121 (2002)
Chen JM, Hao OJ, Crit. Rev. Environ. Sci. Technol., 28(3), 219 (1998)
Dermou E, Velissariou A, Xenos D, Vayenas DV, J. Hazard. Mater., 126(1-3), 78 (2005)
Cheung KH, Gu JD, Chemosphere, 52(9), 1523 (2003)
Guha H, Jayachandran K, Maurrasse F, Chemosphere, 52(1), 175 (2003)
Rothstein A, Frenkel A, Larrabee C, J. Cell. Comp. Physiol., 32, 261 (1948)
Volesky B, “Biosorption of Heavy Metals,” CRC Press, United States (1990)
Aksu Z, Kutsal T, Environ. Technol., 11(10), 979 (1990)
Garnham GW, Green M, J. Ind. Microb., 14(3-4), 247 (1995)
Churchill SA, Walters JV, Churchill PF, J. Environ. Eng., 121(10), 706 (1995)
Kratochvil D, Pimentel P, Volesky B, Environ. Sci. Technol., 32(18), 2693 (1998)
Rapoport AI, Muter OA, Process Biochem., 30(2), 145 (1995)
Pillichshammer M, Pumpel T, Poder R, Eller K, Klima J, Schinner F, BioMetals, 8(2), 117 (1995)
SHARMA DC, FORSTER CF, Bioresour. Technol., 47(3), 257 (1994)
SHARMA DC, FORSTER CF, Bioresour. Technol., 49(1), 31 (1994)
Venkobachar C, Water Sci. Technol., 22(7-8), 319 (1990)
Aksu Z, Kutsal T, Gun S, Environ. Technol., 12(10), 915 (1991)
Chun L, Hongzhang C, Zuohu L, Process Biochem., 39(5), 541 (2004)
Zouboulis AI, Loukidou MX, Matis KA, Process Biochem., 39(8), 909 (2004)
Loukidou MX, Zouboulis AI, Karapantsios TD, Matis KA, Colloids Surf. A: Physicochem. Eng. Asp., 242(1-3), 93 (2004)
Bajpai J, Shrivastava R, Bajpai AK, Colloids Surf. A: Physicochem. Eng. Asp., 236(1-3), 81 (2004)
Babel S, Kurniawan TA, Chemosphere, 54(7), 951 (2004)
Bishnoi NR, Bajaj M, Sharma N, Gupta A, Bioresour. Technol., 91(3), 305 (2004)
Kobya M, Bioresour. Technol., 91(3), 317 (2004)
Garg VK, Gupta R, Kumar R, Gupta RK, Bioresour. Technol., 92(1), 79 (2004)
Melo JS, D'Souza SF, Bioresour. Technol., 92(2), 151 (2004)
Acar FN, Malkoc E, Bioresour. Technol., 94(1), 13 (2004)
Bingol A, Ucun H, Bayhan YK, Karagunduz A, Cakici A, Keskinler B, Bioresour. Technol., 94(3), 245 (2004)
Bayramoglu G, Celik G, Yalcin E, Yilmaz M, Aryca MY, J. Hazard. Mater., 119(1-3), 219 (2005)
Khezami L, Capart R, J. Hazard. Mater., 123(1-3), 223 (2005)
Sahin Y, Ozturk A, Process Biochem., 40(5), 1895 (2005)
Arica MY, Tuzun I, Yalcin E, Ince O, Bayramoglu G, Process Biochem., 40(7), 2351 (2005)
Oguz E, Colloids Surf. A: Physicochem. Eng. Asp., 252(2-3), 121 (2005)
Arica MY, Bayramoglu G, Colloids Surf. A: Physicochem. Eng. Asp., 253(1-3), 203 (2005)
Mohanty K, Jha M, Meikap BC, Biswas MN, Chem. Eng. Sci., 60(11), 3049 (2005)
Tunali S, Kiran I, Akar T, Miner. Eng., 18(7), 681 (2005)
Tewari N, Vasudevan P, Guha BK, Biochem. Eng. J., 23(2), 185 (2005)
Seki H, Suzuki A, Maruyama H, J. Colloid Interface Sci., 281(2), 261 (2005)
Sumathi KMS, Mahimairaja S, Naidu R, Bioresour. Technol., 96(3), 309 (2005)
Karthikeyan T, Rajgopal S, Miranda LR, J. Hazard. Mater., 124(1-3), 192 (2005)
Sarin V, Pant KK, Bioresour. Technol., 97(1), 15 (2006)
Agarwal GS, Bhuptawat HK, Chaudhari S, Bioresour. Technol., 97(7), 949 (2006)
Carmona MER, da Silva MAP, Leite SGF, Process Biochem., 40(2), 779 (2005)
Romero-Gonzalez J, Peralta-Videa JR, Rodriguez E, Ramirez SL, Gardea-Torresdey JL, J. Chem. Thermodyn., 37(4), 347 (2005)
Oliveira EA, Montanher SF, Andrade AD, Nobrega JA, Rollemberg MC, Process Biochem., 40(11), 3485 (2005)
Marshall WE, Wartelle LH, J. Chem. Technol. Biotechnol., 79(11), 1286 (2004)
Ozdemir G, Baysal SH, Appl. Microbiol. Biotechnol., 64(4), 599 (2004)
Ozdemir G, Ceyhan N, Ozturk T, Akirmak F, Cosar T, Chem. Eng. J., 102(3), 249 (2004)
Aoyama M, Kishino M, Jo TS, Sep. Sci. Technol., 39(5), 1149 (2004)
Nakajima A, Baba Y, Water Res., 38(12), 2859 (2004)
Altundogan HS, Process Biochem., 40(3-4), 1443 (2005)
Rojas G, Silva J, Flores JA, Rodriguez A, Ly M, Maldonado H, Sep. Purif. Technol., 44(1), 31 (2005)
Gardea-Torresdey JL, Tiemann KJ, Armendariz V, Bess-Oberto L, Chianelli RR, Rios J, Parsons JG, Gamez G, J. Hazard. Mater., 80(1-3), 175 (2000)
Dambies L, Guimon C, Yiacoumi S, Guibal E, Colloids Surf. A: Physicochem. Eng. Asp., 177(2-3), 203 (2001)
Chun L, Hongzhang C, Zuohu L, Process Biochem., 39(5), 541 (2004)
Zouboulis AI, Loukidou MX, Matis KA, Process Biochem., 39(8), 909 (2004)
Park D, Yun YS, Park JM, Environ. Sci. Technol., 38(18), 4860 (2004)
Park D, Yun YS, Cho HY, Park JM, Ind. Eng. Chem. Res., 43(26), 8226 (2004)
Park D, Yun YS, Park JM, Chemosphere, 60(10), 1356 (2005)
Park D, Yun YS, Jo JH, Park JM, J. Microbiol. Biotechnol., 15(4), 780 (2005)
Park D, Yun YS, Yim KH, Park JM, Bioresour. Technol., in press
Park D, Yun YS, Lee DS, Lim SR, Park JM, J. Hazard. Mater., in press
Park D, Yun YS, Jo JH, Park JM, Water Res., 39(4), 533 (2005)
Park D, Yun YS, Park JM, Process Biochem., 40(7), 2559 (2005)
Park D, Yun YS, Park JM, Ind. Eng. Chem. Res., 45(7), 2405 (2006)
Park D, Yun YS, Park JM, Chemosphere, 63(6), 1060 (2006)
Park D, Yun YS, Park JM, Water Res., in press
Park D, Yun YS, Park JM, J. Hazard. Mater., in press
Park SJ, Jang YS, J. Colloid Interface Sci., 249(2), 458 (2002)
Hu Z, Lei L, Li Y, Ni Y, Sep. Purif. Technol., 31(1), 13 (2003)
Zhao NQ, Wei N, Li JJ, Qiao ZJ, Cui J, He F, Chem. Eng. J., 115(1-2), 133 (2005)