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Received May 15, 2006
Accepted July 13, 2006
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SAPO-34 촉매상에서 디메틸에테르로부터 경질올레핀 제조 및 물의 첨가 효과
Effect of Water Addition on the Conversion of Dimethyl Ether to Light Olefins over SAPO-34
한국화학연구원 신화학연구단, 305-600 대전시 유성구 장동 100
New Chemistry Research Division, Korea Research Institute of Chemical Technology, 100, Jang-dong, Yuseong-gu, Daejeon 305-600, Korea
kwjun@krict.re.kr
Korean Chemical Engineering Research, August 2006, 44(4), 345-349(5), NONE Epub 6 September 2006
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Abstract
SAPO-34 촉매상에서 DME(dimethyl ether) 또는 메탄올로부터 경질 올레핀(에틸렌, 프로필렌, 부텐)을 제조하는 반응을 수행하여, 각각의 올레핀들과 CO, CO2와 같은 부 생성물의 수율을 반응온도와 시간의 흐름에 따라 비교해서 관찰하였다. DME 전환반응은 메탄올 전환반응과 비교하여 볼 때 촉매의 비활성화가 급격히 진행되었다. 물을 첨가할 경우, 올레핀의 수율을 증가와 함께 코크 생성에 의한 촉매의 비활성화가 감소하여 촉매의 수명이 길어짐을 확인하였다.
Conversion of DME (dimethyl ether) or methanol to light olefins (ethylene, propylene, butenes) over SAPO-34 were systematically studied, where it was observed that DME was dehydrated to light olefins and partially converted to by-products such as CO and CO2 at various reaction temperatures on the time-on-stream. SAPO-34 catalyst during the DTO (dimetyl ether-to-olefins) reaction was significantly deactivated compared with MTO (methanol-toolefins) reaction. By addition of water to the reaction feed, the yield to light olefins was not only increased, but the life time of the catalyst was also prolonged by the suppression of the coke formation by steam.
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