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Received January 21, 2008
Accepted April 3, 2008
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회분식반응기에서의 혼합 플라스틱의 저온열분해 kinetics
Kinetics of the Low-temperature Pyrolysis of Mixed Plastics in the Batch Reactor
군산대학교 토목환경공학부, 573-701 전북 군산시 미룡동 산 68 1한서대학교 화학공학과, 356-706 충남 서산시 해미면 대곡리 360 2한경대학교 화학공학과 화학기술연구소, 456-749 경기도 안성시 석정동 67
School of Civil and Environmental Engineering, Kunsan National University, San 68, Miryong-dong, Kunsan, Jeonbuk 573-701, Korea 1Department of Chemical Engineering, Hanseo University, 360, Daegok-ri, Haemi-myon, Seosan, Chungnam 356-706, Korea 2Department of Chemical Engineering (RCCT), Hankyong University, 67, Seokjung-dong, Anseong, Kyonggi 456-749, Korea
wscha@kunsan.ac.kr
Korean Chemical Engineering Research, June 2008, 46(3), 540-544(5), NONE Epub 7 July 2008
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Abstract
혼합플라스틱에 대한 열분해특성실험을 스테인레스 스틸의 회분식 미분반응기에서 수행하였으며, 혼합플라스틱의 혼합비율은 22 wt.% HDPE, 17 wt.% LDPE, 27 wt.% PP, 12 wt.% PS, 16 wt.% ABS, 6 wt.% PVC이었다. 열분해온도는 410~450 oC 이었으며 각 열분해생성물의 수율은 무게측정을 통해 얻었으며, 액상생성물의 분자량분포는 GCSIMDIS 방법을 통해 측정하였다. 혼합플라스틱 열분해의 경우 반응온도와 시간이 증가할수록 고상잔류물의 수율증가와 액상생성물의 수율감소 그리고 액상생성물의 평균 분자량 감소가 두드러졌다. 혼합플라스틱에 포함된 PVC의 약 20%가 염소가스형태로 배출됨을 알 수 있었다. 혼합플라스틱 열분해에서 말단절단의 속도계수인 활성에너지 값은 50.2 kcal/mole 이었다.
Pyrolytic characteristics of mixed plastics containing 22 wt.% HDPE, 17 wt.% LDPE, 27 wt.% PP, 12 wt.% PS, 16 wt.% ABS, 6 wt.% PVC have been studied in the batch-type microreactor of stainless steel. Thermal degradation experiments were performed at temperature of 410~450 oC. The yield of each pyrolytic products were obtained by the weight measurement and molecular weight distribution of pyrolytic liquid products determined by the GC-SIMDIS method. It was shown that the yield and molecular weight of pyrolytic liquid product were decreased with the increase of reaction temperature and time. It was know that 20wt% of PVC composing of the mixed plastics was converted to the gas products of chloride during the pyrolysis process. The chain-end scission rate parameter was determined to be 50.2kcal/mole of mixed plastics by the Arrhenius plot.
References
Environmental Statistics Yearbook, Ministry of Environment (2006)
Nho N, Shin D, Park S, Lee K, Kim K, Jeon S, Cho B, New & Renewable Energy, 2, 118 (2006)
Kim SJ, Lee CG, Song PS, Yun JS, Kang Y, Kim JS, Choi MJ, J. Korean Ind. Eng. Chem., 14(5), 634 (2003)
Westerhout RW, Waanders J, Kuipers JA, Vanswaaij WP, Ind. Eng. Chem. Res., 36(6), 1955 (1997)
Sezgi NA, Cha WS, Smith JM, McCoy BJ, Ind. Eng. Chem. Res., 37(7), 2582 (1998)
Kodera Y, McCoy BJ, J. Jpn. Petrol. Inst., 46, 155 (2003)
Schneider HA, Degradation and Stabilization of Polymers, Vol. 1, Jellinek H. H. G.(Eds.), Elsevier Science Publishing Co., New York, 506-526 (1983)
Madras G, Smith JM, Mccoy BJ, Ind. Eng. Chem. Res., 35(6), 1795 (1996)
Ishihara Y, Nanbu H, Ikemura T, Takesue T, Fuel, 69, 978 (1990)
Wang M, Smith JM, Mccoy BJ, AIChE J., 41(6), 1521 (1995)
Kim S, Jang H, Cha W, Journal of the Korea Academia-Industrial Cooperation Society, 8(3), 632 (2007)
Brebu M, Bhaskar T, Murai K, Muto A, Sakata Y, Uddin MA, Fuel, 83, 2021 (2004)
Wu C, Chang C, Hor J, Shih S, Chen L, Chang F, Waste Manage., 13, 221 (1993)
Nho N, Shin D, Park S, Lee K, Kim K, Jeon S, Cho B, New & Renewable Energy, 2, 118 (2006)
Kim SJ, Lee CG, Song PS, Yun JS, Kang Y, Kim JS, Choi MJ, J. Korean Ind. Eng. Chem., 14(5), 634 (2003)
Westerhout RW, Waanders J, Kuipers JA, Vanswaaij WP, Ind. Eng. Chem. Res., 36(6), 1955 (1997)
Sezgi NA, Cha WS, Smith JM, McCoy BJ, Ind. Eng. Chem. Res., 37(7), 2582 (1998)
Kodera Y, McCoy BJ, J. Jpn. Petrol. Inst., 46, 155 (2003)
Schneider HA, Degradation and Stabilization of Polymers, Vol. 1, Jellinek H. H. G.(Eds.), Elsevier Science Publishing Co., New York, 506-526 (1983)
Madras G, Smith JM, Mccoy BJ, Ind. Eng. Chem. Res., 35(6), 1795 (1996)
Ishihara Y, Nanbu H, Ikemura T, Takesue T, Fuel, 69, 978 (1990)
Wang M, Smith JM, Mccoy BJ, AIChE J., 41(6), 1521 (1995)
Kim S, Jang H, Cha W, Journal of the Korea Academia-Industrial Cooperation Society, 8(3), 632 (2007)
Brebu M, Bhaskar T, Murai K, Muto A, Sakata Y, Uddin MA, Fuel, 83, 2021 (2004)
Wu C, Chang C, Hor J, Shih S, Chen L, Chang F, Waste Manage., 13, 221 (1993)
