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Received April 3, 2008
Accepted May 3, 2008
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Nano-Bio 융합 연구를 위한 콜로이드 공학
Colloidal Engineering for Nano-Bio Fusion Research
Jun Hyuk Moon
Gi-Ra Yi1
Sang-Yup Lee2
Jae-Hyun So3
Young-Seok Kim4
Yeo-Kyun Yoon1
Young-Sang Cho5
Seung-Man Yang6†
서강대학교 화공생명공학과, 121-742 서울시 마포구 신수동 1 1한국기초과학지원연구원 서울센터, 136-713 서울시 성북구 인촌로 56 2연세대학교 화공생명공학과, 120-749 서울시 서대문구 신촌동 134 3특허청, 302-701 대전광역시 서구 선사로 139 정부대전청사 4전자부품연구원, 463-816 경기도 성남시 분당구 야탑동 68 5삼성종합기술원, 446-712 경기도 용인시 농서동 산 14 6한국과학기술원 생명화학공학과, 305-701 대전시 유성구 구성동 373-1
Department of Chemical and Biomolecular Engineering, Sogang University, 1 Shinsu-dong, Mapo-gu, Seoul 121-742, Korea 1Korea Basic Science Institute, 56 Inchon St. Sungbuk-Gu, Seoul 136-713, Korea 2Department of Chemical and Biomolecular Engineering, Yonsei University, 134 Shinchon-dong, Seodaemun-gu, Seoul 120-749, Korea 3Korea Intellectual Property Office, 139 Seonsaro, Seogu, Daejeon 302-701, Korea 4Information Display Research Center, Korea Electronics Technology Institute, 68 Yatap-dong, Bundang-gu, Gyunggi-do 463-816, Korea 5Samsung Advanced Institute of Technology, San 14, Nong-seo dong, Giheung-gu, Yongin, Gyungki 449-711, Korea 6Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701, Korea
Korean Chemical Engineering Research, August 2008, 46(4), 647-659(13), NONE Epub 10 September 2008
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Abstract
콜로이드는 거시적으로 균일한 성질을 갖는 입자분산계이다. 콜로이드 입자는 다양한 입자분산계의 모델로서 많은 기초연구가 이루어져 왔을 뿐만 아니라, 산업적으로 다양하게 응용이 되었다. 최근에는 나노-바이오 관련 연구에 적용되어 새롭게 각광을 받고 있는 나노 소재중 하나이다. 본 총설에서는 입자 분산계의 정의 및 분류에 대해 간략히 기술하고, 나노-바이오 응용을 위한 표면 성질 및 표면 개질방법에 대해 다룰 것이다. 또한, 기존의 구형의 입자분산계에서 더 나아가, 모양과 크기가 제어된 입자 분산계의 합성에 관한 최근 결과를 소개하였다. 마지막으로, 콜로이드 입자의 나노-바이오 응용분야로서, 금속 콜로이드 잉크와, 3차원 콜로이드 결정을 활용한 나노-바이오 센서, 및 2차원 콜로이드 구조를 이용한 패턴제작과 응용 연구에 대해 살펴보았다.
Colloids are a heterogeneous system in which particles of a few nanometers to hundreds micrometers in size are finely dispersed in liquid medium, but show homogeneous properties in macroscopic scale. They have attracted much attention not only as model systems of natural atomic and molecular self-assembled structures but also as novel structural materials of practical applications in a wide range of areas. In particular, recent advances in colloidal science have focused on nano-bio materials and devices which are essential for drug discovery and delivery, diagnostics and biomedical applications. In this review, first we introduce nano-bio colloidal systems and surface modification of colloidal particles which creates various functional groups. Then, various methods of fabrication of colloidal particles using holographic lithography, microfluidics and virus templates are discussed in detail. Finally, various applications of colloids in metal inks, three-dimensional photonic crystals and two-dimensional nanopatterns are also reviewed as representative potential applications.
Keywords
References
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Huh YM, Jun YW, Song HT, Kim S, Choi JS, Lee JH, Yoon S, Kim KS, Shin JS, Suh JS, Cheon J, J. Am. Chem. Soc., 127(35), 12387 (2005)
Coe S, Woo W, Bawendi M, Bulovic V, Nature, 420, 800 (2002)
Kraus T, Malaquin L, Schmid H, Riess W, Spencer ND, Wolf H, Nature Nanotech., 2, 570 (2007)
Hynninen A, Thijssen JHJ, Vermolen ECM, Dijkstra M, van Blaaderen A, Nat. Mater., 6, 202 (2007)
Taton TA, Mirkin CA, Letsinger RL, Science, 289, 1757 (2006)
Bridger K, Fairhurst D, Vincent B, J. Colloid Interface Sci., 68, 190 (1979)
van Helden AK, Jansen JW, Vrij A, J. Colloid Interface Sci., 81, 354 (1981)
Philipse AP, Vrij A, J. Colloid Interface Sci., 128, 121 (1989)
Stober W, Fink A, Bohn E, J. Colloid Interface Sci., 26, 62 (1968)
Pugh RJ, Bergstom L, Marcel Dekker, New York (1994)
Ottewill RH, Rennie AR, Kluwer Academic Publishers, Netherlands (1998)
Kiselv AV, Lygin VI, Wiley, New York (1975)
Jal PK, Patel S, Mishra BK, Talanta, 62, 1005 (2004)
Blitz IP, Blitz JP, Gun’ko VM, Sheeran DJ, Colloids Surf. A: Physicochem. Eng. Asp., 307, 83 (2007)
Grudzien RM, Grabicka BE, Jaroniec M, Colloids Surf. A: Physicochem. Eng. Asp., 300, 235 (2007)
Natan A, Kronik L, Haick H, Tung RT, Adv. Mater., 19(23), 4103 (2007)
Sandstrom P, Akerman B, Langmuir, 20(10), 4182 (2004)
Lee JD, So JH, Yang SM, J. Rheol., 43(5), 1117 (1999)
Caruso F, Wiley-VCH (2004)
Lu Y, Yin YD, Li ZY, Xia YN, Langmuir, 18(20), 7722 (2002)
Kim JW, Larsen RJ, Weitz DA, Adv. Mater., 19(15), 2005 (2007)
Kim JW, Larsen RJ, Weitz DA, J. Am. Chem. Soc., 128(44), 14374 (2006)
Moon JH, Kim AJ, Crocker JC, Yang S, Adv. Mater., 19(18), 2508 (2007)
Dendukuri D, Pregibon DC, Collins J, Hatton TA, Doyle PS, Nat. Mater., 5, 365 (2006)
Pregibon DC, Toner M, Doyle PS, Science, 315, 1393 (2007)
Zhang S, Nat. Biotechnol., 21, 1171 (2003)
Sarikaya M, Tamerler C, Jen AKY, Schulten K, Baneyx F, Nat. Mater., 2, 577 (2003)
Niemeyer C, Angew. Chem.-Int. Edit., 40, 4128 (2001)
Douglas T, Young M, Nature, 393, 152 (1998)
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Shenton W, Douglas T, Young M, Stubbs G, Mann S, Adv. Mater., 11(3), 253 (1999)
Dujardin E, Peet C, Stubbs G, Culver JN, Mann S, Nano Lett., 3, 413 (2003)
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Whaley SR, English DS, Hu EL, Barbara PF, Belcher AM, Nature, 405, 665 (2000)
Nam KT, Kim D, Yoo PJ, Chiang C, Meethong N, Hammond PT, Chiang Y, Belcher AM, Science, 312, 885 (2006)
Lee S, Mao C, Flynn CE, Belcher AM, Science, 296, 892 (2002)
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Baus M, Rull LF, Ryckaert JP, Observation, Prediction and Simulation of Phase Transitions in Complex Fluids: Proceedings of NATO Advanced Study Institute, Varenna, Italy, Kluwer Academic Publishers, Dordrecht (1995)
Lee SY, Culver JN, Harris MT, J. Colloid Interface Sci., 297(2), 554 (2006)
Schulz DL, Curtis CJ, Ginley DS, Electrochem. Solid State Lett., 4(8), c58 (2001)
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Sirringhaus H, Kawase T, Friend RH, Shimoda T, Inbasekaran M, Wu W, Woo EP, Science, 290, 2123 (2000)
Yamada M, Maesaka M, Kurihara M, Sakamoto M, Miyake M, Chem. Commun., 4851 (2005)
Kim JH, Germer TA, Mulholland GW, Ehrman SH, Adv. Mater., 7, 518 (2002)
Xia Y, Sun Y, Science, 13, 2176 (2002)
Esumi K, Tano T, Torigoe K, Meguro K, Chem. Mater., 2, 564 (1990)
Huang HH, Ni XP, Loy GL, Chew CH, Tan KL, Loh FC, Deng JF, Xu GQ, Langmuir, 12(4), 909 (1996)
Kim D, Jeong S, Moon J, Nanotechnology, 17, 4019 (2006)
Kamyshny A, Ben-Moshe M, Aviezer S, Magdassi S, Macromol. Rapid Commun., 26(4), 281 (2005)
Bidoki SM, Lewis DM, Clark M, Vakorov A, Millner PA, McGorman D, J. Micromech. Microeng., 17, 967 (2007)
Shipway AN, Lahav M, Willner I, Adv. Mater., 12(13), 993 (2000)
Jiang P, McFarland MJ, J. Am. Chem. Soc., 126(42), 13778 (2004)
Jiang P, Prasad T, McFarland MJ, Colvin VL, Appl. Phys. Lett., 89, 011908 (2006)
Sun CH, Linn NC, Jiang P, Chem. Mater., 19, 4551 (2007)
Xu X, Goponenko AV, Asher SA, J. Am. Chem. Soc., In press (2008)
Ben-Moshe M, Alexeev V, Asher S, Anal. Chem., 78, 5149 (2006)
Walker JP, Asher SA, Anal. Chem., 77, 1596 (2005)
Alexeev VL, Das S, Finegold DN, Asher SA, Clin. Chem., 50, 2353 (2004)
Shim GH, Han MG, Sharp-Norton JC, Creager SE, Foulger SH, J. Mater. Chem., 18, 594 (2008)
Evanoff DD, Hayes SE, Ying Y, Shim GH, Lawrence JR, Carroll JB, Roeder RD, Houchins JM, Huebner CE, Foulger SH, Adv. Mater., 19(21), 3507 (2007)
Xia JQ, Ying YR, Foulger SH, Adv. Mater., 17(20), 2463 (2005)
Lawrence JR, Shim GH, Jiang P, Han MG, Ying YR, Foulger SH, Adv. Mater., 17(19), 2344 (2005)
Jianzhao L, Heman P, Valdivia C, Kitaev V, Ozin G, Optics Express, 13, 6454 (2005)
Lee SK, Yi GR, Yang SM, Lab Chip, 6, 1171 (2006)
Lee SK, Park SG, Moon JH, Yang SM, Lab Chip, 8, 388 (2008)
Choi CJ, Cunningham BT, Lab Chip, 7, 550 (2007)
Orosco MM, Pacholski C, Miskelly GM, Sailor MJ, Adv. Mater., 18(11), 1393 (2006)
Willets KA, Van Duyne RP, Ann. Rev. Phys. Chem., 58, 267 (2007)
Hicks EM, Lyandres O, Hall WP, Zou S, Glucksberg MR, Van Duyne RP, J. Phys. Chem. C, 111, 4116 (2007)
Zhao J, Zhang X, Yonzon C, Haes AJ, Van Duyne RP, Nanomedicine, 1, 219 (2006)
Shah NC, Lyandres O, Walsh JT, Glucksberg MR, Van Duyne RP, Anal. Chem., 79, 6927 (2007)
Zhang X, Shah NC, Van Duyne RP, Vibrational Spectroscopy, 42, 2 (2006)
Arsenault AC, Clark TJ, von Freymann G, Cademartiri L, Sapienza R, Bertolotti J, Vekris E, Wong S, Kitaev V, Manners I, Wang RZ, John S, Wiersma D, Ozin GA, Nat. Mater., 5, 179 (2006)
