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Received July 8, 2008
Accepted August 2, 2008
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마이크로파로 합성한 주석산화물의 전기화학적 특성
Electrochemical Characterization of Tin Oxide Prepared by Microwave Heating
충북대학교 화학공학부, 361-763 충북 청주시 흥덕구 개신동 12 1KIST 이차전지연구센터, 136-791 서울 성북구 하월곡동 39-1
School of Chemical Engineering, Chungbuk National University, 12 Gaesin-dong, Heungduk-gu, Cheongju 361-763, Korea 1Battery Research Center, KIST, 39-1 Hawolgok-dong, Seongbuk-gu, Seoul 136-791, Korea
nabk@chungbuk.ac.kr
Korean Chemical Engineering Research, December 2008, 46(6), 1119-1123(5), NONE Epub 29 December 2008
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Abstract
마이크로파를 이용하여 주석산화물을 제조한 후에 리튬이온전지의 음극활물질로 사용하였다. 시료들은 마이크로파를 이용하여 가열한 후에 산소분위기에서 300, 500, 700 ℃로 3시간 열처리하였다. 마이크로파로 제조한 주석산화물의 전기화학적인 특성과 가역용량을 고찰하였다. 500 ℃로 가열한 주석산화물이 300 ℃와 700 ℃로 가열한 시료보다 높은 가역용량을 나타내었다. 마이크로파 가열과 전기로 가열을 비교한 결과 마이크로파 가열이 높은 가역용량을 나타내었다. 마이크로파 가열과 500 ℃ 가열한 주석산화물의 경우에 초기 방전용량이 1,500 mAh/g으로 나타났다.
Tin oxide was prepared by microwave heating for anode material of lithium ion battery. The samples were heated at 300, 500 and 700 ℃ for 3h under flowing oxygen after microwave heating. The effect of microwave heating on the electrochemical performance of the manufactured tin oxide and the reversible capacity performance were investigated. Tin oxide heated at 500 ℃ showed higher capacity than those at 300 ℃ and 700 ℃ under microwave heating condition. Comparing microwave and furnace heating, microwave heating condition showed higher capacity. The discharge capacity after microwave heating and 500 ℃ heating showed 1,500 mAh/g.
References
Tatsumi K, Zaghib K, Sawada Y, Abe H, Ohsaki T, J. Electrochem. Soc., 142(4), 1090 (1995)
Jayalakshmi M, Rao MM, Venugopal N, Kim KB, J. Power Sources, 166(2), 578 (2007)
Aboulaich A, Mouyane M, Robert F, Lippens PE, Olivier-Fourcade J, Willmann P, Jumas JC, J. Power Sources, 174, 1224 (2007)
Kim JH, Sohn HJ, Kim H, Jeong G, Choi W, J. Power Sources, 170(2), 456 (2007)
Wan KB, Li SFY, Gao ZQ, Siow KS, J. Power Sources, 75(1), 9 (1998)
Dunlap RA, Small DA, MacNeil DD, Obrovac MN, Dahn JR, J. Alloy Compd., 289, 135 (1999)
Yang J, Winter M, Besenhard JO, Solid State Ion., 90(1-4), 281 (1996)
Brousse T, Retoux R, Herterich U, Schleich DM, J. Electrochem. Soc., 145(1), 1 (1998)
Wu DS, Han CY, Wang SY, Wu NL, Rusakova IA, Mater. Lett., 53, 155 (2002)
Cho BW, Kim DH, Lee HW, Na BK, Korean J. Chem. Eng., 24(6), 1037 (2007)
Doh CH, Jin BS, Lim JH, Moon SI, Korean J. Chem. Eng., 19(5), 749 (2002)
Krishnakumar T, Pinna N, Prasanna Kumari K, Perumal K, Jayaprakash R, Materials Letters, 62, 3437 (2008)
Wakihara M, Mat. Sci. Eng. R, 33, 109 (2001)
Lee M, Byun D, Jeon BJ, Lee JK, Korean J. Mater. Res., 15(1), 66 (2005)
Jayalakshmi M, Rao MM, Venugopal N, Kim KB, J. Power Sources, 166(2), 578 (2007)
Aboulaich A, Mouyane M, Robert F, Lippens PE, Olivier-Fourcade J, Willmann P, Jumas JC, J. Power Sources, 174, 1224 (2007)
Kim JH, Sohn HJ, Kim H, Jeong G, Choi W, J. Power Sources, 170(2), 456 (2007)
Wan KB, Li SFY, Gao ZQ, Siow KS, J. Power Sources, 75(1), 9 (1998)
Dunlap RA, Small DA, MacNeil DD, Obrovac MN, Dahn JR, J. Alloy Compd., 289, 135 (1999)
Yang J, Winter M, Besenhard JO, Solid State Ion., 90(1-4), 281 (1996)
Brousse T, Retoux R, Herterich U, Schleich DM, J. Electrochem. Soc., 145(1), 1 (1998)
Wu DS, Han CY, Wang SY, Wu NL, Rusakova IA, Mater. Lett., 53, 155 (2002)
Cho BW, Kim DH, Lee HW, Na BK, Korean J. Chem. Eng., 24(6), 1037 (2007)
Doh CH, Jin BS, Lim JH, Moon SI, Korean J. Chem. Eng., 19(5), 749 (2002)
Krishnakumar T, Pinna N, Prasanna Kumari K, Perumal K, Jayaprakash R, Materials Letters, 62, 3437 (2008)
Wakihara M, Mat. Sci. Eng. R, 33, 109 (2001)
Lee M, Byun D, Jeon BJ, Lee JK, Korean J. Mater. Res., 15(1), 66 (2005)
