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Received April 3, 2009
Accepted April 18, 2009
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메탄의 건식 개질을 이용한 이산화탄소의 재활용
Recycle of Carbon Dioxide Using Dry Reforming of Methane
포항공과대학교 화학공학과, 790-784 경북 포항시 남구 효자동 산31
Department of Chemical Engineering, POSTECH, San 31, Hyoja-dong, Nam-gu, Pohang, Gyeongbuk 790-784, Korea
jun2002@postech.ac.kr
Korean Chemical Engineering Research, June 2009, 47(3), 267-274(8), NONE Epub 29 June 2009
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Abstract
온실가스 배출 규제에 따라 이산화탄소 배출 감축은 산업계에서 해결해야 할 가장 중요한 과제 중 하나가 되었다. 이산화탄소는 온실가스 발생원 중 대부분을 차지하며 본 논문에서는 실제 대규모 산업 현장에서의 이산화탄소 배출을 저감하는 직접적인 방안으로 메탄의 이산화탄소 개질 반응을 이용하는 방법을 고찰해 보았다. 강한 흡열 반응 형태인 이 반응에 대해 추가적인 이산화탄소 발생을 피하며 효율적으로 에너지를 공급하기 위해서는 자열 개질 반응을 이용하는 것이 적합한 방법으로 판단된다. 생산된 합성가스는 환원가스로 재활용하거나 화학제품 및 연료의 합성에 활용 할 수 있다.
Considerable attention has been given to developing methodologies to reduce the emission of carbon dioxide from industry to meet strengthened environmental regulations. In this article, recent research trends on dry reforming of methane as an alternative method to reduce CO2 emission from large scale industrial processes are addressed. To efficiently provide the energy needed in this strong endothermic reaction without additional CO2 emission, it seems to be_x000D_
desirable to adopt autothermal reaction mode. The produced synthesis gas could be used as a reducing gas, or a feedstock for synthesis of chemicals and fuels.
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Effendi A, Hellgardt K, Zhang ZG, Yoshida T, Catalysis Communications, 4, 203 (2003)
Chen X, Honda K, Zhang ZG, Appl. Catal. A: Gen., 288(1-2), 86 (2005)
Choudhary VR, Rajput AM, Prabhakar B, Catal. Lett., 32(3-4), 391 (1995)
Choudhary VR, Uphade BS, Mamman AS, Appl. Catal. A: Gen., 168(1), 33 (1998)
Ruckenstein E, Hu YH, Ind. Eng. Chem. Res., 37(5), 1744 (1998)
Song CS, Wei P, Catal. Today, 98(4), 463 (2004)
Choudhary VR, Mondal KC, Choudhary TV, Appl. Catal. A: Gen., 306, 45 (2006)
Larentis AL, de Resende NS, Salim VMM, Pinto JC, Appl. Catal. A: Gen., 215(1-2), 211 (2001)
Souza MMVM, Macedo Neto OIR, Schmal M, Journal of Natural Gas Chemistry, 15, 21 (2006)
Choudhary VR, Mamman AS, J. Chem. Technol. Biotechnol., 73(4), 345 (1998)
Ruckenstein E, Wang HY, Catal. Lett., 73(2-4), 99 (2001)
Ashcroft AT, Cheetham AK, Green MLH, Vernon PDF, Nature, 352, 225 (1991)
Pant B, Stagg-Williams SM, Catalysis Communications, 5, 305 (2004)
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Song CS, Catal. Today, 115(1-4), 2 (2006)
Hu YH, Ruckenstein E, Catal. Rev.-Sci. Eng., 44(3), 423 (2002)
Bradford MCJ, Vannice MA, Catal. Rev.-Sci. Eng., 41(1), 1 (1999)
Hu YH, Ruckenstein E, Bruce CG, Helmut K, Advances in Catalysis, Academic Press, 2097 (2004)
Choudhary TV, Choudhary VR, Angewandte Chemie International Edition, 47, 1828 (2008)
Yagi F, Kanai R, Wakamatsu S, Kajiyama R, Suehiro Y, Shimura M, Catal. Today, 104(1), 2 (2005)
Pena MA, Gomez JP, Fierro JL, Appl. Catal. A: Gen., 144(1-2), 7 (1996)
http://www.ulcos.org/en/
Moon KI, “Carbon Dioxide Reforming of Methane over Nickelbased Catalyst”, Department of Chemical Engineering, Pohang University of Science and Technology, Pohang, 111 (1996)
http://www.gms21.com
Chubb TA, Solar Energy., 24, 341 (1980)
Rostrup-Nielsen J, Trimm DL, Journal of Catalysis, 48, 155 (1977)
Hu YH, Ruckenstein E, Catal. Lett., 43(1-2), 71 (1997)
Snoeck JW, Froment GF, Fowles M, J. Catal., 169(1), 240 (1997)
Ruckenstein E, Wang HY, J. Catal., 205(2), 289 (2002)
Bychkov VY, Tyulenin YP, Korchak VN, Kinetics and Catalysis, 44, 353 (2003)
Sierra Gallego G, Mondrag F, Tatibou JM, Barrault J, Batiot-Dupeyrat C, Catalysis Today, 133, 200 (2008)
Assabumrungrat S, Laosiripojana N, Piroonlerkgul P, J. Power Sources, 159(2), 1274 (2006)
Gadalla AM, Bower B, Chemical Engineering Science., 43, 3049 (1988)
Rostrup-Nielsen JR, Journal of Catalysis., 85, 31 (1984)
Rostrup-Nielsen JR, Calvin HB, John BB, Studies in Surface Science and Catalysis, Elsevier, 85 (1991)
Duprez D, DeMicheli MC, Marecot P, Barbier J, Ferretti OA, Ponzi EN, Journal of Catalysis., 124, 324 (1990)
Li L, Liu BS, Leung JWH, Au CT, Cheung ASC, Catalysis Today, 131, 533 (2008)
Laosiripojana N, Chadwick D, Assabumrungrat S, Chemical Engineering Journal., 138, 264 (2008)
Lima SM, Assaf JM, Pena MA, Fierro JLG, Appl. Catal. A: Gen., 311, 94 (2006)
Choudhary VR, Mondal KC, Mamman AS, J. Catal., 233(1), 36 (2005)
Fei JH, Hou ZY, Zheng XM, Yashima TS, Catal. Lett., 98(4), 241 (2004)
Bouarab R, Akdim O, Auroux A, Cherifi O, Mirodatos C, Appl. Catal. A: Gen., 264(2), 161 (2004)
Mattos LV, Rodino E, Resasco DE, Passos FB, Noronha FB, Fuel Process. Technol., 83(1-3), 147 (2003)
Seok SH, Choi SH, Park ED, Han SH, Lee JS, J. Catal., 209(1), 6 (2002)
Souza MMVM, Aranda DAG, Schmal M, J. Catal., 204(2), 498 (2001)
Xu ZL, Zhen M, Bi YL, Zhen KJ, Appl. Catal. A: Gen., 198(1-2), 267 (2000)
Seok SH, Department of chemical engineering, Pohang University of Science and Technology, Pohang, 133 (2000)
Kaengsilalai A, Luengnaruemitchai A, Jitkarnka S, Wongkasemjit S, J. Power Sources, 165(1), 347 (2007)
Ruckenstein E, Hu YH, Appl. Catal. A: Gen., 133(1), 149 (1995)
Ruckenstein E, Hu YH, Appl. Catal. A: Gen., 154(1-2), 185 (1997)
Tomishige K, Yamazaki O, Chen YG, Yokoyama K, Li XH, Fujimoto K, Catal. Today, 45(1-4), 35 (1998)
Valderrama G, Kiennemann A, Goldwasser MR, Catalysis Today, 133, 142 (2008)
Araujo GCD, Lima SMD, Assaf JM, Pe MA, Fierro JLG, do Carmo Rangel M, Catalysis Today, 133, 129 (2008)
Gallego GS, Mondragon F, Barrault J, Tatibouet JM, Batiot-Dupeyrat C, Appl. Catal. A: Gen., 311, 164 (2006)
Batiot-Dupeyrat C, Gallego GAS, Mondragon F, Barrault J, Tatibou JM, Catalysis Today, 107, 474 (2005)
Guo J, Lou H, Zhu Y, Zheng X, Materials Letters, 57, 4450 (2003)
Hayakawa T, Suzuki S, Nakamura J, Uchijima T, Hamakawa S, Suzuki K, Shishido T, Takehira K, Appl. Catal. A: Gen., 183(2), 273 (1999)
Tomishige K, Nurunnabi M, Maruyama K, Kunimori K, Fuel Process. Technol., 85(8-10), 1103 (2004)
Hou ZY, Gao J, Guo JZ, Liang D, Lou H, Zheng XM, J. Catal., 250(2), 331 (2007)
Souza MMVM, Schmal M, Appl. Catal. A: Gen., 281(1-2), 19 (2005)
Amin NAS, Yaw TC, International Journal of Hydrogen Energy, 32, 1789 (2007)
Liu SL, Xiong GX, Dong H, Yang WS, Appl. Catal. A: Gen., 202(1), 141 (2000)
Tomishige K, Kanazawa S, Suzuki K, Asadullah M, Sato M, Ikushima K, Kunimori K, Appl. Catal. A: Gen., 233(1-2), 35 (2002)
Choudhary VR, Mondal KC, Choudhary TV, Fuel, 85, 2484 (2006)
Choudhary VR, Mondal KC, Choudhary TV, Energy Fuels, 20(5), 1753 (2006)
Wei W, Stagg-Williams SM, Noronha FB, Mattos LV, Passos FB, Catal. Today, 98(4), 553 (2004)
Tomishige K, Matsuo Y, Yoshinaga Y, Sekine Y, Asadullah M, Fujimoto K, Appl. Catal. A: Gen., 223(1-2), 225 (2002)
O'Connor AM, Ross JRH, Catal. Today, 46(2-3), 203 (1998)
Mo LY, Zheng XM, Chan YH, Fei JH, React. Kinet. Catal. Lett., 78(2), 233 (2003)
Mo LY, Fei JH, Huang CJ, Zheng XM, J. Mol. Catal. A-Chem., 193(1-2), 177 (2003)
Jing QS, Lou H, Mo LY, Fei JH, Zheng XM, React. Kinet. Catal. Lett., 83(2), 291 (2004)
Guo JJ, Lou H, Zhao H, Chai DF, Zheng XM, Appl. Catal. A: Gen., 273(1-2), 75 (2004)
Gao J, Guo J, Liang D, Hou Z, Fei J, Zheng X, International Journal of Hydrogen Energy, 33, 5493 (2008)
Matsuo Y, Yoshinaga Y, Sekine Y, Tomishige K, Fujimoto K, Catal. Today, 63(2-4), 439 (2000)
Kunii D, Levenspiel O, Fluidization Engineering, Wiley, New York (1969)
Santos A, Menendez M, Monzon A, Santamaria J, Miro EE, Lombardo EA, J. Catal., 158(1), 83 (1996)
Effendi A, Hellgardt K, Zhang ZG, Yoshida T, Catalysis Communications, 4, 203 (2003)
Chen X, Honda K, Zhang ZG, Appl. Catal. A: Gen., 288(1-2), 86 (2005)
Choudhary VR, Rajput AM, Prabhakar B, Catal. Lett., 32(3-4), 391 (1995)
Choudhary VR, Uphade BS, Mamman AS, Appl. Catal. A: Gen., 168(1), 33 (1998)
Ruckenstein E, Hu YH, Ind. Eng. Chem. Res., 37(5), 1744 (1998)
Song CS, Wei P, Catal. Today, 98(4), 463 (2004)
Choudhary VR, Mondal KC, Choudhary TV, Appl. Catal. A: Gen., 306, 45 (2006)
Larentis AL, de Resende NS, Salim VMM, Pinto JC, Appl. Catal. A: Gen., 215(1-2), 211 (2001)
Souza MMVM, Macedo Neto OIR, Schmal M, Journal of Natural Gas Chemistry, 15, 21 (2006)
Choudhary VR, Mamman AS, J. Chem. Technol. Biotechnol., 73(4), 345 (1998)
Ruckenstein E, Wang HY, Catal. Lett., 73(2-4), 99 (2001)
Ashcroft AT, Cheetham AK, Green MLH, Vernon PDF, Nature, 352, 225 (1991)
Pant B, Stagg-Williams SM, Catalysis Communications, 5, 305 (2004)
