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Received September 6, 2010
Accepted November 9, 2010
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국내 산업 여건을 고려한 CO2 저장 방안으로서 광물 탄산화 기술의 타당성
Feasibility of Mineral Carbonation Technology as a CO2 Storage Measure Considering Domestic Industrial Environment
포항산업과학연구원 CO2 연구단, 790-600 경북 포항시 남구 효자동 산 32번지 포항산업과학연구원
CO2 Project, Research Institute of industrial Science & Technology, San 32, Nam-gu, Hyoja-dong, Pohang-si, Gyeongbuk 790-600, Korea
hdchun@rist.re.kr
Korean Chemical Engineering Research, April 2011, 49(2), 137-150(14), NONE Epub 12 April 2011
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Abstract
CO2를 탄산염의 형태로 고정화하는 광물 탄산화 기술은 CO2 지중 저장의 대안 기술의 하나로 중소규모로 CO2 저장을 실현할 수 있는 기술로 여겨지고 있다. 이 연구에서는 광물 탄산화 기술의 전세계적인 연구 개발 동향을 파악하고, 특히 우리 나라의 지질 및 산업 여건을 고려할 때 CO2 광물 탄산화가 CO2 저감 대책이 될 수 있는지에 대한 기술적 및 경제적 타당성을 검토하였다. 그 결과 국내에서는 연간 1,200만톤 이상의 CO2를 고정화할 수 있는 산업 부산물이 발생하고 있으며, 이를 광물탄산화에 이용한다면 CO2 광물탄산화는 유망한 CO2 저감 방안이 될 수 있을 것으로 기대된다. 이 기술의 경제성 증대를 위해서는 산업 부산물의 전처리, 금속 용출액 및 용출 방법, 고속 탄산화 기술 개발,공정열의 이용 극대화, 생성된 탄산화물의 부가가치 향상 등의 분야에서 향후 추가적인 연구 개발이 필요할 것으로 판단된다.
CO2 mineral carbonation technology, fixation technology of CO2 as carbonates, is considered to be an alternative to the CO2 geological storage technology, which can perform small- or medium-scale CO2 storage. We provide the current R&D status of the mineral carbonation with special emphasis on the technical and economical feasibility of CO2 mineral carbonation taken into consideration of the domestic geological and industrial environment. Given that the domestic industry produces relatively large amount of the industrial by-products, it is expected that the technology play a pivotal role on the CO2 reduction countermeasure, reaching the potential storage capacity to 12Mt-CO2/yr. The economics of the overall process should be improved via the development of advanced technologies on the pretreatment of raw materials, method/solvents for metal extraction, enhanced kinetics of carbonation reactions, heat integration, and the production of highly value-added carbonates.
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Zevenhoven R, Teir S, Eloneva S, Energy, “Heat Optimisation of a Staged Gas-Solid Mineral Carbonation Process for Long-Term CO2 Storage.”, 33(2), 362 (2008)
Iizuka A, Fujii M, Yamasaki A, Yanagisawa Y, Ind. Eng. Chem. Res., “Development of a New CO2 Sequestration Process Utilizing the Carbonation of Waste Cement.”, 43(24), 7880 (2004)
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Kakizawa M, Yamasaki A, Yanagisawa Y, Energy, “A New CO2 Disposal Process via Artificial Weathering of Calcium Silicate Accelerated by Acetic Acid.”, 26(4), 341 (2001)
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Katsuyama Y, Yamasaki A, Iizuka A, Fujii M, Kumagai K, Yanagisawa Y, Env. Progr., “Development of a Process for Producing High-Purity Calcium Carbonate (CaCO3) from Waste Cememt Using Pressurized CO2”, 24(2), 162 (2005)
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Oyamada K, Watanabe K, Okamoto M, Iwata I, JFE Technical Report., “Reproduction Technology of Coral Reefs Using “Marine Block.”" (2009)
Tsutsumi N, Tanaka M, Tasaki T, Amada K, Hisasue O, Yamamoto T, Yamada H, Endoh K, Nippon Steel Technical Report., “Development of Rapid Stabilization Process for Steelmaking Slag.” (2008)
Stolaroff JK, Lowry GV, Keith DW, Energy Conv. Manag., “Using CaO and MgO-Rich Industrial Waste Streams for Carbon Sequestration.", 46(5), 687 (2005)
Richards V, Peaslee K, Smith J, Geological Sequestration of CO2 by Hydrogen Carbonate Formation with Reclaimed Slag, AISI/DOE Technology Roadmap Program for the Steel Industry, Final Report, Missouri University of Science and Technology (2008)
Huijgen WJJ, Comans RNJ, Witkamp GJ, Energy Conv. Manag., “Cost Evaluation of CO2 Sequestration by Aqueous Mineral Carbonation.", 48(7), 1923 (2007)
Druckenmiller ML, Maroto-Valer MM, Fuel Process. Technol., “Carbon Sequestration Using Brine of Adjusted pH to Form Mineral Carbonates.", 86(14-15), 1599 (2005)
Seifritz W, Nature., “CO2 Disposal by Means of Silicates.”, 345, 486 (1990)
Kojima T, Nagamine A, Ueno N, Uemiya S, Energy Conv. Manag., “Absorption and Fixation of Carbon Dioxide by Rock Weathering.”, 38, S461 (1997)
Schuiling RD, Krijgsman P, Climate Change., “Enhanced Weathering: An Effective and Cheap Tool to Sequester CO2.”, 74, 349 (2006)
Pohang University of Science & Technology, Study on the Conversion of CO2 into Calcium Carbonate Using Coli E, Research Institute of Industrial Science & Technology, Research Report, in Korean. (2010)
Bond GM, Stringer J, Brandvold DK, Simsek FA, Medina MG, Egeland G, Energy Fuels, “Development of Integrated System for Biomimetic CO2 Sequestration Using the Enzyme Carbonic Anhydrase.”, 15(2), 309 (2001)
Favre N, Christ ML, Pierre AC, J. Mol. Cat. B: Enzymatic., “Biocatalytic Capture of CO2 with Carbonic Anhydrase and Its Transformation to Solid Carbonate.”, 60, 163 (2009)
Trachtenberg MC, Cowan RM, Smith DA, Horazak DA, Jensen MD, Laumb JD, Vucelic AP, Chen H, Wang L, Wu X, Energy Procedia., “Membrane-Based, Enzyme-Facilitated, Efficient Carbon Dioxide Capture.”, 1(1), 353 (2009)
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Zevenhoven R, Eloneva S, Teir S, Catal. Today, “Chemical Fixation of CO2 in Carbonates: Routes to Valuable Products and Long-Term Storage.”, 115(1-4), 73 (2006)
Roskill Information Sevices, Inc., The Economics of Ground Calcium Carbonate, 3rd Ed., Report [cited 2010 Jun. 28]; Available from: http://www.roskill.com/.
Goff F, Guthrie G, Lipin B, Fite M, Chipera S, Counce D, Kluk E, Ziock H, Evaluation of Ultramafic Deposits in the Eastern United States and Puerto Rico as Sources of Magnesium for Carbon Dioxide Sequestration, Los Alamos National Laboratory (2000)
O'Connor WK, Dahlin DC, Nilsen DN, Walters RP, Turner PC, “Carbon Dioxide Sequestration by Direct Mineral Carbonation with Carbonic Acid,” 25th International Technical Conference on Coal Utilization & Fuel Systems, Clear Water, FL, USA (2000)
O'Connor WK, Dahlin DC, Nilsen DN, Rush GE, Walters RP, Turner PC, “CO2 Storage in Solid Form: A Study of Direct Mineral Carbonation,” Proceedings of the 5th International Conference on Greenhouse Gas Technologies, Cairns, Australia (2000)
Fauth DJ, Soong Y, “Mineral Sequestration Utilizing Industrial by-Products, Residues, and Minerals,” Mineral Sequestration Workshop, National Energy Technology Laboratory (2001)
Reddy KJ, Argyle MD, Viswatej A, Taylor DT, “A Novel Method to Capture and Store Flue Gas Carbon Dioxide (CO2): Accelerated Mineral Carbonation,” IOP Conf. Ser.: Earth Environ. Sci., 6 (2009)
Lackner KS, Duby P, Yegulalp T, Krevor S, Graves C, Integrating Steel Production with Mineral Carbon Sequestration, AISI/DOE Technology Roadmap Program for the Steel Industry, Final Report, Columbia University (2008)
Eloneva S, Teir S, Salminen J, Revitzer K, Kontu K, Forsman AM, Zevenhoven R, Fogelholm CJ, “Pure Calcium Carbonate Product from the Carbonation of a Steelmaking Slag,” 2nd International Conference on Accelerated Carbonation for Environmental and Materials Engineering, Rome, Italy (2008)
Hamelinck CN, Faaij APC, Turkenburg WC, van Bergen F, Pagnier HJM, Barzandji OHM, Wolf KHAA, Ruijg GJ, Energy, “CO2 Enhanced Coalbed Methane Production in the Netherlands.”, 27(7), 647 (2002)
Comans RNJ, Personal Communication(e-mail), (2009)
Research Institute of Innovative Technology for the Earth, Programmatic Approach to the Technology Development of Carbon Dioxide Fixation and Utilization, Research Report, in Japanese. (2009)
Yogo K, Teng Y, Yashima T, Yamada K, Rubin ES, Keith DW, Gilboy CF, Wilson M, Morris T, Gale J, Thambimuthu K, “Development of a New CO2 Fixation/Utilization Process (1): Recovery of Calcium Form Steelmaking Slag and Chemical Fixation of Carbon Dioxide by Carbonation Reaction." Proceedings of the 7th International Conference on Greenhouse Gas Control Technologies, 2427-2430 (2005)
Iizuka A, “Development of a New Total Recycling Process of Waste Concrete with a Carbonic Acid Treatment,” Ph.D. Dissertation, University of Tokyo, Tokyo (2006)
Iizuka A, Yanagisawa Y, Yamasaki A, “Development of a New Recycling Process for Concrete Sludge Generated from Concrete Pole Plant,” AIChE, Nashville, TN, USA (2009)
Wright J, Australian CCS Commercial and R&D Projects, CCS Workshop Tokyo 2007, Tokyo, Japan (2007)
Consulting LKE, An Ideal Portfolio of CCS Projects and Rationale for Supporting Projects, Global CCS Institute (2009)
Korea Institute of Geoscience and Mineral Resources, Planning Study on the Base Building for the Mineral Carbonation Technology, Research Report JP2008-026, in Korean. (2008)
“Building An Ocean Forest Using Steel Slag”, DK Ilbo(http: // www.dkilbo.com), 2010. 2.10 (2010), in Korean.
Teir S, Eloneva S, Fogelholm CJ, Zevenhoven R, Energy, “Dissolution of Steelmaking Slags in Acetic Acid for Precipitated Calcium Carbonate Production.”, 32(4), 528 (2007)
Teir S, Eloneva S, Zevenhoven R, Energy Conv. Manag., “Production of Precipitated Calcium Carbonate from Calcium Silicates and Carbon Dioxide.", 46(18-19), 2954 (2005)
Goldberg P, Romanosky R, Chen ZY, “CO2 Mineral Sequestration Studies in US,” 5th International Conference on Greenhouse Gas Technologies, Cairns Convention Center, Australia (2000)
Goldberg P, “CO2 Mineral Sequestration Studies . Introduction, Issues and Plans,” Workshop on CO2 Sequestration with Minerals (2001)
Takagi M, “Cost Evaluation of CCS Technology and Deployment Scenarios in Japan,” CCS Workshop 2007, Kyoto, Japan (2007)
Kang SG, Development of Technology for CO2 Marine Geological Storage (V), Ministry of Land, Transport, and Maritime Affairs, Annual Evaluation Meeting, in Korean. (2009)
LACKNER KS, WENDY CH, BUTT DP, JOYCE EL, SHARP DH, Energy, “Carbon Dioxide Disposal in Carbonate Minerals.", 20(11), 1153 (1995)
Lackner KS, Butt DP, Wendt CH, Energy Convers.Mgmt., “Progress on Binding CO2 in Mineral Substrates.", 38, 259 (1997)
Teir S, “Fixation of Carbon Dioxide by Producing Carbonates from Minerals and Steelmaking Slags,” Department of Energy Technology, Ph.D. Dissertation, Helsinki University of Technology, Espoo (2008)
Huijgen WJJ, “Carbon Dioxide Sequestration by Mineral Carbonation,” Ph.D. Dissertation, Energy Research Centre of The Netherlands, Petten (2006)
Gerdemann SJ, O’Connor WK, Dahlin DC, Penner LR, Rush H, Env. Sci. Technol., “Ex Situ Aqueous Mineral Carbonation.”, 41, 2587 (2007)
Maroto-Valer MM, Fauth DJ, Kuchta ME, Zhang Y, Andresen JM, Fuel Process. Technol., “Activation of Magnesium Rich Minerals as Carbonation Feedstock Materials for CO2 Sequestration.”, 86(14-15), 1627 (2005)
Park AHA, Fan LS, Chem. Eng. Sci., “CO2 Mineral Sequestration: Physically Activated Dissolution of Serpentine and pH Swing Process.", 59(22-23), 5241 (2004)
Zevenhoven R, Teir S, Eloneva S, Energy, “Heat Optimisation of a Staged Gas-Solid Mineral Carbonation Process for Long-Term CO2 Storage.”, 33(2), 362 (2008)
Iizuka A, Fujii M, Yamasaki A, Yanagisawa Y, Ind. Eng. Chem. Res., “Development of a New CO2 Sequestration Process Utilizing the Carbonation of Waste Cement.”, 43(24), 7880 (2004)
Byeon TB, Lee JY, Kim DY, Lee HH, Kim HS, RIST Journal of R&D., “Carbonation Treatment Technology of Steel Making Slag,” in Korean., 19(1), 3239 (2005)
Kakizawa M, Yamasaki A, Yanagisawa Y, Energy, “A New CO2 Disposal Process via Artificial Weathering of Calcium Silicate Accelerated by Acetic Acid.”, 26(4), 341 (2001)
Maroto-Valer MM, ZhangY, Kuchta ME, Andresen JM, Fauth DJ, Process for Sequestering Carbon Dioxide and Sulphur Dioxide: U.S.A., US Patent No.0002847 (2005)
Blencoe JG, Anovitz LM, Beard JS, Palmer DA, Carbonation of Serpentine for Long-Term CO2 Sequestration, Final Report, Oak Ridge National Laboratory, Project Number: 3210-2024 (2003)
Wendt CH, Butt DP, Lackner KS, Ziock HJ, Greenhouse Gas Control Technologies,, “Thermodynamic Considerations of Using Chlorides to Accelerate the Carbonate Formation from Magnesium Silicates.”, 4, 349 (1999)
Zevenhoven R, Teir S, “Long Term Storage of CO2 as Magnesium Carbonate in Finland,” Thrid Annual Conference on Carbon Capture & Sequestration, Alexandria, VA, USA (2004)
Newall PS, Clarke SJ, Haywood HM, Scholes H, Clarke NR, King PA, Barley RW, CO2 Storage as Carbonate Minerals, International Energy Agency (2000)
Park AHA, Jadhav R, Fan LS, Can. J. Chem. Eng., “CO2 Mineral Sequestration: Chemically Enhanced Aqueous Carbonation of Serpentine.", 81(3-4), 885 (2003)
Yamasaki A, Iizuka A, Kakizawa M, Katsuyama Y, Nakagawa M, Fujii M, Kumagi K, Yanagisawa Y, “Development of a Carbon Sequestration Process by the Carbonation Reaction of Waste Streams Containing Calcium or Magnesium,” Fifth Annual Conference on Carbon Capture & Sequestration., Alexandria, Virginia, USA (2006)
Katsuyama Y, Iizuka A, Yamasaki A, Fujii M, Kumagai K, Yanagisawa Y, Greenhouse Gas Control Technologies., “Development of a New Process of Waste Concrete for CO2 Reduction in Cement Industry.”, 7, 1433 (2005)
Katsuyama Y, Yamasaki A, Iizuka A, Fujii M, Kumagai K, Yanagisawa Y, Env. Progr., “Development of a Process for Producing High-Purity Calcium Carbonate (CaCO3) from Waste Cememt Using Pressurized CO2”, 24(2), 162 (2005)
Research Institute of Industrial Science & Technology, “Feasibility Study on the Project of Technology Development for CO2 Storage uner the Ground,” Research Report, Ministry of Environment, in Korean. (2009)
Oyamada K, Watanabe K, Okamoto M, Iwata I, JFE Technical Report., “Reproduction Technology of Coral Reefs Using “Marine Block.”" (2009)
Tsutsumi N, Tanaka M, Tasaki T, Amada K, Hisasue O, Yamamoto T, Yamada H, Endoh K, Nippon Steel Technical Report., “Development of Rapid Stabilization Process for Steelmaking Slag.” (2008)
Stolaroff JK, Lowry GV, Keith DW, Energy Conv. Manag., “Using CaO and MgO-Rich Industrial Waste Streams for Carbon Sequestration.", 46(5), 687 (2005)
Richards V, Peaslee K, Smith J, Geological Sequestration of CO2 by Hydrogen Carbonate Formation with Reclaimed Slag, AISI/DOE Technology Roadmap Program for the Steel Industry, Final Report, Missouri University of Science and Technology (2008)
Huijgen WJJ, Comans RNJ, Witkamp GJ, Energy Conv. Manag., “Cost Evaluation of CO2 Sequestration by Aqueous Mineral Carbonation.", 48(7), 1923 (2007)
Druckenmiller ML, Maroto-Valer MM, Fuel Process. Technol., “Carbon Sequestration Using Brine of Adjusted pH to Form Mineral Carbonates.", 86(14-15), 1599 (2005)
Seifritz W, Nature., “CO2 Disposal by Means of Silicates.”, 345, 486 (1990)
Kojima T, Nagamine A, Ueno N, Uemiya S, Energy Conv. Manag., “Absorption and Fixation of Carbon Dioxide by Rock Weathering.”, 38, S461 (1997)
Schuiling RD, Krijgsman P, Climate Change., “Enhanced Weathering: An Effective and Cheap Tool to Sequester CO2.”, 74, 349 (2006)
Pohang University of Science & Technology, Study on the Conversion of CO2 into Calcium Carbonate Using Coli E, Research Institute of Industrial Science & Technology, Research Report, in Korean. (2010)
Bond GM, Stringer J, Brandvold DK, Simsek FA, Medina MG, Egeland G, Energy Fuels, “Development of Integrated System for Biomimetic CO2 Sequestration Using the Enzyme Carbonic Anhydrase.”, 15(2), 309 (2001)
Favre N, Christ ML, Pierre AC, J. Mol. Cat. B: Enzymatic., “Biocatalytic Capture of CO2 with Carbonic Anhydrase and Its Transformation to Solid Carbonate.”, 60, 163 (2009)
Trachtenberg MC, Cowan RM, Smith DA, Horazak DA, Jensen MD, Laumb JD, Vucelic AP, Chen H, Wang L, Wu X, Energy Procedia., “Membrane-Based, Enzyme-Facilitated, Efficient Carbon Dioxide Capture.”, 1(1), 353 (2009)
Jeong SK, Lim KS, Kim DH, Lee SW, Lee SH, Korean Ind. Chem. News, “Biomimetic CO2 Capture and Sequestration”, 12(6), 29 (2009)
Zevenhoven R, Eloneva S, Teir S, Catal. Today, “Chemical Fixation of CO2 in Carbonates: Routes to Valuable Products and Long-Term Storage.”, 115(1-4), 73 (2006)
Roskill Information Sevices, Inc., The Economics of Ground Calcium Carbonate, 3rd Ed., Report [cited 2010 Jun. 28]; Available from: http://www.roskill.com/.
Goff F, Guthrie G, Lipin B, Fite M, Chipera S, Counce D, Kluk E, Ziock H, Evaluation of Ultramafic Deposits in the Eastern United States and Puerto Rico as Sources of Magnesium for Carbon Dioxide Sequestration, Los Alamos National Laboratory (2000)
O'Connor WK, Dahlin DC, Nilsen DN, Walters RP, Turner PC, “Carbon Dioxide Sequestration by Direct Mineral Carbonation with Carbonic Acid,” 25th International Technical Conference on Coal Utilization & Fuel Systems, Clear Water, FL, USA (2000)
O'Connor WK, Dahlin DC, Nilsen DN, Rush GE, Walters RP, Turner PC, “CO2 Storage in Solid Form: A Study of Direct Mineral Carbonation,” Proceedings of the 5th International Conference on Greenhouse Gas Technologies, Cairns, Australia (2000)
Fauth DJ, Soong Y, “Mineral Sequestration Utilizing Industrial by-Products, Residues, and Minerals,” Mineral Sequestration Workshop, National Energy Technology Laboratory (2001)
Reddy KJ, Argyle MD, Viswatej A, Taylor DT, “A Novel Method to Capture and Store Flue Gas Carbon Dioxide (CO2): Accelerated Mineral Carbonation,” IOP Conf. Ser.: Earth Environ. Sci., 6 (2009)
Lackner KS, Duby P, Yegulalp T, Krevor S, Graves C, Integrating Steel Production with Mineral Carbon Sequestration, AISI/DOE Technology Roadmap Program for the Steel Industry, Final Report, Columbia University (2008)
Eloneva S, Teir S, Salminen J, Revitzer K, Kontu K, Forsman AM, Zevenhoven R, Fogelholm CJ, “Pure Calcium Carbonate Product from the Carbonation of a Steelmaking Slag,” 2nd International Conference on Accelerated Carbonation for Environmental and Materials Engineering, Rome, Italy (2008)
Hamelinck CN, Faaij APC, Turkenburg WC, van Bergen F, Pagnier HJM, Barzandji OHM, Wolf KHAA, Ruijg GJ, Energy, “CO2 Enhanced Coalbed Methane Production in the Netherlands.”, 27(7), 647 (2002)
Comans RNJ, Personal Communication(e-mail), (2009)
Research Institute of Innovative Technology for the Earth, Programmatic Approach to the Technology Development of Carbon Dioxide Fixation and Utilization, Research Report, in Japanese. (2009)
Yogo K, Teng Y, Yashima T, Yamada K, Rubin ES, Keith DW, Gilboy CF, Wilson M, Morris T, Gale J, Thambimuthu K, “Development of a New CO2 Fixation/Utilization Process (1): Recovery of Calcium Form Steelmaking Slag and Chemical Fixation of Carbon Dioxide by Carbonation Reaction." Proceedings of the 7th International Conference on Greenhouse Gas Control Technologies, 2427-2430 (2005)
Iizuka A, “Development of a New Total Recycling Process of Waste Concrete with a Carbonic Acid Treatment,” Ph.D. Dissertation, University of Tokyo, Tokyo (2006)
Iizuka A, Yanagisawa Y, Yamasaki A, “Development of a New Recycling Process for Concrete Sludge Generated from Concrete Pole Plant,” AIChE, Nashville, TN, USA (2009)
Wright J, Australian CCS Commercial and R&D Projects, CCS Workshop Tokyo 2007, Tokyo, Japan (2007)
Consulting LKE, An Ideal Portfolio of CCS Projects and Rationale for Supporting Projects, Global CCS Institute (2009)
Korea Institute of Geoscience and Mineral Resources, Planning Study on the Base Building for the Mineral Carbonation Technology, Research Report JP2008-026, in Korean. (2008)
“Building An Ocean Forest Using Steel Slag”, DK Ilbo(http: // www.dkilbo.com), 2010. 2.10 (2010), in Korean.
Teir S, Eloneva S, Fogelholm CJ, Zevenhoven R, Energy, “Dissolution of Steelmaking Slags in Acetic Acid for Precipitated Calcium Carbonate Production.”, 32(4), 528 (2007)
Teir S, Eloneva S, Zevenhoven R, Energy Conv. Manag., “Production of Precipitated Calcium Carbonate from Calcium Silicates and Carbon Dioxide.", 46(18-19), 2954 (2005)
Goldberg P, Romanosky R, Chen ZY, “CO2 Mineral Sequestration Studies in US,” 5th International Conference on Greenhouse Gas Technologies, Cairns Convention Center, Australia (2000)
Goldberg P, “CO2 Mineral Sequestration Studies . Introduction, Issues and Plans,” Workshop on CO2 Sequestration with Minerals (2001)
Takagi M, “Cost Evaluation of CCS Technology and Deployment Scenarios in Japan,” CCS Workshop 2007, Kyoto, Japan (2007)
Kang SG, Development of Technology for CO2 Marine Geological Storage (V), Ministry of Land, Transport, and Maritime Affairs, Annual Evaluation Meeting, in Korean. (2009)