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Received October 16, 2011
Accepted December 4, 2011
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세그먼트 관형 SOFC의 제작 및 특성 평가
Fabrication and Property Evaluation of Tubular Segmented-in-Series Solid Oxide Fuel Cell (SOFC)
Ui-Jin Yun1 2
Jong-Won Lee1
Seung-Bok Lee1
Tak-Hyoung Lim1†
Seok-Joo Park1
Rak-Hyun Song1
Dong-Ryul Shin1
Kyoo-Seung Han2
1한국에너지기술연구원 연료전지연구센터, 305-343 대전광역시 유성구 가정로 102 2충남대학교 바이오 응용화학과, 305-343 대전시 유성구 궁동 220
1Fuel Cell Research Center, Korea Institute of Energy Research, 102 Gajung-ro, Yuseong-gu, Daejeon 305-343, Korea 2Department of Fine chemical Engineering and Appilied chemistry, Chungnam National Univ., 220 Gung-dong, Yuseong-gu, Daejeon 305-764, Korea
ddak@kier.re.kr
Korean Chemical Engineering Research, June 2012, 50(3), 562-566(5), NONE Epub 5 June 2012
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Abstract
본 논문에서는 세그먼트 관형 고체산화물 연료전지(SOFC)의 설계 및 제작과 특성 분석을 다루고 있다. 관형 세라믹 지지체는 압출 공정을 통하여 제작하였으며, NiO-YSZ 연료극과 YSZ 전해질은 담금 코팅법을 통해 세라믹 지지체에 코팅하였다. 코팅된 세라믹 지지체를 1,350 ℃에서 5시간 동안 열처리하였으며, 10 μm 미만의 치밀하고, 균열이 없는 YSZ 전해질 층을 얻을 수 있었다. 또한 열처리된 세라믹 지지체에 LSM-YSZ/LSM/LSCF로 구성된 다층 구조 공기극을 담금법으로 코팅하여 1,150 ℃에서 열처리하였다. 세라믹 관형 지지체에 코팅된 세그먼트 SOFC 셀은 Ag-glass 연결재를 사용하여 전기적으로 직렬 연결하였으며, 수소연료 유량과 운전 온도에 따른 세그먼트 SOFC의 성능 변화를 측정하였다.
A novel design of tubular segmented-in-series(SIS) solid oxide fuel cell (SOFC) sub module was presented in this paper. The tubular ceramic support was fabricated by the extrusion technique. The NiO-YSZ anode and the yttria-stabilized zirconia (YSZ) electrolyte were deposited onto the ceramic support by dip coating method. After sintering at 1350 ℃ for 5 h, a dense and crack-free YSZ film was successfully fabricated. Also, the multi-layered cathode composed of LSM-YSZ composite, LSM and LSCF were coated onto the sintered ceramic support by dip coating method and sintered at 1150 ℃. The performance of the tubular SIS SOFC cell and sub module electrically connected by the Ag-glass interconnect was measured and analysed with different fuel flow and operating temperature.
References
Tompsett GA, Finnerty C, Kendall K, Alston T, Sammes NM, J. Power Sources., 86, 376 (2000)
Singhal SC, Solid State Ion., 152, 405 (2002)
Wang JM, Lu Z, Huang XQ, Chen KF, Ai N, Hu JY, Su WH, J. Power Sources, 163(2), 957 (2007)
Sammes NM, Du Y, Bove R, J. Power Sources, 145(2), 428 (2005)
Gardner FJ, Day MJ, Brandon NP, Pashley MN, Cassidy M, J. Power Sources, 86(1-2), 122 (2000)
Costamagna P, Selimovic A, Del Borghi M, Agnew G, Chem. Eng. J., 102(1), 61 (2004)
Lai TS, Barnett SA, J. Power Sources, 147(1-2), 85 (2005)
Yun UJ, Lee JW, Lee SB, Lim TH, Park SJ, Song RH, Han KS, Korean Hydrogen and New Energy Society., 21, 214 (2010)
Lee DS, Lee JH, Kim J, Lee HW, Song HS, Solid State Ion., 166(1-2), 13 (2004)
Wanzenberg E, Tietz F, Kek D, Panjan P, Stover D, Solid State Ion., 164(3-4), 121 (2003)
Serincan MF, Pasaogullari U, Sammes NM, J. Power Sources, 192(2), 414 (2009)
Ding J, Liu J, J. Power Sources, 193(2), 769 (2009)
Singhal SC, Solid State Ion., 152, 405 (2002)
Wang JM, Lu Z, Huang XQ, Chen KF, Ai N, Hu JY, Su WH, J. Power Sources, 163(2), 957 (2007)
Sammes NM, Du Y, Bove R, J. Power Sources, 145(2), 428 (2005)
Gardner FJ, Day MJ, Brandon NP, Pashley MN, Cassidy M, J. Power Sources, 86(1-2), 122 (2000)
Costamagna P, Selimovic A, Del Borghi M, Agnew G, Chem. Eng. J., 102(1), 61 (2004)
Lai TS, Barnett SA, J. Power Sources, 147(1-2), 85 (2005)
Yun UJ, Lee JW, Lee SB, Lim TH, Park SJ, Song RH, Han KS, Korean Hydrogen and New Energy Society., 21, 214 (2010)
Lee DS, Lee JH, Kim J, Lee HW, Song HS, Solid State Ion., 166(1-2), 13 (2004)
Wanzenberg E, Tietz F, Kek D, Panjan P, Stover D, Solid State Ion., 164(3-4), 121 (2003)
Serincan MF, Pasaogullari U, Sammes NM, J. Power Sources, 192(2), 414 (2009)
Ding J, Liu J, J. Power Sources, 193(2), 769 (2009)
