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Received October 23, 2013
Accepted November 24, 2013
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가축 분뇨를 이용한 미생물 연료전지의 특성 및 MEA 열화
Characteristics of Microbial Fuel Cells Using Livestock Waste and Degradation of MEA
Young-Sook Kim
Cheun-Ho Chu
Jae-Jin Jeong1
Myung-Won Ahn1
Il-Chai Na2
Jeong-Hoon Lee2
Kwon-Pil Park1†
(주)ETIS, 415-813 경기도 김포시 고천읍 풍곡리 431-1 1순천대학교 화학공학과, 540-742 전남 순천시 매곡동 315 2(주)CNL Energy, 540-742 전남 순천시 매곡동 315
ETIS Co, 431-1 Punggok-ri, Gochon-eup, Gimpo-si, Gyeonggi 415-813, Korea 1Department of Chemical Engineering, Sunchon National University, 315 Maegok-dong, Suncheon-si, chonnam 540-742, Korea 2CNL Energy Co, 315 Maegok-dong, Suncheon-si, chonnam 540-742, Korea
parkkp@sunchon.ac.kr
Korean Chemical Engineering Research, April 2014, 52(2), 175-181(7), 10.9713/kcer.2014.52.2.175 Epub 1 April 2014
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Abstract
고분자전해질 연료전지용 MEA(Membrane and Electrode Assembly)와 가축분뇨를 이용해 미생물연료전지(MFC)를 구동하였다. 여러 균을 혼합해 MFC를 구동했을 때 개별적으로 구동했을 때보다 높은 개회로전위(OCV)를 나타냈다. 돼지분뇨, 소분뇨, 닭분뇨, 오리 분뇨 중 돼지 분뇨를 이용했을 때 제일 높은 OCV 540mV를 보였다. 그리고 돼지분뇨에서 최고 963mW/m2의 전력이 발생하였다. MFC 구동과정에서 MEA의 Na2+, Ca2+, K+ 이온 및 불순물들에 의한 오염이 MFC의 낮은 성능의 한 원인임을 확인하였다.
Microbial fuel cells (MFC) were operated with livestock wastes and PEMFC (Proton Exchange Membrane Fuel Cells) MEA (Membrane and Electrode Assembly). OCV of MFC with mixtures of microbial was higher than that of MFC with single microbial. MFC using pig wastes showed highest OCV (540 mV) among cow waste, chicken waste and duck waste. And the power density of MFC using pig waste was 963 mW/m2. Contamination of MEA with Na2+, Ca2+, K+ ion and impurities was the one cause for low performance of MFC during operation.
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Du Z, Li H, Gu T, Biotechnol. Adv., 25, 464 (2007)
Kim JR, Min B, Logan BE, Appl. Microbiol. Biotechnol., 68(1), 23 (2005)
Min BK, Kim JR, Oh SE, Regan JM, Logan BE, Water Res., 39, 4961 (2005)
Lee H, Kim T, Sim W, Kim S, Ahn B, Lim T, Park K, Korean J. Chem. Eng., 28(2), 487 (2011)
Song J, Kim S, Ahn B, Ko J, Park K, Korean Chem. Eng. Res., 51(1), 68 (2013)
Pham TH, Boon N, Aelterman P, Clauwaert P, De Schamphelaire L, Vanhaecke L, De Maeyer K, Hofte M, Verstraete W, Rabaey K, Appl. Microbiol. Biotechnol., 77(5), 1119 (2008)
Watanabe K, Manefield M, Lee M, Kouzuma A, Curr. Opin. Biotechnol., 20, 633 (2009)
Liu M, Yuan Y, Zhang LX, Zhuang L, Zhou SG, Ni JR, Bioresour. Technol., 101(6), 1807 (2010)
van Dyk JS, Sakka M, Sakka K, Pletschke BI, Enzyme Microb. Technol., 45(5), 372 (2009)
Amutha KB, Murugesan AG, Renewable Energy, 50, 621 (2013)
Wang W, Wang Z, Lin X, Wang ZW, Fu FF, Talanta, 100, 338 (2012)
Ruan Z, Zhou S, Jiang S, Sund L, Zhaie Y, Wang Y, Chen C, Zhao B, Bioresour. Technol., 147, 477 (2013)
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Cerqueira VS, Hollenbach EB, Maboni F, Vainstein MH, Camargo FAO, Peralba MDR, Bento FM, Bioresour. Technol., 102(23), 11003 (2011)
Morris JM, Jin S, Crimi B, Pruden A, Chem. Eng. J., 146(2), 161 (2009)
Nandy A, Kumar V, Kundu PP, Enzyme Microb. Technol., 53(5), 339 (2013)
Zuo Y, Xing D, Regan JM, Logan BE, Appl. Environ. Microbiol, 74, 3130 (2008)
Lee DJ, Show KY, Wang A, Bioresour. Technol., 136, 697 (2013)
