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- In relation to this article, we declare that there is no conflict of interest.
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Received February 16, 2014
Accepted March 22, 2014
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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재생가능한 바이오매스 자원인 억새로부터 화학중간체 푸르프랄의 생산
Production of Chemical Intermediate Furfural from Renewable Biomass Miscanthus Straw
부경대학교 생물공학과, 608-737 부산광역시 남구 용소로 45
Department of Biotechnology, Pukyong National University, 45 Yongso-ro, Nam-gu, Busan 608-737, Korea
gtjeong@pknu.ac.kr
Korean Chemical Engineering Research, August 2014, 52(4), 492-496(5), 10.9713/kcer.2014.52.4.492 Epub 30 July 2014
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Abstract
본 연구는 재생가능한 목질계 바이오매스 자원인 억새를 이용한 푸르프랄의 생산가능성을 평가하였다. 또한, 억새줄기로부터 푸르프랄의 생산을 위한 반응조건을 찾기 위하여 고/액 비, 반응온도, 촉매량, 그리고 반응시간의 영향을 조사하였다. 최종적으로 억새로부터 1:10의 고/액 비, 반응온도 150 ℃, 3% 황산, 그리고 반응시간 60분의 반응조건에 서 5.1 g/L의 푸르프랄을 생산하였다. 이러한 결과는 재생가능한 자원으로부터 석유를 대체할 수 있는 귀중한 화학물질로 전환할 수 있는 기초 정보를 제공하는 것이다.
In this work, the possibility of Miscanthus as renewable lignocellulosic biomass was evaluated for production of furfural. Also, to find the reaction conditions of furfural production from Miscanthus straw, the effects of solidto-liquid ratio, reaction temperature, catalyst amount, and reaction time were investigated. Finally, 5.1 g/L furfural was produced from Miscanthus straw in the condition of solid-to-liquid ratio at 1:10, reaction temperature at 150 ℃, sulfuric acid at_x000D_
3%, and reaction time of 60 minutes. This result will provide basic knowledge for converting renewable resources into valuable chemicals substituted for fossil fuels.
Keywords
References
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Kang KY, Park DH, Jeong GT, Carbohydr. Polym., 92, 1321 (2013)
Kim JS, Korean Chem. Eng. Res., 51(4), 438 (2013)
Kim TH, Jeon YJ, Oh KK, Kim TH, Korean J. Chem. Eng., 30(6), 1339 (2013)
Yemis O, Mazza G, Bioresour. Technol., 109, 215 (2012)
Vazquez M, Oliva M, Tellez-Luis SJ, Ramirez JA, Bioresour. Technol., 98(16), 3053 (2007)
Mansilla HD, Baeza J, Urzua S, Maturana G, Villasenor J, Duran N, Bioresour. Technol., 66(3), 189 (1998)
Faaij A, Biomass Bioenerg., 32(8), 657 (2008)
Demibras A, Prog. Energy Combust. Sci., 33, 1 (2007)
Jeong GT, Park DH, Appl. Biochem. Biotechnol., 161(1-8), 41 (2010)
Jeong GT, Park DH, Korean Society for Biotechnology and Bioengineering Journal, 26, 341 (2011)
Cha JY, Hanna MA, Industrial Crops and Products, 16, 109 (2002)
The Pacific Northwest National Laboratory (PNNL) and the National Renewable Energy Laboratory (NREL), Top value added chemicals from biomass, volume I - Results of screening for potential candidates from sugars and synthesis gas. http://www.osti.gov/bridge (2004)
Lee SJ, Go S, Jeong GT, Kim SK, Biotechnology and Bioprocess Engineering, 16, 561 (2011)
Han JG, Oh SH, Choi WY, Woong KJ, Seo HB, Jeong KH, Kang DH, Lee HY, KSBB Journal, 25(4), 357 (2010)
Moon YH, Koo BC, Choi YH, Ahn SH, Bark ST, Cha YL, An GH, Kim JK, Suh SJ, Korean Journal of Weed Science, 30(4), 330 (2010)
Seo SG, Lee JE, Jeon SB, Lee BH, Koo BC, Suh SJ, Kim SH, Korean Journal of Plant Biotechnology, 36(4), 320 (2009)
Kang KY, Park DH, Jeong GT, Carbohydr. Polym., 92, 1321 (2013)
Kim JS, Korean Chem. Eng. Res., 51(4), 438 (2013)
Kim TH, Jeon YJ, Oh KK, Kim TH, Korean J. Chem. Eng., 30(6), 1339 (2013)
Yemis O, Mazza G, Bioresour. Technol., 109, 215 (2012)
Vazquez M, Oliva M, Tellez-Luis SJ, Ramirez JA, Bioresour. Technol., 98(16), 3053 (2007)
Mansilla HD, Baeza J, Urzua S, Maturana G, Villasenor J, Duran N, Bioresour. Technol., 66(3), 189 (1998)