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Language: korean

Conflict of Interest: In relation to this article, we declare that there is no conflict of interest.

Publication history: Received March 31, 2014
Accepted May 18, 2014

This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

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4성분계 다중반응증류 공정의 시각화

Visualization of Stage Calculations in Quaternary Reactive Distillation with Multiple Reactions

강도형 이재우^†

Dohyung Kang Jae W. Lee^†

한국과학기술원 생명화학공학과, 305-701 대전시 유성구 대학로 291

Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon 305-701, Korea

jaewlee@kaist.ac.kr

Korean Chemical Engineering Research, December 2014, 52(6), 713-719(7), 10.9713/kcer.2014.52.6.713 Epub 1 December 2014

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Abstract

4성분계 다중반응이 반응증류 탑 내에서 발생할 때 증류거동의 변화를 시각화 방법을 통해 분석하였다. 시각화 방법이란 단순 증류의 물질수지에 각 반응에 의한 벡터를 추가하고 이를 공간상에 표현하는 것으로 각 단에서 혼합물의 조성 변화 및 반응의 진척도를 직관적으로 알 수 있다. 또한 이를 통해 주어진 운전조건에서 필요한 총 단수 및 최적 반응 단의 위치를 결정할 수 있다. 본 연구에서는에틸렌글리콜 (Ethylene glycol) 생산공정을 시각화 방법을 통해 분석 하였다. 제안된 시각화 방법을 사용하여 복잡한 실험이나 공정모사 없이 4성분계 다중반응증류 공정에 대한 타당성 평가 및 분석이 가능하다.

When multiple reactions of quaternary mixtures take place in a reactive distillation column, the behavior of composition trajectory is analyzed by a visual-aided method. By adding additional vectors of multiple reactions and visualizing them in composition space, the composition of each component and extent of each reaction on an arbitrary stage can be easily estimated in terms of the composition trajectory and reaction cascade difference points. Moreover, for a given operating conditions, the number of total stages and position of optimum reaction zone can be determined by the visual-aided method. In this study, ethylene glycol synthesis with a side reaction is taken as an example and analyzed by the proposed graphical method. Through this method, the quaternary reactive distillation with multiple reactions can be analyzed without numerous experiments and simulations.

Keywords

Reactive Distillation Multiple Reactions Ethylene Glycol

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