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Received October 20, 2014
Accepted November 24, 2014
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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고체 산촉매를 이용한 창자파래로부터 환원당 생산에 미치는 인자들의 영향

Effect of Reaction Factors on Reducing Sugar Production from Enteromorpha intestinalis Using Solid Acid Catalyst

1부경대학교 생물공학과, 608-737 부산광역시 남구 용소로 45 2전남대학교 생물공학과, 500-757 광주광역시 북구 용봉로 77 3전남대학교 바이오에너지 및 바이오소재 협동과정, 500-757 광주광역시 북구 용봉로 77
1Department of Biotechnology, Pukyong National University, 45 Yongso-ro, Nam-gu, Busan 608-737, Korea 2Department of Biotechnology and Bioengineering, Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Korea 3Interdisciplinary Program of Graducate School for Bioenergy and Biomaterials, Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Korea
gtjeong@pknu.ac.kr
Korean Chemical Engineering Research, August 2015, 53(4), 478-481(4), 10.9713/kcer.2015.53.4.478 Epub 29 July 2015
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Abstract

본 연구는 거대 녹조류인 창자파래(Enteromorpha intestinalis)를 대상으로 고체 산촉매를 사용하여 환원당을 생산하고자 하였다. 가수분해 반응은 고액비, 촉매량, 반응온도와 반응시간을 대상으로 최적화하였다. 결과적으로 액/고비 7.5, 반응온도 140 oC, 촉매량 15%, 그리고 반응시간 2 hr에서 7.74 g/L의 환원당을 얻었다. 반면에 단지 0.13 g/L의 5-HMF만이 생성되었다. 이로부터 고체 산촉매를 이용한 해양 바이오매스 자원의 가능성을 확인하였다.
In this study, the hydrolysis of green macro-algae Enteromorpha intestinalis using solid acid catalyst was conducted to obtain total reducing sugar. The hydrolysis was optimized with four reaction parameters of liquid-to-solid (L/S) ratio, catalyst amount, reaction temperature, and reaction time. As a optimized result, the highest TRS of 7.74 g/L was obtained under condition of 7.5 L/S ratio, 140 oC, 15% catalyst amount and 2 hr. By the way, at this condition, only 0.13 g/L 5-HMF was detected. The solid acid-catalyzed hydrolysis of marine resources had the potential in the field of bioenergy.

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