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Received December 24, 2014
Accepted February 3, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Cempedak Durian (Artocarpus sp.) Peel as a Biosorbent for the Removal of Toxic Methyl Violet 2B from Aqueous Solution
1Department of Chemistry, Faculty of Science, Universiti Brunei Darussalam, Jalan Tungku Link, Gadong, Brunei Darussalam 2Department of Chemistry, Faculty of Science, University of Peradeniya, Peradeniya, Sri Lanka 3Postgraduate Institute of Science, University of Peradeniya, Peradeniya, Sri Lanka
kiddri86@hotmail.com
Korean Chemical Engineering Research, October 2015, 53(5), 576-583(8), 10.9713/kcer.2015.53.5.576 Epub 12 October 2015
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Abstract
This paper aims to investigate the potential use of cempedak durian peel (CDP) from Negara Brunei Darussalam, which is low-cost, locally available, eco-friendly and highly efficient to remove methyl violet (MV) dye from aqueous solutions. The time required for equilibrium to be reached is 2.0 h with no adjustment of pH necessary. FTIR analysis was indicative of the involvement of -COOH and C=O functional groups in adsorption process. The Langmuir model provided the best fit with maximum adsorption capacity of 0.606 mmol g-1. Thermodynamics data indicate that the adsorption is spontaneous, feasible and endothermic in nature. Best regeneration of CDP’s adsorption ability is achieved by base solution, showing about 95% removal efficiency of MV even after 5 cycles, indicating that CDP can be regenerated and reused. This, together with its high adsorption capacity, makes CDP a potential adsorbent for the removal of MV in wastewater.
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Zehra T, Priyantha N, Lim LBL, Iqbal E, Desalin. Water Treat., 1 (2014)
Chieng HI, Lim LBL, Priyantha N, Desalin. Water Treat., 1 (2014)
Wu YH, Jiang L, Mi XM, Li B, Feng SX, Korean J. Chem. Eng., 28(3), 895 (2011)
Rehman MSU, Munir M, Ashfaq M, Rashid N, Nazar MF, Danish M, Han JI, Chem. Eng. J., 228, 54 (2013)
Lim LBL, Priyantha N, Chan CM, Matassan D, Chieng HI, Kooh MRR, Arab. J. Sci. Eng., 39, 6757 (2014)
Rajaram R, Banu JS, Mathivanan K, Toxicol. Environ. Chem., 95, 590 (2013)
Mao J, Won SW, Min J, Yun YS, Korean J. Chem. Eng., 25(5), 1060 (2008)
Priyantha N, Lim LBL, Dahri MK, Tennakoon DTB, J. Appl. Sci. Environ. Sanitat., 8, 179 (2013)
Bhatti HN, Bajwa II, Hanif MA, Bukhari IH, Korean J. Chem. Eng., 27(1), 218 (2010)
Lim LBL, Priyantha N, Ramli UK, Chieng HI, J. Appl. Phytotechnol. Environ. Sanitat., 3, 65 (2014)
Lafi R, Fradj A, Hafiane A, Hameed BH, Korean J. Chem. Eng., 31(12), 2198 (2014)
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Hameed BH, J. Hazard. Mater., 154(1-3), 204 (2008)
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Vachalkova A, Novotny L, Blesova M, Neoplasma, 43, 113 (1996)
Tang YP, Lim LBL, Wimmer FL, Int. Food. Res. J., 20, 409 (2013)
Lim LBL, Chieng HI, Wimmer FL, ASEAN J. Sci. Technol. Dev., 28, 122 (2011)
Lim LBL, Priyantha N, Ing CH, Dahri MK, Tennakoon DTB, Zehra T, Suklueng M, Desalin. Water Treat., 1 (2013)
Chieng HI, Lim LBL, Priyantha N, Environ. Technol., 36, 86 (2014)
Lim LBL, Priyantha N, Tennakoon DTB, Dahri MK, Envion. Sci. Pollut. Res., 19, 3250 (2012)
Shawabkeh R, Al-Khashman O, Al-Omari H, Shawabkeh A, Environmentalist, 27, 357 (2007)
Ghaedi M, Hossainian H, Montazerozohori M, Shokrollahi A, Shojaipour F, Soylak M, Purkait MK, Desalination, 281, 226 (2011)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
Redlich O, Peterson DL, J. Phys. Chem., 63, 1024 (1959)
Tsai SC, Juang KW, J. Radioanal. Nucl. Chem., 243, 741 (2000)
Weber TW, Chakravorti RK, J. Amer. Inst. Chem. Engrs., 20, 228 (1974)
McKay G, Blair HS, Gardner JR, J. Appl. Polym. Sci., 27, 3043 (1982)
Annadurai G, Juang RS, Lee DJ, J. Hazard. Mater., 92(3), 263 (2002)
Li P, Su YJ, Wang Y, Liu B, Sun LM, J. Hazard. Mater., 179(1-3), 43 (2010)
Cengiz S, Cavas L, Mar. Biotechnol., 6, 728 (2010)
Duran C, Ozdes D, Gundogdu A, Senturk HB, J. Chem. Eng. Data, 56(5), 2136 (2011)
Mane VS, Babu PVV, Desalination, 273(2-3), 321 (2011)
Lagergren S, K. Sven. Vetenskapsakad. Handl., 24, 1 (1898)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Weber W, Morris J, J. Sanit. Eng. Div., 89, 31 (1963)
Boyd GE, Adamson AW, Myers LS, J. Am. Chem. Soc., 69, 2836 (1947)
Li Q, Yue QY, Su Y, Gao BY, Fu L, J. Hazard. Mater., 147(1-2), 370 (2007)
Akkaya G, Ozer A, Process Biochem., 40, 3559 (2005)
Gad HMH, El-Sayed AA, J. Hazard. Mater., 168(2-3), 1070 (2009)
Hu YQ, Guo T, Ye XS, Li Q, Guo M, Liu HN, Wu ZJ, Chem. Eng. J., 228, 392 (2013)
Vilar VJP, Botelho CMS, Boaventura RAR, Process Biochem., 40, 3267 (2005)
Newcombe G, Drikas M, Carbon, 35, 1239 (1997)
Abdallah R, Taha S, Chem. Eng. J., 195, 69 (2012)
Kumar D, Gaur JP, Bioresour. Technol., 102(3), 2529 (2011)
Fernandez ME, Nunell GV, Bonelli PR, Cukierman AL, Bioresour. Technol., 106, 55 (2012)
Chowdhury S, Misra R, Kushwaha P, Das P, Biorem. J., 15, 77 (2011)
