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- In relation to this article, we declare that there is no conflict of interest.
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Received December 23, 2014
Accepted March 27, 2015
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다양한 온도에서 석탄/바이오매스의 혼합 촤-CO2 가스화 반응특성 연구
Kinetic Study of Coal/Biomass Blended Char-CO2 Gasification Reaction at Various temperature
충남대학교 에너지과학기술대학원, 34134 대전광역시 유성구 대학로 99 1한국에너지기술연구원, 34130 대전광역시 유성구 가정로 152
Graduate School of Energy Science and Technology, Chungnam National University, 99, Daehak-ro, Yusung-gu, Daejeon 34134, Korea 1Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeon 34130, Korea
Korean Chemical Engineering Research, December 2015, 53(6), 746-754(9), 10.9713/kcer.2015.53.6.746 Epub 30 November 2015
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Abstract
본 연구는 이온교환법을 통해 Ni촉매를 담지한 저등급 석탄(인도네시아 Eco탄)과 바이오매스(대한민국 상록수)의 혼합물로부터 제조된 촤(char)를 700~900 oC 등온조건에서 온도가 반응속도에 미치는 영향에 대해 알아보았다. Char-CO2 가스화 반응은 700, 750, 800, 850, 900 oC의 온도에서 진행하였으며, 기-고체 반응의 가스화 거동특성을 알아보기 위하여 각각 다른 가정을 갖고 있는 shrinking core model(SCM), volumetric reaction model(VRM), random pore model (RPM), modified volumetric reaction model(MVRM)을 실험결과에 적용하여 비교하였다. Arrhenius equation를 이용하여 Ni-coal/biomass와 Non-catalyst coal/biomass의 활성화에너지를 구하였고 이를 비교하였다.
In this study, we investigated the effects of the temperature on the coal/biomass char-CO2 gasification reaction under isothermal conditions of 700~900 oC using the lignite(Indonesia Eco coal) with biomass (korea cypress). Ni catalysts were impregnated on the coal by the ion-exchange method. Four kinetic models which are shrinking core model (SCM), volumetric reaction model (VRM), random pore model (RPM) and modified volumetric reaction model (MVRM) for gas-solid reaction were applied to the experimental data against the measured kinetic data. The Activation energy of Ni-coal/biomass, non-catalyst coal/biomass Char-CO2 gasification was calculated from the Arrhenius equation.
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Park DK, Kim SD, Lee SH, Lee JG, Bioresour. Technol., 101(15), 6151 (2010)
Umar DF, Usui H, Komoda Y, Fuel, 90(4), 611 (2009)
Hall DO, Energy, 19(8), 711 (1991)
Pan YG, Velo E, Roca X, Manya JJ, Puigjaner L, Fuel, 70(11), 1317 (2000)
Wu CZ, Huang H, Zheng SP, Yin XL, Bioresour. Technol., 83(1), 65 (2002)
Taba LE, Irfan MF, Wan AM, Wan D, Chakrabarti MH, Renew. Sust. Energ. Rev., 16(8), 5584 (2012)
Miccio F, Ruoppolo G, Kalisz S, Andersen L, Morgan TJ, Baxter D, Fuel, 95(22), 45 (2012)
Kim DW, Lee JM, Kim JS, Seon PK, Korean Chem. Eng. Res., 48(1), 58 (2010)
Williams A, Pourkashanian M, Jones JM, Prog. Energy Combust. Sci., 27(6), 587 (2001)
Lee SH, Hyun JS, Rhim YJ, Park YY, Kim SC, Energy Eng., 4(5), 197 (2003)
Corella J, Toledo JM, Molina G, Ind. Eng. Chem. Res., 45(18), 6137 (2006)
Park JY, Lee DK, Hwang SC, Kim SK, Lee SH, Yoon SK, Yoo JH, Lee SH, Rhee YW, Clean Technol., 19(3), 306 (2013)
Walker PL, Shelef M, Anderson RA, Chem. Phys. Carbon, 4(13), 287 (1968)
McKee DW, Carbon, 20(1), 59 (1982)
Ochoa J, Cassanello MC, Bonelli PR, Cukierman AL, Fuel Process. Technol., 74(3), 161 (2001)
Ye DP, Agnew JB, Zhang DK, Fuel, 77(11), 1209 (1998)
Xiao X, Cao J, Meng X, Le LL, Ogawa Y, Sato K, Fuel, 130, 135 (2013)
Li L, Morishita K, Mogi H, Yamasaki K, Takarada T, Fuel, 91(8), 889 (2010)
Roberts DG, Harris DJ, Fuel, 86(17-18), 2672 (2007)
Tomitam A, Yoshida K, Nishiyama Y, Tamai Y, Carbon, 10, 601 (1972)
Tomitam A, Ohtsuka Y, Tamai Y, Fuel, 62, 105 (1983)
Kim DH, Choi SM, Christopher R, Shaddix MG, Fuel, 120(15), 130 (2014)
Lee DK, Kim SK, Hwang SC, Lee SH, Rhee YW, Korean Chem. Eng. Res., 52(4), 544 (2014)
Wen CY, J. Ind. Eng. Chem., 60(9), 34 (1968)
Shida M, Wen CY, AIChE J., 14(2), 311 (1968)
Asaoka S, Sakata Y, Tong C, Int. Chem. Eng., 25(1) (1985)
Bhatia SK, Perlmutter DD, AIChE J., 23(3), 379 (1980)
Kim SH, Rhee YW, “Reforming of Toluene Using Nickelloaded Coal,” 2014.
Choi YK, Moon SH, Lee HI, Lee WY, Rhee HK, Korean Chem. Eng. Res., 30(3), 292 (1992)
Bak YC, Yang HS, Son JE, HWAHAK KONGHAK, 29(3), 323 (1991)
LEE IC, Korean J. Chem. Eng., 4(2), 194 (1987)
Hippo EJ, Jenkins RG, Walker PL, Fuel, 58(5), 338 (1979)
Liu GS, Tate AG, Bryant GW, Wall TF, Fuel, 79(10), 1145 (2000)
Kajitani S, Suzuki N, Ashizawa M, Hara S, Fuel, 85(2), 163 (2006)
Kim YT, Seo DK, Hwang J, Korean Chem. Eng. Res., 49(3), 372 (2011)
Gomez-Barea A, Ollero P, Fernandez-Baco C, Energy Fuels, 20(5), 2202 (2006)
Li S, Cheng Y, Fuel, 74(3), 456 (1995)
Song BH, Jang YW, Byoun YS, Korean Chem. Eng. Res., 41(3), 349 (2003)
Miura K, Aimi M, Naito T, Hashimoto K, Fuel, 65(3), 407 (1986)
Chan FL, Tanksale A, Renew. Sust. Energ. Rev., 38, 428 (2014)
Kim YT, Seo DK, Hwang JH, Korean Society of Combustion, 15(2), 41 (2010)
Zhang LX, Huang JJ, Fang YT, Wang Y, Energy Fuels, 20(3), 1201 (2006)
Tangsathitkulchai C, Junpirom S, Katesa J, Ind. Crop. Prod., 17(1), 13 (2012)
Song BH, Kim SD, Korean Chem. Eng. Res., 72(6), 797 (1993)
Jeong HJ, Park SS, Hwang JH, Fuel, 116(15), 465 (2014)
Kayembe N, Pulsifer AH, Fuel, 55(3), 211 (1976)
Li S, Cheng Y, Fuel, 74(3), 456 (1995)
