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Language: korean

Conflict of Interest: In relation to this article, we declare that there is no conflict of interest.

Publication history: Received January 12, 2016
Accepted January 20, 2016

This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

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수소생산을 위한 해조류 유래 수용액 상 바이오오일의 수증기 개질 반응

Hydrogen Production by Steam Reforming of Aqueous Bio-Oil from Marine Algae

박용범 임한권^1† 우희철^†

Yong Beom Park Hankwon Lim^1† Hee-Chul Woo^†

부경대학교 공과대학 화학공학과, 48547 부산광역시 남구 신선로 365 ¹대구가톨릭대학교 공과대학 신소재화학공학과, 38430 경상북도 경산시 하양읍 하양로 13-13

Department of Chemical Engineering, Pukyong National University, 365, Sinseon-ro, Nam-gu, Busan, 48547, Korea ¹Department of Advanced Materials and Chemical Engineering, Catholic University of Daegu, 13-13, Hayang-ro, Hayang-eup, Gyeongsan, Gyeongbuk, 38430, Korea

hklim@cu.ac.kr

Korean Chemical Engineering Research, February 2016, 54(1), 94-100(7), 10.9713/kcer.2016.54.1.94 Epub 12 February 2016

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Abstract

해조류 유래 급속열분해를 통해 생성된 바이오오일로부터 수소가스를 생산하기 위해 상용 개질 촉매를 사용하여 수증기 개질 반응을 수행하였다. 반응원료로 급속열분해로부터 생성되는 crude 바이오오일의 상분리를 통해 얻어진 수용액상의 바이오오일이 사용되었으며, 상용 개질 촉매(FCR-4-02, POS-7, Cat. A, RUA), 반응온도 및 수증기/탄소(S/C)비율에 따른 수증기 개질 반응의 활성을 비교 연구하였다. 실험 결과 원료의 S/C 비율과 촉매의 구성성분에 따라 반응활성이 크게 달라지는 것이 확인되었으며, 특히 POS-7 촉매를 사용한 1073 K, S/C 비율 10의 조건에서의 수증기 개질 반응에서 가장 높은 수소 수율(70%)이 확인되었다.

Hydrogen production via steam reforming of bio-oil from algal biomass over fast pyrolysis with commercial catalysts was carried out. Aqueous bio-oil obtained by phase separation from a crude oil over fast pyrolysis was used as a reactant and comparison studies for activity over different catalysts (FCR-4-02, POS-7, Cat. A, RUA), reaction temperature, and steam/carbon (S/C) ratios were performed. Experimental results showed that different catalytic activities were observed with different S/C ratios and catalyst composition and the highest hydrogen yield of 70% was obtained with a POS-7 catalyst at a S/C ratio of 10 and 1073 K.

Keywords

Marine Algae Fast Pyrolysis Steam Reforming Nickel Catalyst

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