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Received May 26, 2015
Accepted October 1, 2015
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판상형 Glass-flake를 이용한 내캐비테이션 도료 개발 및 성능평가

Development and Performance Evaluation of Anti-cavitation Paint with a Lamella Glass-flake

성균관대학교 화학공학과 바이오나노융합재료연구센터, 16419 경기도 수원시 장안구 서부로 2066 1(주)비앤비 기술연구소, 11168 경기도 포천시 가산면 가산로 96번길 56 2성균관대학교 화학공학과, 16419 경기도 수원시 장안구 서부로 2066 3한국건설생활환경연구원, 06711 서울특별시 서초구 남부순환로 319길 7
Dept. of Chemical Eng., Sungkyunkwan University, 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi, 16419, Korea 1BNB Technology Reserch Center, 56, Gasan-ro 96beon-gil, Gasan-myeon, Pocheon, Gyeonggi, 11168, Korea 2Korea Conformity Laboratories, 7, Nambusunhwan-ro 319-gil, Seocho-gu, Seoul, 06711, Korea
Korean Chemical Engineering Research, April 2016, 54(2), 145-151(7), 10.9713/kcer.2016.54.2.145 Epub 5 April 2016
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Abstract

유체의 흐름에 의한 부분적 진공현상인 캐비테이션이 재료 표면에 충격을 주어 철강류 표면이 마모되는 현상에 대응하기 위해 판상형 glass-flake를 적용한 내캐비테이션용 도료를 개발하였다. 특히, 가소성이 좋고 내수성이 뛰어난 특성의 NBR (Acrylonitrile-butadiene rubber) 변성 에폭시 수지에 판상형 glass-flake를 필러로 상용하여 유·무기 복합 세라믹 코팅도료를 개발하였다. 특히 glass-flake는 두께는 100~200 nm 정도로 박막형이며, 길이는 20~30 μm 정도의 판상으로 종횡비가 약 200~300배에 달해 마모 및 내식성에 우수한 성능을 나타낸다. 본 도료로 도막형성 후 접착강도, 인장강도, 연신률, 내캐비테이션 성능을 평가한 결과, 인장강도 4.8~6N/mm2 이상, 파단연신률 30%이상, 마식속도 10 mm2/h이하, 복합사이클 내식성시험에서 모두 우수한 성능을 보였다. 특히 내 캐비테이션 성능 평가에서 기존 선진 외국 제품대비 2배 이상의 우수한 성능을 나타내었다.
In response to the cavitation caused by the partial vacuum caused by the fluid flow, a paint was developed by dispersing the lamella-shaped glass-flake in resin for anti-cavitation. This composite paint was developed by using the inorganic filler (lamella shaped glass-flake) and the NBR (Acrylonitrile-butadiene rubber) which was modified epoxy resin. Especially, the glass-flake was a thin film with a thickness of about 100~200 nm and length of about 20~30 μm, the aspect ratio was about 200 to 300 times that of the plate-shaped. So the paint for anti-cavitation have shown excellent performance in corrosion resistance. The results of evaluating anti-cavitation performance was below, tensile strength 4.8~6 N/mm2 or more, rupture elongation 30% or higher, abrasive speed 10 mm2/h or less. In particular, it showed more than twice the superior performance compared to existing advanced foreign products in anti-cavitation performance evaluation.

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