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Received September 9, 2016
Accepted October 7, 2016
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Synthesis of Complex Compounds Ni(II)-Chlorophyll as Dye Sensitizer in Dye Sensitizer Solar Cell (DSSC)
Department of Chemistry, Faculty of Science and Technology, Airlangga University, 60115, Indonesia
handokodarmokoesoemo@gmail.com
Korean Chemical Engineering Research, February 2017, 55(1), 19-26(8), 10.9713/kcer.2017.55.1.19 Epub 1 February 2017
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Abstract
Increasing global energy demand has resulted in an energy crisis. The dye sensitizer solar cell (DSSC) is an alternative source because of its ability to convert the sun’s energy into electrical energy. Our aim was to determine the effect of synthesized Ni(II)-Chlorophyll for enhancing the efficiency of solar cells based DSSC. Complex compound Ni(II)-Chlorophyll was successfully synthesized as a dye sensitizer of Ni(NO3)2·6H2O and chlorophyll ligand with saponification method. Characterization results with spectrophotometer UV-Vis showed that the complex compounds of Ni(II)-Chlorophyll have a maximum wavelength of 295.00 nm, 451.00 and 665.00 nm. The bond between the ligand and metal appears in the vibration Ni-O at wave number 455.2 cm-1. Complex compoun Ni(II)-Chlorophyll has a magnetic moment 7.10 Bohr Magneton (BM). The performance of complex compound Ni(II)-Chlorophyll as a dye sensitizer shows the value of short-circuit current (Jsc) at 3.00 mA/cm2, open circuit voltage (Voc) at 0.15 V and the efficiency (η) 0.20%.
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References
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Maddu A, Zuhri M, Irmansyah I, Makara, 11, 78 (2007)
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Mojumdar SC, Melnik M, Jona E, Chem. Pap. Slovak Acad. Sci., 53, 309 (1999)
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Murugakoothan P, Ananth S, Vivek P, Arumanayagam T, J. Nano Electron. Phys., 6, 01003- (2014)
Pancaningtyas L, Akhlus S, The Role of Electrolytes in Dye Sensitized Solar Cell (DSSC) Performance (in Bahasa Indonesia), Thesis (2013).
Qadir MB, Sun KC, Sahito IA, Arbab AA, Choi BJ, Yi SC, Jeong SH, Sol. Energy Mater. Sol. Cells, 140, 141 (2015)
Susanti D, Nafi M, Purwaningsih H, Fajarin R, Kusuma GE, Procedia Chem, 9, 3 (2014)
Syafinar R, Gomesh N, Irwanto M, Fareq M, Irwan YM, Energy Procedia, 79, 799 (2015)
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Yin JF, Velayudham M, Bhattacharya D, Lin HC, Lu KL, Coord. Chem. Rev., 256, 3008 (2012)
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