본 연구에서는 방수시트재를 위한 아스팔트의 styrene-butadiene-styrene (SBS)와 styrene-isoprene-styrene (SIS)에 의한 개질에 있어서 자가치유성을 가지는 개질아스팔트 방수시트재의 연화점(softening point), 침입도(penetration), 저온굴곡저항성능(low temperature flexibility), 점도(viscosity) 및 부착성능(adhesion) 등의 물성을 관찰하고, 반응표면분석법(response surface methodology, RSM)을 활용하여 아스팔트 질량 대비 SBS와 SIS의 적정조성을 도출하고 자가치유성을 가지는 개질아스팔트 방수시트재의 물성을 최적화하였다. 고온에서 측정이 수행되는 연화점과 점도는 SBS 또는 SIS의 함량이 증가함에 따라서 유의하게 값이 증가하였다. 그러나 함량 대비 연화점과 점도 증가분은 SBS 경우가 SIS보다 커짐이 관찰되었다. 이러한 원인은 SBS와 SIS의 열적거동의 차이 때문인데, SBS는 고온에서 점도 상승을 동반하는 겔화(gelation)가 되어 가교도가 커지나 SIS는 점도감소를 초래하는 폴리이소프렌 블록의 사슬분리(chain scission)때문에 사슬꼬임(chain entanglement)이 상대적으로 적어지기 때문이다. 반면에 SIS-SBS 개질아스팔트는 상온에서 측정되는 침입도, 부착성능 및 저온굴곡성능에 대하여, 아스팔트 63 g을 기본으로 SIS 4~5 g과 SBS 8.5 g의 조성에서 최소 탄성거동을 나타내어 최대 침입도 및 최대 부착성능과 최저 저온굴곡성능 값을 보였다.

In this study, styrene-isoprene-styrene (SIS)-styrene-butadiene-styrene (SBS) modified asphalt was prepared for waterproof-sheet to measure its properties including softening point, penetration, low temperature flexibility, viscosity and adhesion. Then the properties of SIS-SBS modified asphalt imparted with self-healing were optimized to seek for optimal compositions of SIS and SBS versus asphalt according to response surface methodology (RSM). As the content of SBS or SIS was increased, both properties of softening point and viscosity, measured at high temperature, were increased with a statistical significance. However, the increments of softening point and viscosity per unit content of SBS added, were observed to be greater than those per unit content of SIS added, respectively. It was due to the difference of thermal properties of SBS and SIS at high temperature that the cross-linking degree of SBS was increased by gelation accompanied with the increase of viscosity, while chain-entanglement of SIS was relatively reduced owing to a chain scission of poly(isoprene) blocks causing the decrease of viscosity. To the contrary, SIS-SBS modified asphalt showed a behavior of the least elasticity resulting in both the maximum of penetration and adhesion, measured at room temperature, as well as the lowest low temperature flexibility at the composition of SIS, 4 g and SBS, 8.5 g based on asphalt, 63 g.

SIS-SBS modified asphalt Optimization Softening point Penetration Low temperature flexibility Viscosity Adhesion

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