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Received February 20, 2018
Accepted June 4, 2018
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Application of Flory-Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory to Excess Molar Volumes of Isomers of Propanol with Cyclohexane or n-Hexane
Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, Sonepat 131039, India 1Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, Sonepat 131039, India
sanjeevmakin@gmail.com
Korean Chemical Engineering Research, August 2018, 56(4), 536-541(6), 10.9713/kcer.2018.56.4.536 Epub 2 August 2018
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Abstract
Excess molar volumes (Vm E ) of binary mixtures of 1-propanol or 2-propanol (1) + cyclohexane or n-hexane (2) were measured with V-shaped dilatometer at 303.15 K. The Vm E data for these mixtures varied as: 2-propanol > 1-propanol and were higher for cyclohexane than n-hexane for both propanol systems. The experimental data were correlated with Redlich-Kister polynomial. The Vm E data were interpreted qualitatively as well as quantitatively in terms of Flory- Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory. Both models correctly described the sign and shape of Vm E vs x1 curves. The values calculated by both the models agree well with the experimental data.
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References
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Rani M, Gahlyan S, Om H, Verma N, Maken S, J. Mol. Liq., 194, 100 (2014)
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Gahlyan S, Verma S, Rani M, Maken S, Korean J. Chem. Eng., 35 (2018)
Treszczanowicz AJ, Benson GC, Fluid Phase Equilib., 23, 117 (1985)
Patterson D, Delmas G, Discussions of the Faraday Society, 49, 98 (1970)
Barta L, Kooner ZS, Hepler LG, Roux-Desgranges G, Grolier JPE, Canadian J. Chem., 67, 1225 (1989)
Kumar S, Maken A, Agarwal S, Maken S, J. Mol. Liq., 155, 115 (2010)
Weissenberger A, “Physical Methods of Organic Chemistry,” Third ed., Interscience, New York, 1959.
Maken S, Gaur A, Verma N, Singh KC, Lee S, Park JW, J. Ind. Eng. Chem., 13(7), 1098 (2007)
Nikam PS, Shirsat LN, Hasan M, J. Chem. Eng. Data, 43(5), 732 (1998)
Ortega J, J. Chem. Eng. Data, 27, 312 (1982)
Pereiro AB, Rodriguez A, J. Chem. Thermodyn., 39(9), 1219 (2007)
Riddick JA, Bunger WB, Sakano TK, Wiley, New York, 1 (1986)
Gonzalez B, Calvar N, Dominguez A, Tojo J, J. Chem. Thermodyn., 39(2), 322 (2007)
Nayak JN, Aralaguppi MI, Aminabhavi TM, J. Chem. Eng. Data, 48(5), 1152 (2003)
Orge B, Iglesias M, Rodriguez A, Canosa JM, Tojo J, Fluid Phase Equilib., 133(1-2), 213 (1997)
Dubey GP, Sharma M, Phys. Chem. Liquids, 46, 610 (2008)
Lee LS, Chuang ML, J. Chem. Eng. Data, 42(5), 850 (1997)
Marcus Y, “Introduction to Liquid State Chemistry,”Wiley Interscience, New York, 1977.
Nain AK, J. Solution Chem, 42, 1404 (2013)
Flory PJ, J. Am. Chem. Soc., 87, 1833 (1965)
Abe A, Flory PJ, J. Am. Chem. Soc., 87, 1838 (1965)
Rani M, Maken S, J. Ind. Eng. Chem., 18(5), 1694 (2012)
Verma S, Gahlyan S, Rani M, Maken S, J. Mol. Liq., 265, 468 (2018)
Kashyap P, Gahlyan S, Rani M, Tiwari DP, Maken S, J. Mol. Liq., 268, 303 (2018)
