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Received May 14, 2018
Accepted August 31, 2018
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Optical and Acoustic Properties of Binary Mixtures of Butanol Isomers as Oxygenates with Cyclohexane, Benzene and Toluene at 308.15 K
Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India 1Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India
sanjeevmakin@gmail.com
Korean Chemical Engineering Research, October 2018, 56(5), 663-678(16), 10.9713/kcer.2018.56.5.663 Epub 5 October 2018
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Abstract
Refractive index and speeds of sound for the binary mixture of isomer of butanol (1) + cyclohexane, benzene and toluene (2) were measured at 308.15 K. The measured data were used to calculate deviation in refractive index Δn, ultrasonic speed Δu, isentropic compressibility Ks E, available volume Va, excess intermolecular free length Lf and molecular association MA. All the derived properties were correlated with polynomial equation. Ultrasonic speed data were predicted using various empirical correlations like Nomoto, van Dael, impedance dependence and theoretically with Schaaff’s collision factor theory (CFT). Jacobson free length theory (FLT) was used to calculate Lf. The measured refractive index was also correlated with various mixing rules. The deviation in refractive index Δn and ultrasonic speed Δu was used to determine the intermolecular interactions.
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Surisetty VR, Dalai AK, Kozinski J, Appl. Catal. A: Gen., 404(1-2), 1 (2011)
Karabektas M, Ergen G, Hosoz M, Fuel, 115, 855 (2014)
Ezeji TC, Blaschek HP, Butanol Production from Lignocellulosic Biomass, in: Biofuels from Agricultural Wastes and Byproducts, Wiley-Blackwell, Oxford, UK (2010)
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Regulation 715/2007 of the European Parliament ad of the Council on type approval of motor vehicles with respect to emissions from light passenger and commercial vehicles (Euro 5 and Euro 6) (2007).
Directive 2009/30/EC of the European Parliament ad of the Council on the specification of petrol, diesel and gas-oil and introducing a mechanism to monitor and reduce greenhouse gas emissions (2009).
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Rani M, Agarwal S, Lahot P, Maken S, J. Ind. Eng. Chem., 19(5), 1715 (2013)
Rani M, Gahlyan S, Gaur A, Maken S, Chinese J. Chem Eng., 23, 689 (2015)
Kashyap P, Rani M, Gahlyan S, Tiwari DP, Maken S, J. Mol. Liq., 268, 304 (2018)
Rani M, Maken S, J. Ind. Eng. Chem., 18(5), 1694 (2012)
Gahlyan S, Rani M, Maken S, J. Mol. Liq., 219, 1107 (2016)
Rani M, Gahlyan S, Om H, Verma N, Maken S, J. Mol. Liq., 194, 100 (2014)
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Schaaffs W, Molekularakustik, Springer-Verlag, 1963.
Schaaffs W, Acustica, 33, 272 (1975)
Jacobson B, Acta. Chem. Scand., 9, 997 (1955)
Jacobson B, J. Chem. Phys., 20, 927 (1952)
Jacobson B, Acta. Chem. Scand., 6, 1485 (1952)
Riddick JA, Bunger WB, Sakano TK, 4th ed., Wiley, New York(1986).
Vogel AI, “A Text Book of Practical Organic Chemistry, 4th ed.,” ELBS Longman, London(1978).
Barta L, Kooner ZS, Hepler LG, Roux-Desgranges G, Grolier JPE, Can. J. Chem., 67, 1225 (1989)
de Cominges BE, Pineiro MM, Mosteiro E, Mascato E, Mato MM, Iglesias TP, Legido JL, J. Therm. Anal. Calorim., 70, 217 (2002)
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Troncoso J, Tovar CA, Cerdeirina CA, Carballo E, Romani L, J. Chem. Eng. Data, 46, 312 (2001)
Chandra Sekhar M, Madhu MT, Vijaya KT, Venkatesulu A, Siva KK, J. Sol.Chem, 44, 237 (2015)
Sastry NV, Patel SR, J. Chem. Thermodyn., 32(12), 1669 (2000)
Kijevcanin ML, Radovic IR, Djordjevic BD, Tasic AZ, Serbanovic SP, Thermochim. Acta, 525(1-2), 114 (2011)
Gilani AG, Paktinat N, Moghadam M, J. Chem. Thermodyn., 43(4), 569 (2011)
George J, Sastry NV, J. Chem. Eng. Data, 48(4), 977 (2003)
Nayak JN, Aralaguppi MI, Aminabhavi TM, J. Chem. Eng. Data, 47(4), 964 (2002)
Sastry NV, Patel MC, Patel SR, Fluid Phase Equilib., 155(2), 261 (1999)
Nayak JN, Aralaguppi MI, Aminabhavi TM, J. Chem. Eng. Data, 46, 891 (2001)
Kiyohara O, Benson GC, J. Chem. Thermodyn., 11, 861 (1979)
Troncoso J, Carballo E, Cerdeirina CA, Gonzalez D, Romani L, J. Chem. Eng. Data, 45, 594 (2000)
Sharma VK, Dua R, Dimple, Jangra SK, Fluid Phase Equilib., 378, 83 (2014)
Troncoso J, Valencia JL, Souto-Caride M, Gonzalez-Salgado D, Peleteiro J, J. Chem. Eng. Data, 49(6), 1789 (2004)
Paramo R, Zouine M, Casanova C, J. Chem. Eng. Data, 47(3), 441 (2002)
Oswal SL, Prajapati KD, Oswal P, Ghael NY, Ijardar SP, J. Mol. Liq., 116, 73 (2005)
Bhardwaj U, Maken S, Singh KC, J. Chem. Eng. Data, 41(5), 1043 (1996)
Bhardwaj U, Maken S, Singh KC, Indian J. Chem., 37A, 316 (1998)
Bhardwaj U, Maken S, Singh KC, J. Chem. Thermodyn., 28(10), 1173 (1996)
