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Received August 13, 2018
Accepted September 7, 2018
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Phase Equilibrium of Binary Mixture for the (Carbon Dioxide + 1-Phenyl-2-Pyrrolidone) System at High Pressure
Department of Chemical and Biomolecular Engineering, Chonnam National University, 50, Daehak-ro, Yeosu-si, Jeollanam-do, 59626, Korea
Korean Chemical Engineering Research, October 2018, 56(5), 732-737(6), 10.9713/kcer.2018.56.5.732 Epub 5 October 2018
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Abstract
Experimental data of phase equilibria are reported for the binary mixture of 1-phenyl-2-pyrrolidone in supercritical carbon dioxide. Phase behavior data was measured in a synthetic method at a temperature ranging from 333.2 to 393.2 K and at pressures up to 97.14 MPa. The solubility of 1-phenyl-2-pyrrolidone in the carbon dioxide + 1- phenyl-2-pyrrolidone system increased as temperature increased at a constant pressure and it exhibited the type-I phase behavior. The experimental data for the binary mixture were correlated with the Peng-Robinson equation of state using mixing rule and the critical properties of 1-phenyl-2-pyrrolidone were predicted with the Joback and Lyderson method.
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McHugh MA, Krukonis VJ, Supercritical Fluid Extraction, 2nd ed., Butterworth-Heinemann, Stoneham, Boston, 1994.
Lee JC, Kim CR, Byun HS, Korean J. Chem. Eng., 31(12), 2266 (2014)
Jang YS, Byun HS, J. Chem. Eng. Data, 59(5), 1391 (2014)
Jang YS, Kim SH, Yoo KP, Byun HS, Fluid Phase Equilib., 302(1-2), 234 (2011)
Yoon SD, Byun HS, Korean J. Chem. Eng., 31(3), 522 (2014)
Byun HS, J. Supercrit. Fluids, 120, 218 (2017)
Byun HS, Rhee SY, Korean J. Chem. Eng., 34(4), 1170 (2017)
Lee BS, Byun HS, J. Supercrit. Fluids, 135, 211 (2018)
Lee BS, Lee JK, Bong JH, Byun HS, Fluid Phase Equilib., 462, 1 (2018)
Kim SH, Chun D, Yoon SD, Byun HS, J. Chem. Eng. Data, 61(3), 1101 (2016)
Rebelatto EA, Polloni AE, Andrade KS, Bender JP, Corazza ML, Lanza M, Oliveira JV, J. Chem. Thermodyn., 122, 125 (2018)
Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15(1), 59 (1976)
Poling BE, Prausnitz JM, O’Connell JP, The Properties of Liquids and Gases, 5th ed., McGraw-Hill, New York, 2001.
Lee BS, Byun HS, Korean J. Chem. Eng., 34(7), 2056 (2017)
Cho DW, Shin J, Bae W, Kim H, Lee JH, Shin MS, Fluid Phase Equilib., 319, 37 (2012)
Chirico RD, Frenkel M, Diky VV, Marsh KN, Wilhoit RC, J. Chem. Eng. Data, 48(5), 1344 (2003)
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Rowlinson JB, Swinton FL, Liquid and Liquid Mixtures, 3rd ed., Butterworth, Boston, 1982.
http://www.chemspider.com/Chemical-Structure.70744.html.
