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Received January 21, 2019
Accepted March 28, 2019
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Ni Nanoparticles Supported on MIL-101 as a Potential Catalyst for Urea Oxidation in Direct Urea Fuel Cells
Department of machine and Equipment, Industrial University of Ho Chi Minh City, Nguyen Van Bao, HCMC, Vietnam 1Department of Chemical and Bio Engineering, Gachon University, 1342, Seongnam-daero, Sujeong-gu, Seongnam-si, Gyeonggi-do, 13120, Korea
Korean Chemical Engineering Research, June 2019, 57(3), 387-391(5), 10.9713/kcer.2019.57.3.387 Epub 3 June 2019
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Abstract
A highly porous Ni@MIL-101catalyst for urea oxidation was synthesized by anchoring Ni into a Cr-based metal-organic framework, MIL-101, particles. The morphology, structure, and composition of as synthesized Ni@MIL- 101 catalysts were characterized by X-Ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy. The electro-catalytic activity of the Ni@MIL-101catalysts towards urea oxidation was investigated using cyclic voltammetry. It was found that the structure of Ni@MIL-101 retained that of the parent MIL-101, featuring a high BET surface area of 916 m2 g-1, and thus excellent electro-catalytic activity for urea oxidation. A urea/H2O2 fuel cell with Ni@MIL-101 as anode material exhibited an excellent performance with maximum power density of 8.7 mWcm-2 with an open circuit voltage of 0.7 V. Thus, this work shows that the highly porous three-dimensional Ni@MIL-101 catalysts can be used for urea oxidation and as an efficient anode material for urea fuel cells.
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