ISSN: 0304-128X ISSN: 2233-9558
Copyright © 2024 KICHE. All rights reserved

Articles & Issues

Language
english
Conflict of Interest
In relation to this article, we declare that there is no conflict of interest.
Publication history
Received December 5, 2018
Accepted May 17, 2019
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.

All issues

Purification of Biohydrogen Produced From Palm Oil Mill Effluent Fermentation for Fuel Cell Application

Research Center for Sustainable Process Technology, Faculty of Engineering & Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Malaysia 1Department of Chemical and Petroleum Engineering, Faculty of Engineering, Technology and Built Environment, UCSI University (Block E) Kuala Lumpur Campus Jalan Mandarina Damai 1 56000 Cheras, Kuala Lumpur, Malaysia
Korean Chemical Engineering Research, August 2019, 57(4), 469-474(6), 10.9713/kcer.2019.57.4.469 Epub 2 August 2019
downloadDownload PDF

Abstract

Fermentation of palm oil mill effluent (POME) produces biohydrogen in a mixture at a specific set condition. This research was conducted to purify the produced mixed biohydrogen via absorption and membrane techniques. Three different solvents, methyl ethanolamine (MEA), ammonia (NH3) and potassium hydroxide (KOH) solutions, were used in absorption technique. The highest H2 purity was found using 1M MEA solution with 5.0 ml/s feed mixed gas flow rate at 60 minutes absorption time. Meanwhile, the purified biohydrogen using a polysulfone membrane had the highest H2 purity at 2~3 bar operating pressure. Upon testing with proton exchange membrane fuel cell (PEMFC), the highest current and power produced at 100% H2 were 1.66 A and 8.1 W, while the lowest were produced at 50/50 vol% H2/CO2 (0.32 A and 0.49 W). These results proved that both purification techniques have significant potential for H2 purification efficiency.

References

Sayari A, Belmabkhout Y, Serna-Guerrero R, Chem. Eng. J., 171(3), 760 (2011)
Yang H, Fan S, Lang X, Wang Y, Nie J, Chinese J. Chem. Eng., 19(4), 615 (2011)
Chin MJ, Poh PE, Tey BT, Chan ES, Chin KL, Renew. Sust. Energ. Rev., 26, 717 (2013)
Kim K, Ingole PG, Kim J, Lee H, Chem. Eng. J., 233, 242 (2013)
Rufford TE, Smart S, Watson GCY, Graham BF, Boxall J, Diniz da Costa JC, J. Pet. Sci. Eng., 94-95, 123 (2012)
Bakonyi P, Nemestothy N, Belafi-Bako K, Int. J. Hydrog. Energy, 38(23), 9673 (2013)
Diao YF, Zheng XY, He BS, Chen CH, Xu XC, Energy Conv. Manag., 45(13-14), 2283 (2004)
Ma SC, Song HH, Wang MX, Yang JH, Zang B, Chem. Eng. Res. Des., 91(7), 1327 (2013)
Kumbharkar SC, Liu Y, Li K, J. Membr. Sci., 375(1-2), 231 (2011)
Modigell M, Schumacher M, Teplyakov VV, Zenkevich VB, Desalination, 224(1-3), 186 (2008)
Badiei M, Jahim JM, Anuar N, Rozaimah S, Abdullah S, Int. J. Hydrog. Energy, 36(10), 5912 (2011)
Chong PS, Jahim JM, Harun S, Lim SS, Abd Mutalib S, Hassan O, Nor MTM, Int. J. Hydrog. Energy, 38(22), 9592 (2013)
Mohamad IN, Rohani R, Masdar MSM, Nor MTM, Jahim JM, Int. J. Hydrog. Energy, 41(7), 4474 (2016)
Maceiras R, Alves SS, Cancela MA, Alvarez E, Chem. Eng. J., 137(2), 422 (2008)
Zhao B, Su Y, Peng Y, Int. J. Greenh. Gas Control, 17, 481 (2013)
Luis P, Desalination, 380, 93 (2016)
Spigarelli BP, Kawatra SK, J. CO2 Util., 1, 69 (2013)
Choi SH, Lee MK, Oh SJ, Koo JK, J. Membr. Sci., 221(1-2), 37 (2003)
Rezakazemi M, Ebadi Amooghin A, Montazer-Rahmati MM, Ismail AF, Matsuura T, Prog. Polym. Sci, 39(5), 817 (2014)
David OC, Gorri D, Urtiaga A, Ortiz I, J. Membr. Sci., 378(1-2), 359 (2011)
Ebert K, Fritsch D, Koll J, Tjahjawiguna C, J. Membr. Sci., 233(1-2), 71 (2004)
Bakonyi P, Nemestothy N, Lanko J, Rivera I, Buitron G, Belafi-Bako K, Int. J. Hydrog. Energy, 40(4), 1690 (2015)
Ahluwalia RK, Wang X, J. Power Sources, 180(1), 122 (2008)

The Korean Institute of Chemical Engineers. F5, 119, Anam-ro, Seongbuk-gu, 233 Spring Street Seoul 02856, South Korea.
Phone No. +82-2-458-3078FAX No. +82-507-804-0669E-mail : kiche@kiche.or.kr

Copyright (C) KICHE.all rights reserved.

- Korean Chemical Engineering Research 상단으로