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Received March 31, 2019
Accepted May 29, 2019
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합성가스로부터 경질탄화수소 및 중산유분을 생산하기 위한 Fischer-Tropsch의 국내연구동향
Review of Domestic Research Trends of Fischer-Tropsch for the Production of Light Hydrocarbons and Middle Distillates From Syngas
1고등기술연구원 플랜트엔지니어링센터, 17180 경기도 용인시 처인구 백암면 고안로 51번길 175-28 2아주대학교 화학공학과, 16499 경기도 수원시 영통구 월드컵로 206 3아주대학교 에너지시스템학과, 16499 경기도 수원시 영통구 월드컵로 206
1Plant Engineering Center, Institute for Advances Engineering (IAE), 175-28 Goan-ro, 51Beon-gil, Baegam-myeon, Cheoin-ju, Yongin-si, Gyeonggi-do, 17180, Korea 2Department of Chemical Engineering, Ajou University, 206, Worldcup-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16499, Korea 3Department of Energy Systems Research, Ajou University, 206, Worldcup-ro, Yeongtong-gu, Suwon-si, Gyeonggi-do, 16499, Korea
shkang@iae.re.kr
Korean Chemical Engineering Research, August 2019, 57(4), 565-574(10), 10.9713/kcer.2019.57.4.565 Epub 2 August 2019
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Abstract
Fischer-Tropsch 합성공정은 합성가스로부터 탄화수소를 합성하는 대표적인 방법이며, 주로 철(Fe)계와 코발트(Co) 계 촉매로 알려져 있다. 현재 생성물에 따라 일부 기술(CTL, GTL 등)은 상용 규모로 운전되고 있으나, 경질탄화수소와 중간유분을 직접 생산하는 연구는 아직 상용화되지는 않았다. 그러므로, 본 연구에서는 국내에서 현재까지 경질탄화수소와 중간유분을 직접 생산하기 위한 연구들을 정리하였으며, 촉매의 제조법, 조촉매 첨가, 제올라이트의 조합과 같은 영향이 생성물의 선택도에 미치는 영향을 고찰하였다.
Fischer-Tropsch synthesis process is a typical method for synthesizing hydrocarbons from syngas and is mainly known as iron (Fe) and cobalt (Co) catalysts. Currently, some technologies such as CTL (Coal to Liquid) and GTL (Gas to Liquid) are operated on a commercial scale depending on the products, but the research to produce light hydrocarbons and middle distillates directly has not been commercialized. Therefore, in this study, domestic studies for direct production of light hydrocarbons and middle distillates are summarized and the effect of catalyst preparation, promoter addition, zeolite combination on product selectivity is investigated.
Keywords
References
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Cho JM, Kasipandi S, Park YM, Bae JW, Fuel, 239, 547 (2019)
