ISSN: 0256-1115 (print version) ISSN: 1975-7220 (electronic version)
Copyright © 2024 KICHE. All rights reserved

Articles & Issues

Language
English
Conflict of Interest
In relation to this article, we declare that there is no conflict of interest.
Publication history
Received August 23, 2023
Accepted August 23, 2023
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.

All issues

Inorganic Membranes and Membrane Reactors

Department of Chemical Engineering, University of Cincinnati, Cincinnati, OH 45221-0171, USA
shwang@alpha.che.uc.edu
Korean Journal of Chemical Engineering, November 2001, 18(6), 775-787(13), 10.1007/BF02705597
downloadDownload PDF

Abstract

The inorganic membrane reactor is a combined unit operation of chemical reactions and membrane separations. By having a membrane reactor, the downstream separation load can be reduced. Also, the yields can be increased and conversion can be improved for equilibrium limited reactions. However, many of the industrial chemical reactions take place at high temperature that the conventional polymeric membranes cannot withstand. A great deal of research has been done recently to develop ion-conducting ceramic membranes. Many of these have been successfully employed to form membrane reactors for many industrially relevant chemical reactions, such as hydrogenation, dehydrogenation, oxidation, coupled reactions, and decomposition reactions. An overview is given for the area of inorganic membrane preparations and membrane reactors. Many examples of petrochemical interests are presented, including hydrocarbon conversions and fuel cell applications.

References

Abdalla BK, Elnashaie SS, J. Membr. Sci., 101(1-2), 31 (1995) 
Adris AM, Elnashaie SSEH, Hughes R, Can. J. Chem. Eng., 69, 1061 (1991)
Alberti G, Casciola M, Palombari R, J. Membr. Sci., 172(1-2), 233 (2000) 
Alqahtany H, Chiang PH, Eng D, Stoukides M, Robbat A, Catal. Lett., 13(3), 289 (1992)
Alqahtany H, Eng D, Stoukides M, J. Electrochem. Soc., 140(6), 1677 (1993) 
Alqahtany H, Eng D, Stoukides M, Energy Fuels, 7(4), 495 (1993) 
Anshits AG, Shigapov AN, Vereshchagin SN, Shevnin VN, Kinet. Catal., 30(5), 1103 (1989)
Arashi H, Naito H, Solid State Ion., 53, 431 (1992) 
Armor JN, J. Membr. Sci., 147(2), 217 (1998) 
Armor JN, Chem. Tech., 22, 557 (1992)
Armor JN, Farris TS, Silveston PL, Hightower JW, Haag WO, Ross JRH, Kaliaguine S, Sarkany A, Geus JW, Stud. Surf. Sci. Catal., 75(B), 1362 (1993)
Asano K, Hibino T, Iwahara H, J. Electrochem. Soc., 142(10), 3241 (1995) 
Bafas IC, Constantinou IE, Vayenas CG, Chem. Eng. J., 82(1-3), 109 (2001) 
Beatrice P, Pliangos C, Worrell WL, Vayenas CG, Solid State Ion., 136-137, 833 (2000) 
Bieberle A, Meier LP, Gauckler LJ, J. Electrochem. Soc., 148(6), a646 (2001) 
Bitter JGA, "Process and Apparatus for the Dehydration of Organic Compounds," Br. Patent, 2,201,159 (1988)
Boddeker KW, Peinemann KV, Nunes SP, J. Membr. Sci., 185(1), 1 (2001) 
Bouwmeester HJM, Kruidhof H, Burggraaf AJ, Gellings PJ, Solid State Ion., 53, 460 (1992) 
Cavalca CA, Larsen G, Vayenas CG, Haller GL, J. Phys. Chem., 97(23), 6115 (1993) 
Champagnie AM, Tsotsis TT, Minrt RG, Wagner E, J. Catal., 134, 713 (1992) 
Chan KK, Brownstein AM, Ceram. Bull., 70, 703 (1991)
Chen CS, Kruidhof H, Bouwmeester HJ, Verweij H, Burggraaf AJ, Solid State Ion., 86-88, 569 (1996) 
Cheng YS, Yeung KL, J. Membr. Sci., 158(1-2), 127 (1999) 
Chiang PH, Eng D, Stoukides M, J. Catal., 139(2), 683 (1993) 
Chiang PH, Eng D, Alqahtany H, Stoukides M, Solid State Ion., 53(1), 135 (1992)
Cicero DC, Jarr LA, Sep. Sci. Technol., 25(13-15), 1455 (1990)
Daub K, Wunder VK, Dittmeyer R, Catal. Today, 67(1-3), 257 (2001) 
Dou S, Mason CR, Pacey PD, J. Electrochem. Soc., 132, 1843 (1985) 
Drioli E, J. Membr. Sci., 181(1), 1 (2001) 
Edlund DJ, Pledger WA, J. Membr. Sci., 77(2-3), 255 (1993) 
Edlund DJ, Pledger WA, Johnson BM, Friesen DT, "Toward Economical and Energy Efficient Production of Hydrogen from Coal using Metal-Membrane Reactors," 5th Annu. Meet. NAMS, Lexington, KY, paper 11F (1992)
Eng D, Stoukides M, Catal. Lett., 9(1-2), 47 (1991) 
Eng D, Stoukides M, Catal. Rev., 33(3-4), 375 (1991)
Eng D, Chiang PH, Stoukides M, Energy Fuels, 9(5), 794 (1995) 
Farris TS, Armor JN, Appl. Catal. A: Gen., 96(1), 25 (1993) 
Gallaher GR, Gerdes TE, Liu PKT, Sep. Sci. Technol., 28, 309 (1993)
Goto S, Assabumrungrat S, Tagawa T, Praserthdam P, J. Membr. Sci., 175(1), 19 (2000) 
Govind R, Atnoor D, Ind. Eng. Chem. Res., 30, 591 (1991) 
Gryaznov VM, Platinum Met. Rev., 36, 70 (1992)
Gryaznov VM, Ermilova MM, Orekhova NV, Catal. Today, 67(1-3), 185 (2001) 
Gryaznov VM, Guliyanova SG, Serov YM, USP Khim., 58(1), 58 (1989)
Gryaznov VM, Mischenko AP, Sarylova ME, "Catalyst for Cyclization of Pentadiene-1,3 into Cyclopentene and Cyclopentane," GB Patent, 2,187,758 A (1987)
Gryaznov VM, Serebryannikova OS, Serov YM, Appl. Catal. A: Gen., 96, 15 (1993) 
Gryaznov VM, Vedemikov VI, Guliyanova SG, Kinet. Catal., 27(1), 129 (1986)
Guy C, Rev. Inst. Fr. Pet., 47, 133 (1992)
Hamakawa S, Hibino T, Iwahara H, J. Electrochem. Soc., 140, 459 (1993) 
Hamakawa S, Hibino T, Iwahara H, J. Electrochem. Soc., 141(7), 1720 (1994) 
Han P, Worrell WL, J. Electrochem. Soc., 142(12), 4235 (1995) 
Han JH, Zeng YX, Lin YS, J. Membr. Sci., 132(2), 235 (1997) 
Hibino T, Masegi A, Iwahara H, J. Electrochem. Soc., 142(10), 3262 (1995) 
Hibino T, Ushiki K, Kuwahara Y, Masegi A, Iwahara H, J. Chem. Soc.-Faraday Trans., 92(13), 2393 (1996) 
Hibino T, Hashimoto A, Inoue T, Tokuno J, Yoshida S, Sano M, J. Electrochem. Soc., 148(6), A544 (2001) 
Hwang ST, Kammemeyer K, "Techniques of Chemistry, VII: Membranes in Separations," Wiley Interscience, New York (1975)
Ilinitch OM, Cuperus FP, Nosova LV, Gribov EN, Catal. Today, 56(1-3), 137 (2000) 
Ioannides T, Gavalas GR, J. Membr. Sci., 77(2-3), 207 (1993) 
Itoh N, AIChE J., 33, 1576 (1987) 
Itoh N, Sanchez MA, Xu WC, J. Membr. Sci., 77(2-3), 245 (1993) 
Iwahara H, Esaka T, Uchida H, Yamauchi T, Okaki K, Solid State Ion., 18, 1003 (1986) 
Iwahara H, Uchida H, Morimoto K, J. Electrochem. Soc., 137, 462 (1990) 
Iwahara H, Matsumoto H, Takeuchi K, Solid State Ion., 136-137, 133 (2000) 
Jayaraman V, Lin YS, Pakala M, Lin RY, J. Membr. Sci., 99(1), 89 (1995) 
Jiang Y, Virkar AV, J. Electrochem. Soc., 148(7), A706 (2001) 
Jiang Y, Yentekakis IV, Vayenas CG, Science, 264(5165), 1563 (1994) 
Jin WQ, Li SG, Huang P, Xu NP, Shi J, Lin YS, J. Membr. Sci., 166(1), 13 (2000) 
Jun CS, Lee KH, J. Membr. Sci., 157(1), 107 (1999) 
Jun CS, Lee KH, J. Membr. Sci., 176(1), 121 (2000) 
Jurado JR, Moure C, Duran P, Valverde N, Solid State Ion., 28, 518 (1988) 
Kaloyannis A, Vayenas CG, J. Catal., 171(1), 148 (1997) 
Kikuchi E, Uemiya S, Sato N, Inoue H, Ando H, Matauda T, Chem. Lett., 489 (1989) 
Kikuchi E, Uemiya S, Sato N, Inoue H, Ando H, Matsuda T, Chem. Lett., 489 (1989) 
Kim J, Lin YS, J. Membr. Sci., 139(1), 75 (1998) 
Kim J, Lin YS, J. Membr. Sci., 167(1), 123 (2000) 
Kim H, Park S, Vohs JM, Gorte RJ, J. Electrochem. Soc., 148(7), A693 (2001) 
Kobayashi T, Morishita S, Abe K, Iwahara H, Solid State Ion., 86-88, 603 (1996) 
Kobayashi T, Abe K, Ukyo Y, Iwahara H, Electrochem., 68(6), 494 (2000)
Kobayashi T, Yamazaki K, Abe K, Ukyo Y, Iwahara H, J. Ceram. Soc. Jpn., 108(6), 554 (2000)
Kobayashi T, Abe K, Ukyo Y, Iwahara H, Solid State Ion., 134(3-4), 241 (2000) 
Konno M, Shindo M, Sugawara S, Saito S, J. Membr. Sci., 37, 193 (1988) 
Kreuer KD, Solid State Ion., 97(1-4), 1 (1997) 
Kruidhof H, Bouwmeester HJMV, Doom RHE, Burggraaf AJ, Solid State Ion., 63-65B, 816 (1993) 
Langguth J, Dittmeyer R, Hofmann H, Tomandl G, Appl. Catal. A: Gen., 158(1), 287 (1997) 
Langguth J, Dittmeyer R, Hofmann H, Tomandl G, Chem. Ing. Tech., 69(3), 354 (1997) 
Li A, Liang W, Hughes R, J. Membr. Sci., 165(1), 135 (2000) 
Li ZY, Macda H, Kusakabe K, Morooka S, Anzai H, Akiyama S, J. Membr. Sci., 78, 247 (1993) 
Lin YS, Zeng Y, J. Catal., 164(1), 220 (1996) 
Lin YS, Zeng Y, J. Catal., 168(2), 546 (1997) 
Marnellos G, Zisekas S, Stoukides M, J. Catal., 193(1), 80 (2000) 
Matsuda T, Koike I, Kubo N, Kikuchi E, Appl. Catal. A: Gen., 96, 3 (1993) 
McKenna EA, Othoneos A, Kiratzis N, Stoukides M, Ind. Eng. Chem. Res., 32(9), 1904 (1993) 
Michaels AS, Chem. Eng. Prog., 64(12), 31 (1968)
Michaels JN, Vayenas CG, J. Catal., 85, 477 (1984) 
Morooka S, Yan SC, Yokoyama S, Kusakabe K, Sep. Sci. Technol., 30(14), 2877 (1995)
Moser WR, Becker Y, Dixon AG, Ma YH, "Catalytic Inorganic Membranes, and Their Modification for Use in Catalyzed Chemical Processes," 5th Annu. Meet. NAMS, Lexington, KY, paper 11E (1992)
Nagamoto H, Inoue H, J. Chem. Eng. Jpn., 14, 377 (1981)
Nagamoto H, Inoue H, Chem. Eng. Commun., 34, 315 (1985)
Nagamoto H, Inoue H, Bull. Chem. Soc. Jpn., 59, 3935 (1986) 
Nam SE, Lee SH, Lee KH, J. Membr. Sci., 153(2), 163 (1999) 
Neomagus HWJP, van Swaaij WPM, Versteeg GF, J. Membr. Sci., 148(2), 147 (1998) 
Neomagus HWJP, Saracco G, Wessel HFW, Versteeg GF, Chem. Eng. J., 77(3), 165 (2000) 
Nigara Y, Mizusaki J, Ishigame M, Solid State Ion., 79, 208 (1995) 
Nigara Y, Watanabe K, Kawamura K, Mizusaki J, Ishigame M, J. Electrochem. Soc., 144(3), 1050 (1997) 
Oertel M, Schmitz J, Weirich W, Jendryssek-Neumann D, Schulten R, Chem. Eng. Technol., 10, 248 (1987) 
Okubo T, Haruta K, Kusakabe K, Morooka S, Anzai H, Akiyama S, Ind. Eng. Chem. Res., 30, 614 (1991) 
Otsuka K, Yamanaka I, Catal. Today, 41(4), 311 (1998) 
Otsuka K, Ishizuka K, Yamanaka I, Electrochim. Acta, 37(13), 2549 (1992) 
Pan XL, Liu BJ, Xiong GX, Sheng SS, Liu J, Yang WS, Catal. Lett., 66(3), 125 (2000) 
Panagos E, Voudouris I, Stoukides M, Chem. Eng. Sci., 51(11), 3175 (1996) 
Peterson D, Winnick J, J. Electrochem. Soc., 143(3), L55 (1996) 
Petrolekas PD, Balomenou S, Vayenas CG, J. Electrochem. Soc., 145(4), 1202 (1998) 
Pliangos C, Raptis C, Badas T, Vayenas CG, Solid State Ion., 136-137, 767 (2000) 
Qi XW, Lin YS, Solid State Ion., 120(1-4), 85 (1999) 
Qi XW, Lin YS, Swartz SL, Ind. Eng. Chem. Res., 39(3), 646 (2000) 
Qi XW, Lin YS, Solid State Ion., 130(1-2), 149 (2000) 
Qiu L, Lee TH, Liu LM, Yang YL, Jacobson AJ, Solid State Ion., 76(3-4), 321 (1995) 
Raich BA, Foley HC, Appl. Catal. A: Gen., 129(2), 167 (1995) 
Raich BA, Foley HC, Ind. Eng. Chem. Res., 37(10), 3888 (1998) 
Roth JF, Stud. Surf. Catal., 38, 925 (1988)
Saracco G, Versteeg GF, Vanswaaij WP, J. Membr. Sci., 95(2), 105 (1994) 
Saracco G, Specchia V, Catal. Rev., 36(2), 305 (1994)
Saracco G, Neomagus HWJP, Versteeg GF, van Swaaij WPM, Chem. Eng. Sci., 54(13-14), 1997 (1999) 
Seok DR, Hwang ST, Stud. Surf. Sci. Catal., 54, 248 (1990)
She Y, Han J, Ma YH, Catal. Today, 67(1-3), 43 (2001) 
Shu J, Grandjean BPA, Ghali E, Kaliaguine S, J. Membr. Sci., 77, 181 (1993) 
Shu J, Grandjean BPA, van Seste A, Kaliaguine S, Can. J. Chem. Eng., 69, 1036 (1991)
Song JY, Hwang ST, J. Membr. Sci., 57, 95 (1991) 
Souleimanova RS, Mukasyan AS, Varma A, J. Membr. Sci., 166(2), 249 (2000) 
Stevenson JW, Armstrong TR, Carneim RD, Pederson LR, Weber WJ, J. Electrochem. Soc., 143(9), 2722 (1996) 
Stoukides M, Catal. Rev., 42(1-2), 1 (2000) 
Teraoka Y, Nobunaga T, Yamazoe N, Chem. Lett., 503 (1988) 
Teraoka Y, Zhang HM, Furukawa S, Yamazoe N, Chem. Lett., 1745 (1985)
Teymouri E, Bagherzadeh E, Petit C, Rehspringer JL, Libs S, Kienneman A, J. Mater. Sci., 30, 3005 (1993) 
Tiscareno-Lechuga F, Hill GC, Anderson MA, Appl. Catal. A: Gen., 96, 33 (1993) 
Tsai CY, Dixon AG, Ma YH, Moser WR, Pascucci MR, J. Am. Ceram. Soc., 81, 1437 (1998)
Tsotsis TT, Champagnie AM, Vasileiadis SP, Ziaka ZD, Minet RG, Chem. Eng. Sci., 47(9-11), 2903 (1992) 
Tsotsis TT, Champagnie AM, Vasileidas SP, Ziaka AD, Minet RG, Sep. Sci. Technol., 28, 397 (1993)
Tuller HL, Solid State Ion., 52, 135 (1992) 
Uemiya S, Kude Y, Sugino K, Sato N, Matsuda T, Kikuchi E, Chem. Lett., 1687 (1988) 
Uemiya S, Matsuda H, Kikuchi E, Chem. Lett., 1335 (1990) 
Uemiya S, Sato N, Ando H, Matsuda T, Kikuchi E, Appl. Catal. A: Gen., 67, 223 (1991)
Uemiya S, Sato N, Ando N, Kikuchi E, Ind. Eng. Chem. Res., 30, 585 (1991) 
Uemiya S, Matsuda T, Kikuchi E, J. Membr. Sci., 56, 325 (1991)
Uemiya S, Sato N, Ando H, Kude Y, Matsuda T, Kikuchi E, J. Membr. Sci., 56, 303 (1991) 
Uemiya S, Koike I, Kikuchi E, Appl. Catal. A: Gen., 76, 171 (1991) 
Uemiya S, Koseki M, Kojima T, "Preparation of Highly Pemeable Membranes for Hydrogen Separation Using a CVD Technique," in Ma, Y.H.(Ed.), Proceedings of the Third Unternational Conference on Inorganic Membranes, Worcester, MA, 545 (1994)
Vayenas CG, Bebelis S, Yentekakis IV, Linz HG, Catal. Today, 11, 303 (1992) 
Xomeritakis G, Lin YS, J. Membr. Sci., 120(2), 261 (1996) 
Xomeritakis G, Lin YS, J. Membr. Sci., 133(2), 217 (1997) 
Xu SJ, Thomson WJ, Ind. Eng. Chem. Res., 37(4), 1290 (1998) 
Yajima T, Koide K, Takai H, Fukatsu N, Iwahara H, Solid State Ion., 79, 333 (1995)
Yamanaka I, Otsuka K, J. Chem. Soc.-Faraday Trans., 89(11), 1791 (1993) 
Yamanaka I, Otsuka K, J. Alloy. Compd., 193(1-2), 56 (1993) 
Yan SC, Maeda H, Kusakabe K, Morooka S, Ind. Eng. Chem. Res., 33(3), 616 (1994) 
Yeung KL, Christiansen SC, Varma A, J. Membr. Sci., 159(1-2), 107 (1999) 
Yiokari CG, Pitselis GE, Polydoros DG, Katsaounis AD, Vayenas CG, J. Phys. Chem. A, 104(46), 10600 (2000) 
Zaman J, Chakma A, J. Membr. Sci., 92(1), 1 (1994) 
Zaspalis VT, van Praag W, Keizer K, van Ommen JG, Ross JHR, Burggraaf AJ, Appl. Catal. A: Gen., 74(2), 223 (1991)
Zeng Y, Lin YS, AIChE J., 47(2), 436 (2001) 
Zeng Y, Lin YS, J. Catal., 193(1), 58 (2000) 
Zhang K, Yang YL, Ponnusamy D, Jacobson AJ, Salama K, J. Mater. Sci., 34(6), 1367 (1999) 
Ziaka ZD, Minet RG, Tsotsis TT, J. Membr. Sci., 77, 221 (1993) 
Ziegler S, Theis J, Fritsch D, J. Membr. Sci., 187(1-2), 71 (2001) 

The Korean Institute of Chemical Engineers. F5, 119, Anam-ro, Seongbuk-gu, 233 Spring Street Seoul 02856, South Korea.
TEL. No. +82-2-458-3078FAX No. +82-507-804-0669E-mail : kiche@kiche.or.kr

Copyright (C) KICHE.all rights reserved.

- Korean Journal of Chemical Engineering 상단으로