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Received February 14, 2011
Accepted July 17, 2011
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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A crossover quasi-chemical nonrandom lattice fluid model for pure carbon dioxide and hydrocarbons
Department of Dermatological Health Management, Eulji University, 212, Yangji-dong, Sujeong-gu, Seongnam-si, Gyeonggi-do 461-713, Korea 1Department of Cosmetic Science, Chungwoon University, San 29, Namjang-ri, Hongseoung-gun, Chungnam 350-701, Korea 2School of Chemical & Biological Engineering, Seoul National University, Shinlim-dong, Gwanak-gu, Seoul 151-744, Korea
Korean Journal of Chemical Engineering, March 2012, 29(3), 404-412(9), 10.1007/s11814-011-0182-6
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Abstract
Thequasi-chemical nonrandom lattice fluid model is capable of describing thermodynamic properties for complex systems containing associating fluids, polymer, biomolecules and surfactants, but this model fails to reproduce the singular behavior of fluids in the critical region. In this research, we used the quasi-chemical nonrandom lattice fluid model and combined this model with a crossover theory to obtain a crossover quasi-chemical nonrandom lattice fluid model which incorporated the critical scaling laws valid asymptotically close to the critical point and reduced to the original quasi-chemical nonrandom model far from the critical point. The crossover quasi-chemical nonrandom lattice fluid model showed a great improvement in prediction of the volumetric properties and second-order derivative properties near the critical region.
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Lacombe RH, Sanchez IC, J. Phys. Chem., 80, 2368 (1976)
Shin MS, Kim H, Fluid Phase Equilib., 246(1-2), 79 (2006)
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Yeom MS, Yoo KP, Park BH, Lee CS, Fluid Phase Equilib., 158-160, 143 (1999)
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Jang SH, Shin MS, Kim HY, Korean J. Chem. Eng., 26(1), 225 (2009)
Shin MS, Lee JH, Kim H, Fluid Phase Equilib., 272(1-2), 42 (2008)
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Park CI, Shin MS, Kim H, J. Chem. Thermodyn., 41(1), 30 (2009)
Panayiotou C, Vera JH, Polymer J., 14, 681 (1982)
Kumar SK, Suter UW, Reid RC, Ind. Eng. Chem. Res., 26, 2532 (1987)
Kiselev SB, Ely JF, Fluid Phase Equilib., 119, 8645 (2003)
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Lemmon EW, McLinden MO, Friend DG, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg MD, 20899, http://webbook.nist.gov (2001)
Kang J, Yoo K, Kim H, Lee J, Yang D, Lee C, Int. J. Thermophys., 22, 487 (2001)
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Sanchez IC, Lacombe RH, J. Phys. Chem., 80, 2352 (1976)
Lacombe RH, Sanchez IC, J. Phys. Chem., 80, 2368 (1976)
Shin MS, Kim H, Fluid Phase Equilib., 246(1-2), 79 (2006)
Shin MS, Yoo KP, Lee CS, Kim H, Korean J. Chem. Eng., 23(3), 469 (2006)
Shin MS, Yoo KP, Lee CS, Kim H, Korean J. Chem. Eng., 23(3), 476 (2006)
Gauter K, Heidemann RA, Ind. Eng. Chem. Res., 39(4), 1115 (2000)
Burstyn HC, Sengers JV, Phys. Rev. Lett., 45, 259 (1980)
Sengers JV, Levelt-Sengers JMH, Ann. Rev. Phys. Chem., 37, 189 (1986)
Kiselev SB, Friend DG, Fluid Phase Equilib., 162(1-2), 51 (1999)
Kiselev SB, Fly JF, Fluid Phase Equilib., 174(1-2), 93 (2000)
Lee Y, Shin MS, Yeo JK, Kim H, Fluid Phase Equilib., 39, 1257 (2007)
Shin MS, Lee Y, Kim H, J. Chem. Thermodyn., 40(2), 174 (2008)
Lee Y, Shin MS, Ha B, Kim H, J. Chem. Thermodyn., 40(5), 741 (2008)
Lee Y, Shin MS, Kim H, J. Chem. Phys., 129, 203503 (2008)
You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 193 (1994)
You SS, Yoo KP, Lee CS, Fluid Phase Equilib., 93, 215 (1994)
Yeom MS, Yoo KP, Park BH, Lee CS, Fluid Phase Equilib., 158-160, 143 (1999)
Kang JW, Lee JH, Yoo KP, Lee CS, Fluid Phase Equilib., 194-197, 77 (2002)
Shin MS, Kim H, Fluid Phase Equilib., 256(1-2), 27 (2007)
Shin MS, Kim H, J. Chem. Thermodyn., 40(7), 1110 (2008)
Jang SH, Shin MS, Kim HY, Korean J. Chem. Eng., 26(1), 225 (2009)
Shin MS, Lee JH, Kim H, Fluid Phase Equilib., 272(1-2), 42 (2008)
Shin MS, Kim H, Fluid Phase Equilib., 270(1-2), 45 (2008)
Park CI, Shin MS, Kim H, J. Chem. Thermodyn., 41(1), 30 (2009)
Panayiotou C, Vera JH, Polymer J., 14, 681 (1982)
Kumar SK, Suter UW, Reid RC, Ind. Eng. Chem. Res., 26, 2532 (1987)
Kiselev SB, Ely JF, Fluid Phase Equilib., 119, 8645 (2003)
Anisimov MA, Kiselev SB, Sengers JV, Tang S, Physica A., 188, 487 (1992)
Lemmon EW, McLinden MO, Friend DG, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg MD, 20899, http://webbook.nist.gov (2001)
Kang J, Yoo K, Kim H, Lee J, Yang D, Lee C, Int. J. Thermophys., 22, 487 (2001)
Anisimov MA, Beketov VG, Voronov VP, Nagaev VB, Smimov VA, Teplofiz. Svoistva Veschestv Mater. (USSR)., 16, 124 (1982)
Abdulagatov IM, Kiselev SB, Levina LN, Zakaryaev ZR, Mamchonkova ON, Int. J. Thermoyphys., 17, 423 (1996)
Abdulagatov IM, Polikhronidi NG, Batyrova RG, J. Chem. Thermodyn., 26(10), 1031 (1994)
