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Received April 24, 2013
Accepted August 5, 2013
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Determination of cost-effective operating condition for CO2 capturing using 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid
Emad Ali†
Inas Alnashef
Abdelhamid Ajbar
Sarwono Mulyono
Hanee Farzana Hizaddin1
Mohamed Kamel Hadj-Kali
Chemical Engineering Department, King Saud University, P. O. Box 800, Riyadh 11421, Saudi Arabia 1Department of Chemical Engineering, University of Malaya, 50603, Kuala Lumpur, Malaysia
amkamal@ksu.edu.sa
Korean Journal of Chemical Engineering, November 2013, 30(11), 2068-2077(10), 10.1007/s11814-013-0148-y
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Abstract
1-Butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]) ionic liquid (IL) is considered for CO2 capturing in a typical absorption/stripper process. The use of ionic liquids is considered to be cost-effective because it requires less energy for solvent recovery compared to other conventional processes. A mathematical model was developed for the process based on Peng-Robinson (PR) equation of state (EoS). The model was validated with experimental data for CO2 solubility in [BMIM][BF4]. The model is utilized to study the sorbent effect and energy demand_x000D_
for selected operating pressure at specific CO2 capturing rates. The energy demand is expressed by the vapor-liquid equilibrium temperature necessary to remove the captured CO2 from the spent solvent in the regeneration step. It is found that low recovery temperature can be achieved at specific pressure combination for the absorber/stripper units. In fact, the temperature requirement is less than that required by the typical monoethanolamine (MEA) solvent. The effect of the CO2 loading in the sorbent stream on the process performance is also examined.
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Aki SNVK, Mellein BR, Saurer EM, Brennecke JF, J. Phys. Chem. B, 108(52), 20355 (2004)
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Harvey AH, Application of molecular modeling to vapor-liquid equilibrium of water with synthesis gas, 15th Inter Conference on the Properties of Water and Steam, Berlin, Sep. 8-11 (2008)
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