Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received January 2, 2013
Accepted February 24, 2013
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Fabrication of superhydrophobic surfaces using structured colloids
Department of Chemical Engineering and Biotechnology, Korea Polytechnic University, 237, Siheung-si, Gyeonggi-do 429-793, Korea 1Division of Powder and Ceramics, Korea Institute of Materials Science, 66, Sangnam-dong, Changwon, Gyeongnam 641-831, Korea 2Materials Processing Division, Korea Institute of Materials Science, 66, Sangnam-dong, Changwon, Gyeongnam 641-831, Korea 3Department of Chemistry, Sungkyunkwan University, Suwon 440-746, Korea
Korean Journal of Chemical Engineering, May 2013, 30(5), 1142-1152(11), 10.1007/s11814-013-0031-x
Download PDF
Abstract
We have introduced water-in-oil emulsion systems to generate confining geometries for the self-organization of monodisperse silica nanospheres as building block particles. Then, through the slow evaporation of emulsion phases by heating, these nanospheres were packed into structural colloids such as raspberry-shaped micro-particles. The suspension of colloidal clusters was deposited onto glass substrate followed by surface modification of fluorinecontaining silane coupling agent to produce superhydrophobic surface with dual scale roughness. Similar self-assembly approach was employed to fabricate macroporous micro-particles from composite micro-particles of polystyrene microspheres and antimony-doped tin oxide nanoparticles by calcination. After deposition of the porous particles and fluorine treatment with silane coupling agent, superhydrophobic surfaces which have potential applications such as self cleaning property could be obtained with contact angle of water larger than 150℃.
References
Cho YS, Yi GR, Moon JH, Kim DC, Lee BJ, Yang SM, Langmuir, 21(23), 10770 (2005)
Yu HM, Kim AR, Moon JH, Lim JS, Choi KY, Bull.Korean Chem. Soc., 32, 2178 (2011)
Moon JH, Kim WS, Ha JW, Jang SG, Yang SM, Park JK, Chem. Commun., 32, 4107 (2005)
Choi DG, Jang SG, Kim S, Lee E, Han CS, Yang SM, Adv. Funct. Mater., 16(1), 33 (2006)
Cho YS, Kim TY, Yi GR, Kim YK, Choi CJ, Bull.Korean Chem. Soc., 33, 159 (2012)
Iskandar F, Abdullah M, and K. Okuyama K, Nano Lett., 1, 231 (2001)
Yang SM, Kim SH, Lim JM, Yi GR, J. Mater. Chem., 18, 2177 (2008)
Blaaderen A, Nature., 439, 545 (2006)
Cho YS, Yi GR, Lim JM, Kim SH, Manoharan VN, Pine DJ, Yang SM, J. Am. Chem. Soc., 127(45), 15968 (2005)
Zoldesi CI, Imhof A, Adv. Mater., 17(7), 924 (2005)
Lee G, Cho YS, Park S, Yi GR, Korean J. Chem. Eng., 28(8), 1641 (2011)
Cho YS, Kim SH, Moon JH, Korean J. Chem. Eng., 29(8), 1102 (2012)
Klein SM, Manoharan VN, Pine DJ, Lang FF, Langmuir., 21, 6669 (2010)
Yi GR, Manoharan VN, Klein S, Brzezinska KR, Pine DJ, Lange FF, Yang SM, Adv. Mater., 14(16), 1137 (2002)
Manoharan VN, Elsesser MT, Pine DJ, Science., 301, 483 (2003)
Velev OD, Lenhoff AM, Kaler EW, Science., 287, 2240 (2000)
Velev OD, Furusawa K, Nagayama K, Langmuir, 12(10), 2385 (1996)
Kuncicky DM, Bose K, Costa KD, Velev OD, Chem.Mater., 19, 141 (2007)
Wang XY, Husson SM, Qian XH, Wickramasinghe SR, J. Membr. Sci., 365(1-2), 302 (2010)
Xu M, Feng D, Dai R, Wu H, Zhao D, Zheng G, Nanoscale., 3, 3329 (2011)
Nandiyanto ABD, Iskandar F, Okuyama K, Chem. Eng. J., 152(1), 293 (2009)
Moon JH, Cho YS, Yang SM, Bull. Korean Chem. Soc., 30, 2245 (2009)
Furstner R, Barthlott W, Neinhuis C, Walzel P, Langmuir, 21(3), 956 (2005)
Xie QD, Fan GQ, Zhao N, Guo XL, Xu J, Dong JY, Zhang LY, Zhang YJ, Han CC, Adv. Mater., 16(20), 1830 (2004)
Lim JM, Yi GR, Moon JH, Heo CJ, Yang SM, Langmuir, 23(15), 7981 (2007)
Ming W, Wu D, Benthem R, With G, Nano Lett., 5, 2298 (2005)
Xu D, Wang M, Ge X, Lam M, Ge X, J. Mater. Chem., 22, 5784 (2012)
Cho YS, Kim YK, Son SJ, Choi CJ, Abstracts of IEEE NMDC 2012 Conference, 522 (2012)
Miyatake K, Ohama O, Kawahara Y, Urano A, Kimura A, SEI Tech. Rev. No. 65, 21 (2007)
Cho YS, Yi GR, Hong JJ, Jang SH, Yang SM, Thin Solid Films, 515(4), 1864 (2006)
Cho YS, Kim HM, Hong JJ, Yi GR, Jang SH, Yang SM, Colloids Surf. A., 336, 88 (2009)
Cassie ABD, Baxter S, Trans. Faraday Soc., 40, 546 (1944)
Wu D, Nature inspired superhydrophobic surfaces, Eindhoven University Press, Eindhoven, Netherlands (2007)
Arsenault E, Soheilnia N, Ozin GA, ACS Nano., 5, 2984 (2011)
Martines E, Seunarine K, Morgan H, Gadegaard N, Wilkinson CDW, Riehle MO, Nano Lett., 5(10), 2097 (2005)
Kim DS, Lee BK, Yeo J, Choi MJ, Yang W, Kwon TH, Microelectron. Eng., 86, 1375 (2009)
Rao AV, Gurav AB, Sanjay SLA, Vhatkar RS, Imai H, Kappenstein C, Wagh PB, Gupta SC, J. Colloid Interface Sci., 352(1), 30 (2010)
Wenzel RN, J. Phys. Chem., 53(9), 1466 (1949)
Frei RM, Contact angle investigations on substrates with controlled periodic roughness: different asperity sizes and different substrate temperatures, Semester Project, Swiss Federal Institute of Technology (EPFL), Lausanne, Switzerland (2004)
Cho YS, Choi SY, Kim YK, Yi GR, J. Colloid Interface Sci., 386, 88 (2012)
Li Y, Cai W, Cao B, Duan G, Sun F, Li C, Jia L, Nanotechnology., 17, 238 (2006)
Yu HM, Kim AR, Moon JH, Lim JS, Choi KY, Bull.Korean Chem. Soc., 32, 2178 (2011)
Moon JH, Kim WS, Ha JW, Jang SG, Yang SM, Park JK, Chem. Commun., 32, 4107 (2005)
Choi DG, Jang SG, Kim S, Lee E, Han CS, Yang SM, Adv. Funct. Mater., 16(1), 33 (2006)
Cho YS, Kim TY, Yi GR, Kim YK, Choi CJ, Bull.Korean Chem. Soc., 33, 159 (2012)
Iskandar F, Abdullah M, and K. Okuyama K, Nano Lett., 1, 231 (2001)
Yang SM, Kim SH, Lim JM, Yi GR, J. Mater. Chem., 18, 2177 (2008)
Blaaderen A, Nature., 439, 545 (2006)
Cho YS, Yi GR, Lim JM, Kim SH, Manoharan VN, Pine DJ, Yang SM, J. Am. Chem. Soc., 127(45), 15968 (2005)
Zoldesi CI, Imhof A, Adv. Mater., 17(7), 924 (2005)
Lee G, Cho YS, Park S, Yi GR, Korean J. Chem. Eng., 28(8), 1641 (2011)
Cho YS, Kim SH, Moon JH, Korean J. Chem. Eng., 29(8), 1102 (2012)
Klein SM, Manoharan VN, Pine DJ, Lang FF, Langmuir., 21, 6669 (2010)
Yi GR, Manoharan VN, Klein S, Brzezinska KR, Pine DJ, Lange FF, Yang SM, Adv. Mater., 14(16), 1137 (2002)
Manoharan VN, Elsesser MT, Pine DJ, Science., 301, 483 (2003)
Velev OD, Lenhoff AM, Kaler EW, Science., 287, 2240 (2000)
Velev OD, Furusawa K, Nagayama K, Langmuir, 12(10), 2385 (1996)
Kuncicky DM, Bose K, Costa KD, Velev OD, Chem.Mater., 19, 141 (2007)
Wang XY, Husson SM, Qian XH, Wickramasinghe SR, J. Membr. Sci., 365(1-2), 302 (2010)
Xu M, Feng D, Dai R, Wu H, Zhao D, Zheng G, Nanoscale., 3, 3329 (2011)
Nandiyanto ABD, Iskandar F, Okuyama K, Chem. Eng. J., 152(1), 293 (2009)
Moon JH, Cho YS, Yang SM, Bull. Korean Chem. Soc., 30, 2245 (2009)
Furstner R, Barthlott W, Neinhuis C, Walzel P, Langmuir, 21(3), 956 (2005)
Xie QD, Fan GQ, Zhao N, Guo XL, Xu J, Dong JY, Zhang LY, Zhang YJ, Han CC, Adv. Mater., 16(20), 1830 (2004)
Lim JM, Yi GR, Moon JH, Heo CJ, Yang SM, Langmuir, 23(15), 7981 (2007)
Ming W, Wu D, Benthem R, With G, Nano Lett., 5, 2298 (2005)
Xu D, Wang M, Ge X, Lam M, Ge X, J. Mater. Chem., 22, 5784 (2012)
Cho YS, Kim YK, Son SJ, Choi CJ, Abstracts of IEEE NMDC 2012 Conference, 522 (2012)
Miyatake K, Ohama O, Kawahara Y, Urano A, Kimura A, SEI Tech. Rev. No. 65, 21 (2007)
Cho YS, Yi GR, Hong JJ, Jang SH, Yang SM, Thin Solid Films, 515(4), 1864 (2006)
Cho YS, Kim HM, Hong JJ, Yi GR, Jang SH, Yang SM, Colloids Surf. A., 336, 88 (2009)
Cassie ABD, Baxter S, Trans. Faraday Soc., 40, 546 (1944)
Wu D, Nature inspired superhydrophobic surfaces, Eindhoven University Press, Eindhoven, Netherlands (2007)
Arsenault E, Soheilnia N, Ozin GA, ACS Nano., 5, 2984 (2011)
Martines E, Seunarine K, Morgan H, Gadegaard N, Wilkinson CDW, Riehle MO, Nano Lett., 5(10), 2097 (2005)
Kim DS, Lee BK, Yeo J, Choi MJ, Yang W, Kwon TH, Microelectron. Eng., 86, 1375 (2009)
Rao AV, Gurav AB, Sanjay SLA, Vhatkar RS, Imai H, Kappenstein C, Wagh PB, Gupta SC, J. Colloid Interface Sci., 352(1), 30 (2010)
Wenzel RN, J. Phys. Chem., 53(9), 1466 (1949)
Frei RM, Contact angle investigations on substrates with controlled periodic roughness: different asperity sizes and different substrate temperatures, Semester Project, Swiss Federal Institute of Technology (EPFL), Lausanne, Switzerland (2004)
Cho YS, Choi SY, Kim YK, Yi GR, J. Colloid Interface Sci., 386, 88 (2012)
Li Y, Cai W, Cao B, Duan G, Sun F, Li C, Jia L, Nanotechnology., 17, 238 (2006)
