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Received February 20, 2013
Accepted May 4, 2013
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Thermodynamics of molecular interactions in binary mixtures containing associated liquids
Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India 1Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India
Korean Journal of Chemical Engineering, August 2013, 30(8), 1636-1643(8), 10.1007/s11814-013-0076-x
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Abstract
Experimentally measured data of excess molar volumes and enthalpies at 308.15 K for binary mixtures of formamide with 1-butanol or 2-methyl-1-propanol were fitted to the Redlich-Kister polynomial equation. Thermodynamics of molecular interaction in these mixtures was discussed using Prigogine-Flory-Patterson theory, Treszczanowicz-Benson association model and Graph theoretical approach. Extent of inter-molecular H-bonding in formamide and butanol in their binary mixtures was also reflected in their molar enthalpy of association of H-bonding ΔhH0 and association constant KH calculated from Treszczanowicz-Benson association model. All the three theories predict the excess property data reasonably well.
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References
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Bhardwaj U, Singh KC, Makin S, Indian J. Chem., 37A, 316 (1998)
Singh KC, Kalra KC, Maken S, Gupta V, Fluid Phase Equilib., 119(1-2), 175 (1996)
Conti G, Gianni P, Lepori L, Matteoli E, Fluid Phase Equilib., 105(1), 93 (1995)
Liu A, Kohler F, Karrer L, Gaube J, Spellucci P, Pure Appl.Chem., 61, 1441 (1989)
Stokes RH, J. Chem. Soc., Faraday Trans. 1: Physical Chemistry in Condensed Phases., 73, 1140 (1977)
Huggins ML, J. Phys. Chem., 74, 371 (1970)
Huggins ML, Polymer., 12, 389 (1971)
Singh PP, Maken S, Pure Appl. Chem., 66, 449 (1994)
Jorgensen WL, Swenson CJ, J. American Chem. Soc., 107, 569 (1985)
Garcia B, Alcalde R, Leal JM, Matos JS, J. Chem. Soc.Faraday Trans., 92, 3347 (1996)
Maken A, Maken S, J. Ind. Eng. Chem., 18(3), 1013 (2012)
Treszczanowicz AJ, Benson GC, Fluid Phase Equilib., 23, 117 (1985)
Treszczanowicz AJ, Benson GC, Fluid Phase Equilib., 41, 31 (1988)
Wang L, Benson GC, Lu BCY, J. Chem. Thermodyn., 24, 1305 (1992)
Bender M, Heintz A, Fluid Phase Equilib., 89, 197 (1993)
Funke H, Wetzel M, Heintz A, Pure Appl. Chem., 61, 1429 (1989)
Seo J, Lee J, Kim H, Fluid Phase Equilib., 172(2), 211 (2000)
Seo J, Lee J, Kim H, Fluid Phase Equilib., 182(1-2), 199 (2001)
Bhardwaj U, Maken S, Singh KC, J. Chem. Thermodyn., 28(10), 1173 (1996)
Kwon CH, Kang JW, Korean J. Chem. Eng., 26(1), 240 (2009)
Singh KC, Kalra KC, Maken S, Gupta V, Fluid Phase Equilib., 119(1-2), 175 (1996)
Gupta V, Maken S, Kalra KC, Singh KC, Thermochim. Acta, 277, 187 (1996)
Singh KC, Kalra KC, Maken S, Gupta V, Thermochim. Acta, 275(1), 51 (1996)
Stokes RH , Burfitt C, J. Chem. Thermodyn., 5, 623 (1973)
Stokes RH, Adamson M, J. Chem. Soc., Faraday Trans. 1: Physical Chemistry in Condensed Phases., 71, 1707 (1975)
Stokes RH, Marsh KN, J. Chem. Thermodyn., 8, 709 (1976)
Stokes RH, Adamson M, J. Chem. Thermodyn., 8, 683 (1976)
Hwang IC, Park SJ, Han KJ, Fluid Phase Equilib., 303(2), 150 (2011)
Hwang IC, Park SJ, Han KJ, Fluid Phase Equilib., 309(2), 145 (2011)
Shin SH, Hwang IC, Park SJ, In SJ, J. Ind. Eng. Chem., 18(2), 848 (2012)
Seo MD, Kim YJ, Lim JS, Kang JW, Korean J. Chem. Eng., 29(1), 103 (2012)
Breitholz A, Yoo KP, Lim JS, Lee CS, Kang JW, Korean J. Chem. Eng., 25(4), 833 (2008)
Lashkarbolooki M, Hezave AZ, babapoor A, Korean J. Chem. Eng., 30(1), 213 (2013)
Gupta V, Maken S, Kalra KC, Singh LC, Fluid Phase Equilib., 120(1-2), 195 (1996)
Pina CG, Francesconi AZ, Fluid Phase Equilib., 143(1-2), 143 (1998)
Torres RB, Francesconi AZ, Volpe PLO, Fluid Phase Equilib., 210(2), 287 (2003)
Acree WE, Campbell SW, Fluid Phase Equilib., 150-151, 207 (1998)
Geppert-Rybczynska M, Hofman T, Acta Phys. Pol., A., 114, 91 (2008)
Kim MG, Korean J. Chem. Eng., 29(9), 1253 (2012)
Khattab IS, Bandarkar F, Fakhree MAA, Jouyban A, Korean J. Chem. Eng., 29(6), 812 (2012)
Rani M, Maken S, Thermochim. Acta., 559, 98 (2013)
Rani M, Maken S, J. Ind. Eng. Chem., 18(5), 1694 (2012)
Flory PJ, J. American Chem. Soc., 87, 1833 (1965)
Abe A, Flory PJ, J. American Chem. Soc., 87, 1838 (1965)
Prigogine I, Trappeniers N, Mathot V, Discussions of the Faraday Society., 15, 93 (1953)
Patterson D, Delmas G, Discussions of the Faraday Society., 49, 98 (1970)
Prigogine I, Trappeniers N, Mathot V, J. Chem. Phys., 21, 559 (1953)
Prigogine I, Bellemans A, Mathot V, The Molecular Theory of Solutions, North-Holland Publishing Company, Amsterdam (1957)
Galvao AC, Francesconi AZ, J. Mol. Liq., 139, 110 (2008)
Singh PP, Maken S, Pure Appl. Chem., 66, 449 (1994)
Maken S, Deshwal BR, Chadha R, Anu, Singh KC, Kim H, Park JW, Fluid Phase Equilib., 235(1), 42 (2005)
Rani M, Maken S, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.01.014. (2013)
Rani M, Agarwal S, Lahot P, Maken S, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.02.011. (2013)
Monk P, Wadso I, Acta Chem. Scand., 22, 1842 (1968)
Adcock DS, McGlashan ML, Proceedings of the Royal Society of London, Series A. Mathematical and Physical Sciences., 226, 266 (1954)
Kumar S, Maken A, Agarwal S, Maken S, J. Mol. Liq., 155, 115 (2010)
Verma N, Maken S, Singh KC, J. Mol. Liq., 141, 35 (2008)
Pikkarainen L, J. Chem. Thermodyn., 23, 877 (1991)
Costas M, Patterson D, J. Solution Chem., 11, 807 (1982)
Kehiaian HV, in MTP international Review of Science, Skinner HA, Ed., Thermochemistry and thermodynamics, Butteworth, London (1972)
Bondi A, Physical properties of molecular crystals, liquids and gases, Wiley, New York (1968)
Dunn LA, Stokes RH, Trans. Faraday Soc., 65, 2906 (1969)
Easteal AJ, Woolf LA, J. Chem. Thermodyn., 15, 195 (1983)
Bhardwaj U, Singh KC, Makin S, Indian J. Chem., 37A, 316 (1998)
Singh KC, Kalra KC, Maken S, Gupta V, Fluid Phase Equilib., 119(1-2), 175 (1996)
Conti G, Gianni P, Lepori L, Matteoli E, Fluid Phase Equilib., 105(1), 93 (1995)
Liu A, Kohler F, Karrer L, Gaube J, Spellucci P, Pure Appl.Chem., 61, 1441 (1989)
Stokes RH, J. Chem. Soc., Faraday Trans. 1: Physical Chemistry in Condensed Phases., 73, 1140 (1977)
Huggins ML, J. Phys. Chem., 74, 371 (1970)
Huggins ML, Polymer., 12, 389 (1971)
Singh PP, Maken S, Pure Appl. Chem., 66, 449 (1994)
