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Received December 27, 2013
Accepted March 18, 2014
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Comparative removal of two textile dyes from aqueous solution by adsorption onto marine-source waste shell : Kinetic and isotherm studies
Department of Environmental Health Engineering, School of Health, Guilan University of Medical Sciences, Rasht, Iran 1Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran 2School of Mechanical Engineering, Yeungnam University, Gyeongsan 712-749, Korea
Korean Journal of Chemical Engineering, August 2014, 31(8), 1451-1459(9), 10.1007/s11814-014-0085-4
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Abstract
Scallop shell was used as a low-cost adsorbent for removal of two anionic textile dyes, Reactive Blue 19 (RB19) and Acid Cyanine 5 R (AC5R), from aqueous solutions. The adsorbent was characterized using inductively coupled plasma optical emission spectrometry (ICP-OES), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). The dye removal efficiency of scallop shell was determined as function of contact time, solution pH, initial dye concentration and adsorbent dosage. With increasing dye concentration, the adsorption of both dyes decreased, while it increased with increasing adsorbent dosage. Optimum removal of RB19 and AC5R was achieved at pH=6. Adsorption equilibrium data were well described by the Freundlich model. The maximum dye adsorption capacity of scallop shell as estimated from the Langmuir isotherm was 12.36 and 12.47 mg/g for RB19 and AC5R, respectively. The adsorption kinetic data showed excellent correlation with the pseudosecond-order model. It was concluded that scallop shell has a remarkable potential for the sorption of RB19 and AC5R and can be used for treatment of the dye contaminated wastewater.
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Khataee AR, Vafaei F, Jannatkhah M, Int. Biodeterior. Biodegrad., 83, 33 (2013)
Chakraborty S, De S, DasGupta S, Basu JK, Chemosphere, 58, 1079 (2005)
Chowdhury S, Chakraborty S, Saha P, Colloids Surf. B: Biointerfaces, 84, 520 (2011)
Yang SY, Yang X, Shao XT, Niu R, Wang LL, J. Hazard. Mater., 186(1), 659 (2011)
Mehta P, Mehta R, Suranaa M, Kabrab BV, J. Curr. Chem. Pharma. Sci., 1, 28 (2011)
Song S, Yao J, He ZQ, Qiu JP, Chen JM, J. Hazard. Mater., 152(1), 204 (2008)
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Zhu MX, Lee L, Wang HH, Wang Z, J. Hazard. Mater., 149(3), 735 (2007)
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Eren Z, Acar FN, Desalination, 194(1-3), 1 (2006)
Garg VK, Gupta R, Yadav AB, Kumar R, Bioresour. Technol., 89(2), 121 (2003)
Malik PK, J. Hazard. Mater., 113, 81 (2004)
Ferrero F, J. Hazard. Mater., 142(1-2), 144 (2007)
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Nigam P, Armour G, Banat IM, Singh D, Marchant R, Bioresour. Technol., 72(3), 219 (2000)
Wang S, Boyjoo Y, Choueib A, Zhu ZH, Water Res., 39, 129 (2005)
Walker GM, Hansen L, Hanna JA, Allen SJ, Water Res., 37, 2081 (2003)
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Shirzad-Siboni M, Khataee A, Joo SW, J. Ind. Eng. Chem., 20 (2014)
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Shirzad-Siboni M, Samarghandi MR, Azizian S, Kim WG, Lee SM, Environ. Eng. Res., 16, 1 (2011)
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Castilho S, Kiennemann A, Pereira MFC, Dias APS, Chem. Eng. J., 226, 146 (2013)
Vijaya Kumar G, Ramalingam P, Kim MJ, Yoo CK, Kumar MD, Korean J. Chem. Eng., 27(5), 1469 (2010)
Kumar PS, Ramalingam S, Sathishkumar K, Korean J. Chem. Eng., 28(1), 149 (2011)
Daneshvar E, Kousha M, Sohrabi MS, Khataee A, Converti A, Chem. Eng. J., 195-196, 297 (2012)
Bishnoi NR, Kumar R, Kumar S, Rani S, J. Hazard. Mater., 145(1-2), 142 (2007)
Mondal MK, Singh RS, Kumar A, Prasad BM, Korean J. Chem. Eng., 28(6), 1386 (2011)
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Ngah WSW, Teong LC, Hanafiah MAKM, Carbohydr. Polym., 83, 1446 (2011)
Chatterjee S, Chatterjee S, Chatterjee BP, Guha AK, Colloids Surf. A: Physicochem. Eng. Asp., 299, 146 (2007)
Barron-Zambrano J, Szygula A, Ruiz M, Sastre AM, Guibal E, J. Environ. Manage., 91, 2669 (2010)
Bellir K, Bouziane IS, Boutamine Z, Lehocine MB, Meniai AH, Energy Procedia, 18, 924 (2012)
Kousha M, Daneshvar E, Esmaeli AR, Jokar M, Khataee AR, Int. Biodeterior. Biodegrad., 69, 97 (2012)
Wang L, Zhang J, Zhao R, Li C, Li Y, Zhang CL, Desalination, 254(1-3), 68 (2010)
Toor M, Jin B, Chem. Eng. J., 187, 79 (2012)
Tunc O, Tanaci H, Aksu Z, J. Hazard. Mater., 163(1), 187 (2009)
Li L, Liu S, Zhu T, J. Environ. Sci., 22, 1273 (2010)
Gok O, Ozcan AS, Ozcan A, Appl. Surf. Sci., 256(17), 5439 (2010)
Xue YJ, Hou HB, Zhu SJ, Chem. Eng. J., 147(2-3), 272 (2009)
Gupta VK, Gupta B, Rastogi A, Agarwal S, Nayak A, J. Hazard. Mater., 186(1), 891 (2011)
