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Received September 10, 2015
Accepted December 2, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Efficient hydrolysis of cellulose over a magnetic lignin-derived solid acid catalyst in 1-butyl-3-methylimidazolium chloride
Jiangsu Key Laboratory for Biomass-based Energy and Enzyme Technology, School of Chemistry and Chemical Engineering, Jiangsu Collaborative Innovation Center of Regional Modern Agriculture & Environmental Protection, Huaiyin Normal University, Huaian 223300, China
Korean Journal of Chemical Engineering, April 2016, 33(4), 1232-1238(7), 10.1007/s11814-015-0267-8
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Abstract
A green and efficient strategy for the hydrolysis of cellulose was developed by using a magnetic lignin-derived solid acid catalyst (MLC-SO3H) in the presence of ionic liquid 1-butyl-3-methylimidazolium chloride ([BMIM]Cl). The results indicated that reaction temperature, reaction time, catalyst loading and water content have a big influence on the yield of total reducing sugars (TRS). By optimizing these reaction parameters, 69.3% TRS yield was observed at_x000D_
140 ℃ for 150 min with the addition of 40 wt% MLC-SO3H and 1 wt% water. More importantly, MLC-SO3H could be easily separated from the reaction mixture with an external magnet and could be repeatedly used five times without an obvious loss of catalytic activity, demonstrating that it possessed excellent recyclability. Furthermore, a plausible mechanism involving three consecutive processes of dissolution, adsorption and catalysis for the hydrolysis of cellulose in_x000D_
[BMIM]Cl over a catalyst of MLC-SO3H was also proposed.
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References
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Cantero DA, Bermejo MD, Cocero M, Bioresour. Technol., 135, 697 (2013)
Zhang QH, Benoit M, De Oliveira Vigier K, Barrault J, Jegou G, Philippe M, Jerome F, Green Chem., 15, 963 (2013)
Hu L, Lin L, Wu Z, Zhou SY, Liu SJ, Appl. Catal. B: Environ., 174-175, 225 (2015)
Gupta KM, Jiang JW, Chem. Eng. Sci., 121, 180 (2015)
Wang H, Gurau G, Rogers RD, Chem. Soc. Rev., 41, 1519 (2012)
Klemm D, Heublein B, Fink HP, Bohn A, Angew. Chem.-Int. Edit., 44, 3358 (2005)
Swatloski RP, Spear SK, Holbrey JD, Rogers RD, J. Am. Chem. Soc., 124(18), 4974 (2002)
Sun N, Rodriguez H, Rahman M, Rogers RD, Chem. Commun., 47, 1405 (2011)
Zakzeski J, Grisel RJ, Smit AT, Weckhuysen BM, ChemSusChem, 5, 430 (2012)
Yang ZZ, Huang RL, Qi W, Tong LP, Su RX, He ZM, Chem. Eng. J., 280, 90 (2015)
Wu CY, Chen W, Zhong LX, Peng XW, Sun RC, Fang JJ, Zheng SB, J. Agric. Food Chem., 62, 7430 (2014)
Freudenmann D, Wolf S, Wolff M, Feldmann C, Angew. Chem.-Int. Edit., 50, 11050 (2011)
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Wang JY, Zhou MD, Yuan YG, Zhang Q, Fang XC, Zang SL, Bioresour. Technol., 197, 42 (2015)
Brandt A, Grasvik J, Hallett JP, Welton T, Green Chem., 15, 550 (2013)
Remsing RC, Swatloski RP, Rogers RD, Moyna G, Chem. Commun., 12, 1271 (2006)
Maki-Arvela P, Anugwom I, Virtanen P, Sjoholm R, Mikkola JP, Ind. Crop. Prod., 32, 175 (2010)
Zhou LP, Yang XM, Xu JL, Shi MT, Wang F, Chen C, Xu J, Green Chem., 17, 1519 (2015)
Parveen F, Patra T, Upadhyayula S, Carbohydr. Polym., 135, 280 (2016)
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Shuai L, Pan XJ, Energy Environ. Sci., 5, 6889 (2012)
Huang YB, Fu Y, Green Chem., 15, 1095 (2013)
Rinaldi R, Palkovits R, Schuth F, Angew. Chem.-Int. Edit., 47, 8047 (2008)
Gliozzi G, Innorta A, Mancini A, Bortolo R, Perego C, Ricci M, Cavani F, Appl. Catal. B: Environ., 145, 24 (2014)
Cai HL, Li CZ, Wang AQ, Xu GL, Zhang T, Appl. Catal. B: Environ., 123-124, 333 (2012)
Cheng MX, Shi T, Guan HY, Wang ST, Wang XH, Jiang ZJ, Appl. Catal. B: Environ., 107(1-2), 104 (2011)
Takagaki A, Nishimura M, Nishimura S, Ebitani K, Chem. Lett., 40(10), 1195 (2011)
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Guo HX, Qi XH, Li LY, Smith RL, Bioresour. Technol., 116, 355 (2012)
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Zhou LP, Liu Z, Shi MT, Du SS, Su YL, Yangm XM, Xu J, Carbohydr. Polym., 98, 146 (2013)
Shen SG, Wang CY, Cai B, Li HM, Han Y, Wang T, Qin HF, Fuel, 113, 644 (2013)
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Qi XH, Lian YF, Yan LL, Smith RL, Catal. Commun., 57, 50 (2014)
Hu SL, Smith TJ, Lou WY, Zong MH, J. Agric. Food Chem., 62, 1905 (2014)
Xiong Y, Zhang ZH, Wang X, Liu B, Lin JT, Chem. Eng. J., 235, 349 (2014)
Guo HX, Lian YF, Yan LL, Qi XH, Smith RL, Green Chem., 15, 2167 (2013)
Kim SJ, Dwiatmoko AA, Choi JW, Suh YW, Suh DJ, Oh M, Bioresour. Technol., 101(21), 8273 (2010)
Tian JA, Fan CY, Cheng MX, Wang XH, Chem. Eng. Technol., 34(3), 482 (2011)
Lai DM, Deng L, Guo QX, Fu Y, Energy Environ. Sci., 4, 3552 (2011)
