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Received January 29, 2019
Accepted April 23, 2019
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Optimization of fructose dehydration to 5-hydroxymethylfurfural catalyzed by SO3H-bearing lignin-derived ordered mesoporous carbon
College of Chemical Engineering, Huaqiao University, Xiamen, 361021, Fujian, China
lhgan401@126.com
Korean Journal of Chemical Engineering, July 2019, 36(7), 1042-1050(9), 10.1007/s11814-019-0281-3
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Abstract
A sulfonated lignin-derived mesoporous carbon (LDMC-SO3H) was prepared from kraft lignin (KL) using phenolation and soft-template method followed by sulfonation. LDMC-SO3H bearing a sulfonic acid density of 0.65 mmol/g possessed a well-ordered 2D hexagonal mesoporous characteristics with mesopore volume of 0.067 cm3/g and specific surface area of 262m2/g as well as mesopore size of 3.42 nm. A high 5-hydroxymethylfurfural (5-HMF) yield of 98.0% with a full fructose conversion was obtained using LDMC-SO3H as catalyst under the optimized reaction conditions of reaction temperature and time of 140 °C and 120 min, initial fructose concentration of 100 g/L, catalyst load of 0.1mg/mg in DMSO. Furthermore, there was no obvious decrease in 5-HMF yield (≥ 95.0%) within the fivecycle experiment, highlighting the superior reusability and stability of LDMC-SO3H in fructose-to-5-HMF transformation.
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References
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Zhao H, Holladay JE, Brown H, Zhang Z, Science, 316, 1597 (2007)
