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저온 고압에서 Ethylene Gas의 열역학적 상태 방정식 및 이에 따르는 Computer Program의 개발
A Study on the Development of an Equation of State and Its Computer Program for Ethylene Gas at Low Temperature and High Pressure
HWAHAK KONGHAK, August 1977, 15(4), 259-268(10), NONE
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Abstract
Ethylene gas의 P-V-T 관계를 임계점 이하(9.5 ℃, 51 bar)에서 가장 날 나타낼 수 있는 상태 방장식 및 이의 계수를 최근 발표된 실험 data를 이용해서 비선형 최소자승법에 의해 구하는 computer program을 개발하였다. 본 연구에서는 243-297oK의 온도와 50 bar 미만의 범위에 있는 90개의 data point를 사용하여 수정된 Bender 방정식에 상기 비선형 최소 자승법에 의해 curve fitting하여 6-parameter 및 10-parameter 방정식들의 계수를 구하였으며 이들로부터 계산된 밀도의 RMS deviation은 0.1 %, Michels의 실험 data로부터의 RMS deviation은 0.15 %로서 이들 방정식들이 상기 실험범위내에서 0.15 % 이내의 오차 한계내에서 사용될 수 있다.
An equation of state, which can best represent the P-V-T data ethylene gas below the critical point (9.5 ℃, 51 bar), and its coefficients were determined by means of the non-linear least-squares technique using recently published experimental data. A total of 90 data points, ranging 243-297 oK temperature and below 50 bar pressure, were fitted to the modified Bender equation and the coefficients of the 6-parameter and 10-parameter equations were obtained. The RMS deviations of the calculated densities are 0.1 % from the experimental data used in this curve fitting, and 0.15 % from Michels data. Therefore these equations of state can be used within the experimental range with a probable error of ±0.15 %.