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구형 무연탄 입자의 비등온 연소현상 해석
An Analysis of Nonisothermal Combustion of a Spherical Anthracite Briquette
HWAHAK KONGHAK, February 1986, 24(1), 19-27(9), NONE
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Abstract
구형 무연탄 입자에 대하여 수축핵모델을 적용하여 비등온 연소현상을 연구하였다. 설정된 모델의 해가 존재하는 가능성영역(feasibility region)을 추적하여 연소현상의 예측에 이용하였으며 이 영역의 경계곡선은 단일회분층모델과 이중회분층모델로 표현되는 3종류의 한계상황을 해석하여 결정될 수 있음을 보였다. 이로부터 여러 가지 입자표면온도에 대응하는 미반응탄 표면온도의 상한과 하한을 추정하였으며, 또한 입자표면에서의 반응물 및 생성물의 속(束)들과 에너지속(束)의 상한과 하한을 식으로 표현하고 반응의 진행에 따라 가능성영역이 변화하는 추이를 관찰하였다. 무연탄입자 연소의 경우 해의 다중성이 나타날 가능성은 적으며 입자표면온도가 높을 때 회분층에서 CO의 재연소반응은 무시될 수 있는 것으로 추론된다.
A nonisothermal combustion model for a spherical anthracite briquette is developed and studied on the basis of the unreacted shrinking core model. The feasibility region, in which the solution must lie, is constructed and used for the prediction of the combustion characteristics. It turns out that the bounding curves of the feasibility region may be determined by analyzing the three limiting cases known as the single ash layer model and the double ash layer model. This treatment enables us to find the upper and lower bounds of the unreacted core surface temperature corresponding to various particle surface temperature. The solutions of the limiting cases provide expressions for the upper and lower bounds of the molar fluxes of the reactants and products as well as those of the energy flux at the particle surface. Also examined is the way how the feasibility region changes as the combustion proceeds. In the case of anthracite briquette combustion it is unlikely that multiple solutions may exist and it is deduced that the oxidation reacton of carbon monoxide in the ash layer may be neglectd when the particle surface temperature is sufficiently high.