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Received July 8, 2019
Accepted August 6, 2019
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Bubble-Point Measurement of Binary Mixture for the CO2 + Caprolactone Acrylate System in High Pressure
Department of Chemical and Biomolecular Engineering, Chonnam National University, Yeosu, Jeonnam 59626, Korea
Korean Chemical Engineering Research, December 2019, 57(6), 826-831(6), 10.9713/kcer.2019.57.6.826 Epub 3 December 2019
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Abstract
Experimental data of phase equilibrium is reported for caprolactone acrylate in supercritical carbon dioxide. Bubble-point data was measured by synthetic method at temperatures ranging from (313.2 to 393.2) K and pressures up to 55.93 MPa. In this research, the solubility of carbon dioxide for the (carbon dioxide + caprolactone acrylate) system decreases as temperature increases at a constant pressure. The (carbon dioxide + caprolactone acrylate) system exhibits type-I phase behavior. The experimental result for the (carbon dioxide + caprolactone acrylate) system was correlated with Peng-Robinson equation of state using mixing rule. The critical property of caprolactone acrylate was predicted with the Joback and Lyderson method.
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https://www.ulprospector.com/en/la/Adhesives/Detail/2097/46197/SR495B.
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Chirico RD, Frenkel M, Diky VV, Marsh KN, Wilhoit RC, J. Chem. Eng. Data, 48(5), 1344 (2003)
Yoon SD, Byun HS, J. Chem. Thermodyn., 71, 91 (2014)
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https://scientificpolymer.com/shop/caprolactone-acrylate-2/.
Yeo SD, Kiran E, J. Supercrit. Fluids, 34(3), 287 (2005)
McHugh, M. A. and Krukonis, V. J., Supercritical Fluid Extraction, 2nd ed., Butterworth-Heinemann, Stoneham, 1994.
Yim JH, Choo YS, Byun HS, J. Chem. Thermodyn., 130, 140 (2019)
Cho SH, Lee BS, Byun HS, J. of CO2 Utilization, 25, 39 (2018)
Lee H, Jeong JD, Byun HS, Korean Chem. Eng. Res., 56(5), 732 (2018)
Byun HS, Rhee SY, Korean J. Chem. Eng., 34(4), 1170 (2017)
Yoon SD, Byun HS, Korean J. Chem. Eng., 31(3), 522 (2014)
Cho DW, Shin J, Bae W, Kim H, Lee JH, Shin MS, Fluid Phase Equilib., 319, 37 (2012)
Jang YS, Kim SH, Yoo KP, Byun HS, Fluid Phase Equilib., 302(1-2), 234 (2011)
Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Poling BE, Prausnitz JM, O’Connell JP, The Properties of Liquids and Gases, 5thed., McGraw-Hill, New York, 2001.
Lee BS, Yeo WH, Byun HS, J. Chem. Eng. Data, 62(6), 1876 (2017)
Byun HS, Korean Chem. Eng. Res., 54(2), 206 (2016)
Chirico RD, Frenkel M, Diky VV, Marsh KN, Wilhoit RC, J. Chem. Eng. Data, 48(5), 1344 (2003)
Yoon SD, Byun HS, J. Chem. Thermodyn., 71, 91 (2014)
Jang YS, Byun HS, J. Chem. Eng. Data, 59(5), 1391 (2014)
Scott RL, van Konynenburg PB, Discuss. Faraday Soc., 49, 87 (1970)
Rowlinson JS, Swinton FL, Liquid and Liquid Mixtures, 3rd ed., Butterworth, Boston, 1982
Kuester JL, Mize JH, Optimization Techniques with Fortran, McGraw-Hill, New York, 1973.
https://scientificpolymer.com/shop/caprolactone-acrylate-2/.
